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Volumn 5, Issue 21, 2014, Pages 3878-3883

Imaging the stereodynamics of Cl + CH4(ν3 = 1): Polarization dependence on the rotational branch and the hyperfine depolarization

Author keywords

[No Author keywords available]

Indexed keywords

DEPOLARIZATION; POLARIZATION; REAGENTS;

EID: 84908611673     PISSN: None     EISSN: 19487185     Source Type: Journal    
DOI: 10.1021/jz502088c     Document Type: Article
Times cited : (8)

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    • note
    • 21-24 for which partial alignment could be retained even after long delay time. However, the temporal profile shown in Figure 4 refers to the reaction products and thus is the result of a cumulative depolarization effect (i.e., not the instantaneous time-dependent alignment of the reactants; see eqs 4 and 5) over the delay time of two lasers. In addition, possible collision-induced depolarization eff ects that tend to damp the oscillatory behaviors cannot be completely ruled out at longer delay time even under the crossed-beam conditions. In conjunction with the fact the observed temporal profiles do not show any oscillation (Figure 4), we surmise that using a more complicated, oscillatory decay form will not significantly affect the estimate made in this work.
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.