Conjugate umpolung of β,β-disubstituted enals by dual catalysis with an N-heterocyclic carbene and a Brønsted acid: facile construction of contiguous quaternary stereocenters

Angewandte Chemie (International ed. in English)

Volumn 53, Issue 39, 2014, Pages 10515-10519

  Li, Jun Long ^a   Sahoo, Basudev ^a   Daniliuc, Constantin G ^a   Glorius, Frank ^a  

^a UNIVERSITY OF MÜNSTER   (Germany)

Author keywords

carbenes; dual catalysis; quaternary centers; spiro compounds; umpolung

Indexed keywords

ACID; ALDEHYDE; CARBENE; HETEROCYCLIC COMPOUND; INDOLE DERIVATIVE; METHANE; OXINDOLE; SPIRO COMPOUND;

ANALOGS AND DERIVATIVES; CATALYSIS; CHEMISTRY; CYCLOADDITION; STEREOISOMERISM;

ACIDS; ALDEHYDES; CATALYSIS; CYCLOADDITION REACTION; HETEROCYCLIC COMPOUNDS; INDOLES; METHANE; SPIRO COMPOUNDS; STEREOISOMERISM;

EID: 84908539962     PISSN: None     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201405178     Document Type: Article

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