Superporous P(2-hydroxyethyl methacrylate) cryogel-M (M:Co, Ni, Cu) composites as highly effective catalysts in H2 generation from hydrolysis of NaBH4 and NH3BH3

International Journal of Hydrogen Energy

Volumn 39, Issue 28, 2014, Pages 15455-15463

  Seven, Fahriye ^a   Sahiner, Nurettin ^a,b  

^a ÇANAKKALE ONSEKIZ MART UNIVERSITY   (Turkey)

^b Nanoscience and Technology Research and Application Center NANORAC   (Turkey)

Author keywords

Chemical hydrides; Cryogel hydrogel reactor; H2 production; Hydrogen energy; Superporous hydrogel

Indexed keywords

ALKALINITY; HYDRIDES; HYDROLYSIS; NANOCATALYSTS; NANOPARTICLES; SODIUM BOROHYDRIDE; SYNTHESIS (CHEMICAL);

CHEMICAL HYDRIDE; CRYOGELS; H2 PRODUCTION; HYDROGEN ENERGY; SUPERPOROUS HYDROGELS;

HYDROGEN PRODUCTION;

EID: 84908240175     PISSN: 03603199     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ijhydene.2014.07.093     Document Type: Article

References (31)

1. X. Zhang, Z. Wei, Q. Guo, and H. Tian Kinetics of sodium borohydride hydrolysis catalyzed via carbon nanosheets supported Zr/Co J Power Sources 231 2013 190 196
2. A. Chinnappan, H. Kim, C. Baskar, and I.T. Hwang Hydrogen generation from the hydrolysis of sodium borohydride with new pyridinium dicationic salts containing transition metal complexes Int J Hydrogen Energy 37 2012 10240 10248
3. 4 (sodium borohydride) solution Energy 54 2013 263 270
4. Li Hao, J. Liao, X. Zhang, W. Liao, L. Wen, and J. Yang Controlled synthesis of nanostructured Co film catalysts with high performance for hydrogen generation from sodium borohydride solution J Power Sources 239 2013 277 283
5. 2 solution Renew Energy 60 2013 637 642
6. 3 Energy 53 2013 147 152
7. J.W. Jaworski, S. Cho, Y. Kim, J.H. Jung, H.S. Jeon, and B.K. Min Hydroxyapatite supported cobalt catalysts for hydrogen generation J Colloid Interface Sci 394 2013 401 408
8. H. Zou, S. Chen, Z. Zhao, and W. Lin Hydrogen production by hydrolysis of aluminum J Alloys Compd 578 2013 380 384
9. Y. Guo, Q. Feng, Z. Dong, and J. Ma Electrodeposited amorphous Co-P catalyst for hydrogen generation from hydrolysis of alkaline sodium borohydride solution J Mol Catal A Chem 378 2013 273 278
10. A. Lu, Y. Chen, J. Jin, G.-H. Yue, and D.-L. Peng CoO nanocrystals as a highly active catalyst for the generation of hydrogen from hydrolysis of sodium borohydride J Power Sources 220 2012 391 398
11. S.S. Mao, S. Shen, and L. Guo Nanomaterials for renewable hydrogen production, storage and utilization Prog Nat Sci Mater Int 22 2012 522 534
12. E. Serrano, G. Rus, and J. GarcIa-MartInez Nanotechnology for sustainable energy Renew Sustain Energy Rev 13 2009 2373 2384
13. C. Sealy Nanomaterials hold key to hydrogen production Nano Energy 2 2013 2 3
14. P.D. Lund Nanostructured materials for energy applications Microelectron Eng 108 2013 84 85
15. M.G. Lines Nanomaterials for practical functional uses J Alloys Compd 449 2008 242 245
16. N. Sahiner Soft and flexible hydrogel templates of different sizes and various functionalities for metal nanoparticle preparation and their use in catalysis Prog Polym Sci 38 2013 1329 1356
17. V.M. Gunko, I.N. Savina, and S.V. Mikhalovsky Cryogels: morphological, structural and adsorption characterization Adv Colloid Interface Sci 187-8 2013 1 46
18. S. Zheng, T. Wang, D. Liu, X. Liu, C. Wang, and Z. Tong Fast deswelling and highly extensible poly(N-isopropylacrylamide)-hectorite clay nanocomposite cryogels prepared by freezing polymerization Polymer 54 2013 1846 1852
19. P. Petrov, A. Utrata-Wesołek, B. Trzebicka, C.B. Tsvetanov, A. Dworak, and J. Aniol Biocompatible cryogels of thermosensitive polyglycidol derivatives with ultra-rapid swelling properties Eur Polym J 47 2011 981 988
20. O.M. Paduraru, D. Ciolacu, R.N. Darie, and C. Vasile Synthesis and characterization of polyvinyl alcohol/cellulose cryogels and their testing as carriers for a bioactive component Mater Sci Eng C 32 2012 2508 2515
21. D.C. Tuncaboylu, and O. Okay Hierarchically macroporous cryogels of polyisobutylene and silica nanoparticles Langmuir 26 2010 7574 7581
22. C. Bilici, S. Karayel, T.T. Demir, and O. Okay Self-oscillating pH-responsive cryogels as possible candidates of soft materials for generating mechanical energy J Appl Polym Sci 118 2010 2981 2988
23. N. Sahiner, O. Ozay, N. Aktas, E. Inger, and J. He The on demand generation of hydrogen from Co-Ni bimetallic nano catalyst prepared by dual use of hydrogel: as template and as reactor Int J Hydrogen Energy 36 2011 15250 15258
24. N. Sahiner, O. Ozay, E. Inger, and N. Aktas Superabsorbent hydrogels for cobalt nanoparticle synthesis and hydrogen production from hydrolysis of sodium boron hydride Appl Catal B 102 2011 201 206
25. N. Sahiner, S. Butun, and T. Turhan p(AAGA) hydrogel reactor for in situ Co and Ni nanoparticle preparation and use in hydrogen generation from the hydrolysis of sodium borohydride Chem Eng Sci 82 2012 114 120
26. N. Sahiner, S. Butun, O. Ozay, and B. Dibek Utilization of smart hydrogel-metal composites as catalysis media J Colloid Interface Sci 373 2012 122 128
27. 4 and hydrogen release with catalyst Renew Energy 34 2009 2362 2365
28. 2 by ball milling and usage as hydrogen carrier Renew Energy 35 2010 1895 1899
29. K.S. Eom, E.A. Cho, M.J. Kim, S.K. Oh, S.-W. Nam, and H.S. Kwon Thermochemical production of sodium borohydride from sodium metaborate in a scaled-up reactor Int J Hydrogen Energy 38 2013 2804 2809
30. N. Cao, J. Su, W. Luo, and G. Cheng Hydrolytic dehydrogenation of ammonia borane and methylamine borane catalyzed by grapheme supported Ru@Ni core-shell nanoparticles Int J Hydrogen Energy 39 2014 426 435
31. 2 production via hydrolysis reaction Fuel Process Tech 126 2014 324 331