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6-, which was initially identified only as a co-crystallization product, has recently been obtained in pure form; see Ref. [6a].
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19
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84957925911
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4POM CV scan; a major abatement of the catalytic wave was observed, which indicates that electrodeposition of active Mn-based catalysts is negligible (Figure S1).
-
4POM CV scan; a major abatement of the catalytic wave was observed, which indicates that electrodeposition of active Mn-based catalysts is negligible (Figure S1).
-
-
-
-
20
-
-
84957925912
-
-
2+ mixtures confirm that the catalyst is not competing with the sensitizer for light absorption in both laser flash photolysis and photocatalytic experiments (Figure S2).
-
2+ mixtures confirm that the catalyst is not competing with the sensitizer for light absorption in both laser flash photolysis and photocatalytic experiments (Figure S2).
-
-
-
-
21
-
-
84957925913
-
-
4POM (Figure S3); see
-
4POM (Figure S3); see:
-
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22
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84863329212
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M. Natali, M. Orlandi, S. Berardi, S. Campagna, M. Bonchio, A. Sartorel, F. Scandola, Inorg. Chem. 2012, 51, 7324-7331.
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23
-
-
84875508033
-
-
n states with n>4 could indeed be envisaged in the catalytic cycle; see.
-
n states with n>4 could indeed be envisaged in the catalytic cycle; see:, S. Piccinin, A. Sartorel, G. Aquilanti, A. Goldoni, M. Bonchio, S. Fabris, Proc. Natl. Acad. Sci. USA 2013, 110, 4917-4922.
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24
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67749124322
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W. J. Youngblood, S. H. A. Lee, Y. Kobayashi, E. A. Hernandez-Pagan, P. G. Hoertz, T. A. Moore, A. L. Moore, D. Gust, T. E. Mallouk, J. Am. Chem. Soc. 2009, 131, 926-927.
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25
-
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84957864118
-
-
II polyazotated complexes; see
-
II polyazotated complexes; see:, P. Huang, A. Magnuson, R. Lomoth, M. Abrahamsson, M. Tamm, L. Sun, B. van Rotterdam, J. Park, L. Hammarstrom, B. Akermark, S. Styring, J. Inorg. Biochem. 2002, 91, 151;
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26
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27
-
-
84957925914
-
-
2+ ions balance the sixfold negative charge of the polyanion (Figure S5).
-
2+ ions balance the sixfold negative charge of the polyanion (Figure S5).
-
-
-
-
28
-
-
84957925915
-
-
3+ on the 50 ms time scale (Figure S7, Ref. [14]).
-
3+ on the 50 ms time scale (Figure S7, Ref. [14]).
-
-
-
-
29
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77949387879
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33
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84957925916
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-1 were observed for highly defective Ca-doped Mn oxides; see Table S3.
-
-1 were observed for highly defective Ca-doped Mn oxides; see Table S3.
-
-
-
-
34
-
-
82455192762
-
-
4POM can be also compared to that of a recently reported dimanganese coordination complex with TON≈1; see
-
4POM can be also compared to that of a recently reported dimanganese coordination complex with TON≈1; see:, E. A. Karlsson, B.-L. Lee, T. Åkermark, E. V. Johnston, M. D. Kärkäs, J. Sun, Ö. Hansson, J.-E. Bäckvall, B. Åkermark, Angew. Chem. Int. Ed. 2011, 50, 11715-11718;
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