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Volumn 53, Issue 42, 2014, Pages 11182-11185

Photocatalytic Water Oxidation by a Mixed-Valent MnIII3MnIVO3 Manganese Oxo Core that Mimics the Natural Oxygen-Evolving Center

Author keywords

flash photolysis; manganese; oxygen evolution; polyoxometalates; water oxidation

Indexed keywords

CATALYTIC OXIDATION; MANGANESE REMOVAL (WATER TREATMENT); OXIDATION; OXYGEN; PHOTOLYSIS; PHOTOSYNTHESIS;

EID: 84907879857     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201404664     Document Type: Article
Times cited : (181)

References (36)
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    • Fang, X.1    McCallum, K.2    Pratt, H.D.3    Anderson, T.M.4    Dennis, K.5    Luban, M.6
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    • 4POM CV scan; a major abatement of the catalytic wave was observed, which indicates that electrodeposition of active Mn-based catalysts is negligible (Figure S1).
    • 4POM CV scan; a major abatement of the catalytic wave was observed, which indicates that electrodeposition of active Mn-based catalysts is negligible (Figure S1).
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    • 2+ mixtures confirm that the catalyst is not competing with the sensitizer for light absorption in both laser flash photolysis and photocatalytic experiments (Figure S2).
    • 2+ mixtures confirm that the catalyst is not competing with the sensitizer for light absorption in both laser flash photolysis and photocatalytic experiments (Figure S2).
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    • 4POM (Figure S3); see
    • 4POM (Figure S3); see:
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    • 2+ ions balance the sixfold negative charge of the polyanion (Figure S5).
    • 2+ ions balance the sixfold negative charge of the polyanion (Figure S5).
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    • 3+ on the 50 ms time scale (Figure S7, Ref. [14]).
    • 3+ on the 50 ms time scale (Figure S7, Ref. [14]).
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    • -1 were observed for highly defective Ca-doped Mn oxides; see Table S3.
    • -1 were observed for highly defective Ca-doped Mn oxides; see Table S3.
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    • Angew. Chem. 2011, 123, 11919-11922.
    • (2011) Angew. Chem. , vol.123 , pp. 11919-11922


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.