Integration of ozone and solar TiO2-photocatalytic oxidation for the degradation of selected pharmaceutical compounds in water and wastewater

Separation and Purification Technology

Volumn 136, Issue , 2014, Pages 18-26

  Márquez, Gracia ^a   Rodríguez, Eva M ^a   Maldonado, M Ignacio ^b   Álvarez, Pedro M ^a  

^a UNIVERSITY OF EXTREMADURA   (Spain)

^b PLATAFORMA SOLAR DE ALMERÍA CIEMAT   (Spain)

Author keywords

Integrated oxidation processes; Ozone; Pharmaceuticals; Solar photocatalysis; Water treatment

Indexed keywords

DRUG PRODUCTS; WATER TREATMENT;

OXIDATION PROCESS; PHARMACEUTICAL COMPOUNDS; PHOTOCATALYTIC OXIDATIONS; SOLAR PHOTOCATALYSIS; TIO; WATER AND WASTEWATER;

OZONE;

EID: 84907487041     PISSN: 13835866     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.seppur.2014.08.024     Document Type: Article

References (30)

1. A.M. Christensen, B. Markussen, A. Baun, and B. Halling-Sorensen Probabilistic environmental risk characterization of pharmaceuticals in sewage treatment plant discharges Chemosphere 77 2009 351 358
2. M. Isiduri, M. Bellotta, M. Cangiano, and A. Parrella Estrogenic activity of pharmaceuticals in the aquatic environment Environ. Int. 35 2009 826 829
3. D. Fatta-Kassinos, S. Meric, and A. Nikolaou Pharmaceutical residues in environmental waters and wastewater: current state of knowledge and future research Anal. Bioanal. Chem. 399 2011 251 275
4. M.M. Huber, A. Gobel, A. Joss, N. Hermann, D. Loffler, C.S. McArdell, A. Ried, H. Siegrist, T.A. Ternes, and U. von Gunten Oxidation of pharmaceuticals during ozonation of municipal wastewater effluents: a pilot study Environ. Sci. Technol. 39 2005 4290 4299
5. M. Ibáñez, E. Gracia-Lor, L. Bijlsma, E. Morales, L. Pastor, and F. Hernández Removal of emerging contaminants in sewage water subjected to advanced oxidation with ozone J. Hazard. Mater. 260 2013 389 398
6. T.A. Ternes, J. Stüber, N. Herrmann, D. McDowell, A. Ried, M. Kampmann, and B. Teiser Ozonation: a tool for removal of pharmaceuticals, contrast media and musk fragrances from wastewater? Water Res. 37 2003 1976 1982
7. N. Hamdi El Najjar, A. Touffet, M. Deborde, R. Journel, and N.K.V. Leither Levofloxacin oxidation by ozone and hydroxyl radicals: kinetic study, transformation products and toxicity Chemosphere 93 2013 604 611
8. M.J. Quero-Pastor, M.C. Garrido-Perez, A. Acevedo, and J.M. Quiroga Ozonation of ibuprofen: a degradation and toxicity study Sci. Total Environ. 466-467 2014 957 964
9. S. Malato, P. Fernandez-Ibáñez, M.I. Maldonado, J. Blanco, and W. Gernjak Decontamination and disinfection of water by solar photocatalysis: recent overview and trends Catal. Today 147 2009 1 59
10. 2 in a solar pilot plant Appl. Catal. B-Environ. 103 2011 294 301
11. -1 initial concentrations by mild solar photo-Fenton in MWTP effluents Water Res. 44 2010 545 554
12. V.L. Singleton, and J.A. Rossi Colorimetry of total phenolic with phosphomolybdicphosphotungstic acid reagents Am. J. Enol. Vitic. 16 1965 144 158
13. H. Bader, and J. Hoigné Determination of ozone in water by the indigo method Water Res. 15 1981 449 456
14. M. Jiménez, I. Oller, M.I. Maldonado, S. Malato, A. Hernández-Ramírez, A. Zapata, and J.M. Peralta-Hernández Catal. Today 161 2011 214 220
15. J. Benner, E. Salhi, T. Ternes, and U. von Gunten Ozonation of reverse osmosis concentrate: kinetics and efficiency of beta blocker oxidation Water Res. 42 2008 3003 3012
16. F.J. Real, J.L. Acero, F.J. Benítez, G. Roldán, and L.C. Fernández Oxidation of hydrochlorothiazide by UV radiation, hydroxyl radicals and ozone: kinetics and elimination from water systems Chem. Eng. J. 160 2010 72 78
17. G. Márquez, E.M. Rodríguez, F.J. Beltrán, and P.M. Álvarez Determination of rate constants for ozonation of ofloxacin in aqueous solution Ozone: Sci. Eng. 35 2013 186 195
18. M. Dodd, M. Buffle, and U. von Gunten Oxidation of antibacterial molecules by aqueous ozone: Moiety-specific reaction kinetics and application to ozone-based wastewater treatment Environ. Sci. Technol. 40 2006 1969 1977
19. F.J. Beltrán, J. Rivas, P.M. Álvarez, M.A. Alonso, and B. Acedo A kinetic model for advanced oxidation processes of aromatic hydrocarbons in water: application to phenanthrene and nitrobenzene Ind. Eng. Chem. Res. 38 1999 4189 4199
20. W.H. G1aze, and J. Kang Advanced oxidation processes. Description of a kinetic model for the oxidation of hazardous materials in aqueous media with ozone and hydrogen peroxide in a semibatch reactor Ind. Eng. Chem. Res. 28 1989 1573 1580
21. K. Soo Tay, N.A. Rahman, and M.R. Bin Abas Characterization of atenolol transformation products in ozonation by using rapid resolution high-performance liquid chromatography/quadrupole-time-of-light mass spectrometry Microchem. J. 99 2011 312 326
22. J. Radjenovic, M. Godehardt, M. Petrovic, A. Hein, M. Farré, M. Jekel, and D. Barceló Evidencing generation of persistent ozonation products of antibiotics roxithromycin and trimethoprim Environ. Sci. Technol. 43 2009 6808 6815
23. B. De Witte, H. Van Langenhove, K. Hemelsoet, K. Demeestere, P. De Wispelaere, V. Van Speybroeck, and J. Dewulf Levofloxacin ozonation in water: rate determining process parameters and reaction pathway elucidation Chemosphere 76 2009 683 689
24. K. Rajeshwar, M.E. Osugi, W. Chanmanee, C.R. Chenthamarakshan, M.V.B. Zanoni, P. Kajitvichyanukul, and R. Krishnan-Ayer Heterogeneous photocatalytic treatment of organic dyes in air and aqueous media J. Photochem. Photobiol. C: Photochem. Rev. 9 2008 171 192
25. K.H. Wammer, A.R. Korte, A.R. Lundeen, J.E. Sundberg, K. McNeill, and W.A. Arnold Direct photochemistry of three fluoroquinolone antibacterials: Norfloxacin, ofloxacin, and enrofloxacin Water Res. 47 2013 439 448
26. M.C. Cuquerella, F. Bosca, M.A. Miranda, A. Belvedere, A. Catalfo, and G. de Guidi Photochemical properties of ofloxacin involved in oxidative DNA damage: a comparison with rufloxacin Chem. Res. Toxicol. 16 2003 562 570
27. J. Radjenovic, C. Sirtori, M. Petrovic, D. Barceló, and S. Malato Solar photocatalytic degradation of persistent pharmaceuticals at pilot-scale: kinetics and characterization of major intermediate products Appl. Catal. B-Environ. 89 2009 255 264
28. 2 photocatalytic decomposition of β-blockers atenolol and propranolol in water and wastewater Sol. Energy 85 2011 1915 1926
29. M.N. Abellán, J. Jiménez, and S. Esplugas Photocatalytic degradation of antibiotics: the case of sulfamethoxazole and trimethoprim Catal. Today 144 2009 131 136
30. C. Sirtori, A. Agüera, W. Gernjak, and S. Malato Effect of water-matrix composition on trimethoprim solar photodegradation kinetics and pathways Water Res. 44 2010 2735 2744.