Adsorption and reaction branching of molecular carbonates on lithiated C(0001) substrates

Journal of Physical Chemistry C

Volumn 118, Issue 33, 2014, Pages 19017-19022

  Song, Wentao ^a   Bharath, Satyaveda ^a   Reutt Robey, Janice ^a  

^a Bldg 142   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ADSORPTION; BINDING ENERGY; BIOASSAY; CARBONATES; CARBONATION; ETHYLENE; SUBSTRATES; TEMPERATURE PROGRAMMED DESORPTION;

ADSORPTION AND REACTIONS; ADSORPTION ENERGIES; DIMETHYL CARBONATE; ETHYLENE CARBONATE; LITHIATED GRAPHITE; LITHIUM CARBONATES; LITHIUM ETHYLENE DICARBONATE; MASS BALANCE ANALYSIS;

LITHIUM;

EID: 84906568918     PISSN: 19327447     EISSN: 19327455     Source Type: Journal    
DOI: 10.1021/jp502230r     Document Type: Article

References (29)

1. Tarascon, J. M.; Armand, M. Issues and Challenges Facing Rechargeable Lithium Batteries Nature 2001, 414, 359-367
2. Tarascon, J. M. Key Challenges in Future Li-Battery Research Philos. Trans. R. Soc., A 2010, 368, 3227-3241
3. Arora, P.; White, R. E.; Doyle, M. Capacity Fade Mechanisms and Side Reactions in Lithium-Ion Batteries J. Electrochem. Soc. 1998, 145, 3647-3667
4. Xu, K. Electrolytes and Interphasial Chemistry in Li Ion Devices Energies 2010, 3, 135-154
5. Peled, E. The Electrochemical Behavior of Alkali and Alkaline Earth Metals in Nonaqueous Battery Systems-The Solid Electrolyte Interphase Model J. Electrochem. Soc. 1979, 126, 2047-2051
6. Aurbach, D.; Ein-Eli, Y.; Chusid, O.; Carmeli, Y.; Babai, M.; Yamin, H. The Correlation between the Surface Chemistry and the Performance of Li-Carbon Intercalation Anodes for Rechargeable 'Rocking-Chair' Type Batteries J. Electrochem. Soc. 1994, 141, 603-611
7. Xu, K. Nonaqueous Liquid Electrolytes for Lithium-Based Rechargeable Batteries Chem. Rev. 2004, 104, 4303-4418
8. Verma, P.; Maire, P.; Novák, P. A Review of the Features and Analyses of the Solid Electrolyte Interphase in Li-Ion Batteries Electrochim. Acta 2010, 55, 6332-6341
9. Matsuoka, O.; Hiwara, A.; Omi, T.; Toriida, M.; Hayashi, T.; Tanaka, C.; Saito, Y.; Ishida, T.; Tan, H.; Ono, S. S.; Yamamoto, S. Ultra-thin Passivating Film Induced by Vinylene Carbonate on Highly Oriented Pyrolytic Graphite Negative Electrode in Lithium-Ion Cell J. Power Sources 2002, 108, 128-138
10. McMillan, R.; Slegr, H.; Shu, Z. X.; Wang, W. Fluoroethylene Carbonate Electrolyte and Its Use in Lithium Ion Batteries with Graphite Anodes J. Power Sources 1999, 81-82, 20-26
11. Zhuang, G. V.; Yang, H.; Ross, P. N.; Xu, K.; Jow, T. R. Lithium Methyl Carbonate as a Reaction Product of Metallic Lithium and Dimethyl Carbonate Electrochem. Solid-State Lett. 2006, 9, A64-A68
12. 6/EC:EMC Electrolyte J. Phys. Chem. B 2005, 109, 17567-17573
13. Xu, K.; Zhuang, G. V.; Allen, J. L.; Lee, U.; Zhang, S. S.; Ross, P. N.; Jow, T. R. Syntheses and Characterization of Lithium Alkyl Mono- and Dicarbonates as Components of Surface Films in Li-Ion Batteries J. Phys. Chem. B 2006, 110, 7708-7719
14. Gireaud, L.; Grugeon, S.; Laruelle, S.; Pilard, S.; Tarascon, J. M. Identification of Li Battery Electrolyte Degradation Products through Direct Synthesis and Characterization of Alkyl Carbonate Salts J. Electrochem. Soc. 2005, 152, A850-A857
15. Gireaud, L.; Grugeon, S.; Pilard, S.; Guenot, P.; Tarascon, J. M.; Laruelle, S. Mass Spectrometry Investigations on Electrolyte Degradation Products for the Development of Nanocomposite Electrodes in Lithium Ion Batteries Anal. Chem. 2006, 78, 3688-3698
16. Gachot, G.; Grugeon, S.; Armand, M.; Pilard, S.; Guenot, P.; Tarascon, J. M.; Laruelle, S. Deciphering the Multi-step Degradation Mechanisms of Carbonate-Based Electrolyte in Li Batteries J. Power Sources 2008, 178, 409-421
17. Andersson, A. M.; Edström, K. Chemical Composition and Morphology of the Elevated Temperature SEI on Graphite J. Electrochem. Soc. 2001, 148, A1100-A1109
18. Sloop, S. E.; Kerr, J. B.; Kinoshita, K. The Role of Li-Ion Battery Electrolyte Reactivity in Performance Decline and Self-Discharge J. Power Sources 2003, 119-121, 330-337
19. Leung, K.; Budzien, J. L. Ab initio Molecular Dynamics Simulations of the Initial Stages of Solid-Electrolyte Interphase Formation on Lithium Ion Battery Graphitic Anodes Phys. Chem. Chem. Phys. 2010, 12, 6583-6586
20. Müller, T.; Flynn, G. W.; Mathauser, A. T.; Teplyakov, A. V. Temperature-Programmed Desorption Studies of n -Alkane Derivatives on Graphite: Desorption Energetics and the Influence of Functional Groups on Adsorbate Self-Assembly Langmuir 2003, 19, 2812-2821
21. Verevkin, S. P.; Toktonov, A. V.; Chernyak, Y.; Schäffner, B.; Börner, A. Vapour Pressure and Enthalpy of Vaporization of Cyclic Alkylene Carbonates Fluid Phase Equilib. 2008, 268, 1-6
22. Campbell, C. T.; Sellers, J. R. V. The Entropies of Adsorbed Molecules J. Am. Chem. Soc. 2012, 134, 18109-18115
23. Hudzik, J. M.; Bozzelli, J. W. Thermochemistry and Bond Dissociation Energies of Ketones J. Phys. Chem. A 2012, 116, 5707-5722
24. Hu, Z. P.; Ignatiev, A. Lithium Adsorption on the Graphite (0001) Surface Phys. Rev. B 1984, 30, 4856-4859
25. Qi, Y.; Guo, H.; Hector, L. G.; Timmons, A. Threefold Increase in the Young's Modulus of Graphite Negative Electrode during Lithium Intercalation J. Electrochem. Soc. 2010, 157, A558-A566
26. + within Liquid Ethylene Carbonate Modell. Simul. Mater. Sci. Eng. 2012, 20, 065004
27. Reddy, V. P.; Smart, M. C.; Chin, K. B.; Ratnakumar, B. V.; Surampudi, S.; Hu, J.; Yan, P.; Surya Prakash, G. K. NMR Spectroscopic, CV, and Conductivity Studies of Propylene Carbonate-Based Electrolytes Containing Various Lithium Salts Electrochem. Solid-State Lett. 2005, 8, A294-A298
28. Anderson, P. A. The Work Function of Lithium Phys. Rev. 1949, 75, 1205-1207
29. Leung, K. Private communication.