Cross coupling between electric and magnetic orders in a multiferroic metal-organic framework

Scientific Reports

Volumn 4, Issue , 2014, Pages

  Tian, Ying ^a   Stroppa, Alessandro ^b   Chai, Yisheng ^a   Yan, Liqin ^a   Wang, Shouguo ^a   Barone, Paolo ^b   Picozzi, Silvia ^b   Sun, Young ^a  

^a INSTITUTE OF PHYSICS   (China)

^b CNR SPIN   (Italy)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 84906225619     PISSN: None     EISSN: 20452322     Source Type: Journal    
DOI: 10.1038/srep06062     Document Type: Article

References (35)

1. Fiebig, M. Revival of the magnetoelectric effect. J. Phys. D-Appl. Phys. 38, R123-R152 (2005). (Pubitemid 41244606)
2. Eerenstein, W., Mathur, N. D. & Scott, J. F. Multiferroic and magnetoelectric materials. Nature 442, 759-765 (2006). (Pubitemid 44261898)
3. Wang, K. F., Liu, J. M. & Ren, Z. F. Multiferroicity: the coupling between magnetic and polarization orders. Adv. Phys. 58, 321-448 (2009).
4. Cheong, S. W. &Mostovoy, M. Multiferroics: amagnetic twist for ferroelectricity. Nat. Mater 6, 13-20 (2007).
5. Spaldin, N. A., Cheong, S. W. & Ramesh, R. Multiferroics: past, present, and future. Phys. Today 63, 38-43 (2010).
6. Sun, Y., Yan, L. Q. & Cong, J. Z. Multiferroics and magnetoelectric effects in charge ordered compounds. Sci. China-Phys. Mech. Astron. 56, 222-231 (2013).
7. Nan, C. W., Bichurin, M. I., Dong, S. X.,Viehland, D.&Srinivasan, G. Multiferroic magnetoelectric composites: historical perspective, status, and future directions. J. Appl. Phys. 103, 35 (2008).
8. Jain, P. et al. Multiferroic behavior associated with an order-disorder hydrogen bonding transition in metal-organic frameworks (MOFs) with the perovskite ABX3 architecture. J. Am. Chem. Soc. 131, 13625-13627 (2009).
9. Rogez, G., Viart, N. & Drillon, M. Multiferroic materials: the attractive approach of metal-organic frameworks (MOFs). Angew. Chem. Int. Ed. Engl. 49, 1921-1923 (2010).
10. Xu, G. C. et al. Coexistence of magnetic and electric orderings in the metalformate frameworks of [NH4][M(HCOO)3]. J. Am. Chem. Soc. 133, 14948-14951 (2011).
11. Canadillas-Delgado, L. et al. The role of order-disorder transitions in the quest for molecular multiferroics: structural and magnetic neutron studies of a mixed valence iron(ii)-iron(iii) formate framework. J. Am. Chem. Soc. 134, 19772-19781 (2012).
12. Yaghi, O. M., Li, G. M. & Li, H. L. Selective binding and removal of guests in a microporous metal-organic framework. Nature 378, 703-706 (1995). (Pubitemid 126647273)
13. Kitagawa, S., Kitaura, R. & Noro, S. Functional porous coordination polymers. Angew. Chem. Int. Ed. 43, 2334-2375 (2004). (Pubitemid 39257732)
14. Cheetham, A. K. & Rao, C. N. R. There's room in the middle. Science 318, 58-59 (2007).
15. Jain, P., Dalal, N. S., Toby, B. H., Kroto, H. W. & Cheetham, A. K. Order-disorder antiferroelectric phase transition in a hybrid inorganic-organic framework with the perovskite architecture. J. Am. Chem. Soc. 130, 10450-10451 (2008).
16. Weng, D. F., Wang, Z. M. & Gao, S. Framework-structured weak ferromagnets. Chem. Soc. Rev. 40, 3157-3181 (2011).
17. Meek, S. T., Greathouse, J. A. & Allendorf, M. D. Metal-organic frameworks: a rapidly growing class of versatile nanoporous materials. Adv. Mater. 23, 249-267 (2011).
18. Zhang, W. & Xiong, R.-G. Ferroelectric metal-organic frameworks. Chem. Rev. 112, 1163-1195 (2012).
19. Lorusso, G. et al. A dense metal-organic framework for enhanced magnetic refrigeration. Adv. Mater. 25, 4653-4656 (2013).
20. Canepa, P., Nijem,N., Chabal, Y. J.&Thonhauser, T. Diffusion of small molecules in metal organic framework materials. Phys. Rev. Lett. 110, 5 (2013).
21. Tian, Y. et al.Quantum tunneling of magnetization in ametal-organic framework. Phys. Rev. Lett. 112, 017202 (2014).
22. Zuluaga, S., Canepa, P., Tan, K., Chabal, Y. J. & Thonhauser, T. Study of vander waals bonding and interactions in metal organic framework materials. J. Phys.: Condes. Matter 26, 15 (2014).
23. Stroppa, A. et al. Electric control of magnetization and interplay between orbital ordering and ferroelectricity in a multiferroic metal-organic framework. Angew. Chem. Int. Ed. 50, 5847-5850 (2011).
24. Fu, D. W. et al. A multiferroic perdeutero metal-organic framework. Angew. Chem. Int. Ed. 50, 11947-11951 (2011).
25. Pardo, E. et al. Multiferroics by rational design: implementing ferroelectricity in molecule-based magnets. Angew. Chem. Int. Ed. 51, 8356-8360 (2012).
26. Zhang, B., Zhang, Y. & Zhu, D. B. [(C2H5)3NH]2Cu2(C2O4)3: a three-dimensional metal-oxalato framework showing structurally related dielectric and magnetic transitions at around 165 k. Dalton Trans. 41, 8509-8511 (2012).
27. Stroppa, A., Barone, P., Jain, P., Perez-Mato, J. M. & Picozzi, S. Hybrid improper ferroelectricity in a multiferroic and magnetoelectric metal-organic framework. Adv. Mater. 25, 2284-2290 (2013).
28. Di Sante, D., Stroppa, A., Jain, P.&Picozzi, S. Tuning the ferroelectric polarization in a multiferroic metal-organic framework. J. Am. Chem. Soc. 135, 18126-18130 (2013).
29. Wang, W. et al. Magnetoelectric coupling in the paramagnetic state of a metalorganic framework. Sci. Rep. 3, 5 (2013).
30. Pato-Doldan, B. et al. Coexistence of magnetic and electrical order in the new perovskite-like (C3N2H5)[Mn(HCOO)3] formate. RSC Adv. 3, 22404-22411 (2013).
31. Kimura, T. et al.Magnetic control of ferroelectric polarization. Nature 426, 55-58 (2003). (Pubitemid 37441280)
32. Hur, N. et al. Electric polarization reversal and memory in a multiferroic material induced by magnetic fields. Nature 429, 392-395 (2004). (Pubitemid 38720172)
33. Besara, T. et al. Mechanism of the order-disorder phase transition, and glassy behavior in the metal-organic framework [(CH3)2NH2]Zn(HCOO)3. Proc. Natl. Acad. Sci. U. S. A. 108, 6828-6832 (2011).
34. Thomson, R. I., Jain, P., Cheetham, A. K. & Carpenter, M. A. Elastic relaxation behavior, magnetoelastic coupling, and order-disorder processes in multiferroic metal-organic frameworks. Phys. Rev. B 86, 214304 (2012).
35. Kundys, B. et al. Multiferroicity and hydrogen-bond ordering in (C2H5NH3)2CuCl4 featuring dominant ferromagnetic interactions. Phys. Rev. B 81, 224434 (2010).