Component dynamics in nanostructured PI-PDMS diblock copolymers with PI segregated in lamellas, cylinders, and spheres

Colloid and Polymer Science

Volumn 292, Issue 8, 2014, Pages 1863-1876

  Alegria, Angel ^a   Lund, Reidar ^a,b   Barroso Bujans, Fabienne ^a,c   Arbe, Arantxa ^a   Colmenero, Juan ^a  

^a UNIVERSITY OF THE BASQUE COUNTRY UPV EHU   (Spain)

^b UNIVERSITY OF OSLO   (Norway)

^c DONOSTIA INTERNATIONAL PHYSICS CENTER DIPC   (Spain)

Author keywords

Block copolymers; Confinement effects; Dielectric relaxation; Nanostructure; Polymer dynamics

Indexed keywords

BLOCK COPOLYMERS; CYLINDERS (SHAPES); DIELECTRIC RELAXATION; DYNAMICS; MICROCHANNELS; NANOSTRUCTURES;

BROAD-BAND DIELECTRIC SPECTROSCOPY; COMPONENT DYNAMICS; CONFINEMENT EFFECTS; NANO-STRUCTURED; POLYDIMETHYLSILOXANE PDMS; POLYMER COMPONENTS; POLYMER DYNAMICS; TEMPERATURE RANGE;

SILICONES;

EID: 84905925140     PISSN: 0303402X     EISSN: 14351536     Source Type: Journal    
DOI: 10.1007/s00396-014-3255-3     Document Type: Article

References (36)

1. Hadjichristidis N, Pispas S, Floudas G (2003) Block copolymers: synthetic strategies, physical properties, and applications. Wiley, Hoboken
2. Bates FS, Fredrickson GH (1990) Block copolymer thermodynamics: theory and experiment. Annu Rev Phys Chem 41(1):525-557
3. Bates FS, Fredrickson GH (1999) Block copolymers - designer soft materials. Phys Today 52(2):32-38 (Pubitemid 129600640)
4. Castelletto V, Hamley IW (2007) Block copolymer melts. In: Mark J (ed) Physical properties of polymers handbook. Springer, New York, pp 641-652
5. Matsen MW, Bates FS (1996) Unifying weak- and strong-segregation block copolymer theories. Macromolecules 29(4):1091-1098
6. Kirkensgaard JJK, Fragouli P, Hadjichristidis N, Mortensen K (2011) Perforated lamellae morphology in novel P2VP(PDMS-b-PI-b-PS)2 3-miktoarm star quarterpolymer. Macromolecules 44(3):575-582
7. Meuler AJ, Hillmyer MA, Bates FS (2009) Ordered network mesostructures in block polymer materials. Macromolecules 42(19):7221-7250
8. Yamauchi K, Hasegawa H, Hashimoto T, Tanaka H, Motokawa R, Koizumi S (2006) Direct observation of polymerization-reaction-induced molecular self-assembling process: in-situ and real-time SANS measurements during living anionic polymerization of polyisoprene-block-polystyrene. Macromolecules 39(13):4531-4539 (Pubitemid 44114084)
9. Mori K, Hasegawa H, Hashimoto T (2001) Order-disorder transition of polystyrene-block-polyisoprene part II. Characteristic length as a function of polymer concentration, molecular weight, copolymer composition, and χ parameter. Polymer 42(7):3009-3021 (Pubitemid 32110050)
10. Kimishima K, Koga T, Hashimoto T (2000) Order-order phase transition between spherical and cylindrical microdomain structures of block copolymer. I. Mech Transit Macromol 33(3):968-977 (Pubitemid 30563069)
11. Frielinghaus H, Hermsdorf N, Almdal K, Mortensen K, Messé L, Corvazier L, Fairclough JPA, Ryan AJ, Olmsted PD, Hamley IW (2001) Micro- vs. macro-phase separation in binary blends of poly(-styrene)-poly(isoprene) and poly(isoprene)-poly(ethylene oxide) diblock copolymers. Europhys Lett 53(5):680
12. Almdal K, Mortensen K, Ryan AJ, Bates FS (1996) Order, disorder, and composition fluctuation effects in low molar mass hydrocarbon- poly(dimethylsiloxane) diblock copolymers. Macromolecules 29(18):5940-5947 (Pubitemid 126520478)
13. Vigild ME (1997) Mesomorphic phase behaviour of low molar mass PEP-PDMS diblock copolymers synthesized by anionic polymerization. Ph.D. thesis, Risø National Laboratory, Roskilde, Denmark
14. Cochran EW, Morse DC, Bates FS (2003) Design of ABC triblock copolymers near the ODT with the random phase approximation. Macromolecules 36(3):782-792
15. Sanz A, Nogales A, Ezquerra TA (2011) From hard to soft confinement in a symmetric block copolymer: local and segmental dynamics. Soft Matter 7(14):6477-6483
16. Lund R, Willner L, Alegría A, Colmenero J, Richter D (2008) Self-concentration and interfacial fluctuation effects on the local segmental dynamics of nanostructured diblock copolymer melts. Macromolecules 41(3):511-514 (Pubitemid 351294453)
17. Willner L, Lund R, Monkenbusch M, Holderer O, Colmenero J, Richter D (2010) Polymer dynamics under soft confinement in a self-assembled system. Soft Matter 6(7):1559-1570
18. Lund R, Barroso-Bujans F, Slimani MZ, Moreno AJ, Willner L, Richter D, Alegría A, Colmenero J (2013) End-to-end vector dynamics of nonentangled polymers in lamellar block copolymer melts: the role of junction point motion. Macromolecules 46(18):7477-7487
19. Havriliak S Jr, Havriliak SJ (1996) Comparison of the Havriliak-Negami and stretched exponential functions. Polymer 37(18):4107-4110
20. Kremer F, Schönhals A (2003) Broadband dielectric spectroscopy. Springer, Berlin, Heidelberg, New York, Germany
21. Förster S, Timmann A, Konrad M, Schellbach C, Meyer A, Funari SS, Mulvaney P, Knott R (2005) Scattering curves of ordered mesoscopic materials. J Phys Chem B 109(4):1347-1360 (Pubitemid 40212515)
22. Rheological measurements were performed in an ARES rotational rheometer, TA Instruments, using an oscillation frequency of 1 Hz, strain amplitude of 2% and temperature sweep at 3 K/min. The measuring geometry was plate/plate with a diameter of 25 mm and a sample thickness of 1 mm. Nitrogen atmosphere was used during the whole experiments
23. Chang K, Macosko CW, Morse DC (2007) Ultralow interfacial tensions of polymer/polymer interfaces with diblock copolymer surfactants. Macromolecules 40(10):3819-3830 (Pubitemid 46841945)
24. Leibler L (1980) Theory of microphase separation in block copolymers. Macromolecules 13(6):1602-1617
25. Fredrickson GH, Helfand E (1987) Fluctuation effects in the theory of microphase separation in block copolymers. J Chem Phys 87(1):697-705
26. Rubinstein M, Colby RH (2003) Polymer physics. Oxford University Press, Oxford
27. Ding Y, Kisliuk A, Sokolov AP (2004) When does a molecule become a polymer? Macromolecules 37(1):161-166
28. Lorthioir C, Alegría A, Colmenero J, Deloche B (2004) Heterogeneity of the segmental dynamics of poly(dimethylsiloxane) in a diblock lamellar mesophase: dielectric relaxation investigations. Macromolecules 37(20):7808-7817
29. del Valle-Carrandi L, Alegría A, Arbe A, Colmenero J (2011) Unexpected PDMS behavior in segregated cylindrical and spherical nanophases of PS - PDMS asymmetric diblock copolymers. Macromolecules 45(1):491-502
30. Lund R, Alegria A, Goitandia L, Colmenero J, Gonzalez MA, Lindner P (2008) Dynamical and structural aspects of the cold crystallization of poly(dimethylsiloxane) (PDMS). Macromolecules 41(4):1364-1376 (Pubitemid 351363142)
31. Vogel H (1921) Das Temperaturabhängigkeitsgesetz der Viskosität von Flüssigkeiten. In: Physik. Zeitschrift, vol 22. pp 645-646
32. Angell CA (1991) Relaxation in liquids, polymers and plastic crystals - strong/fragile patterns and problems. J Non-Cryst Solids 131-133(Part 1):13-31
33. Solar M, Mapesa EU, Kremer F, Binder K, Paul W (2013) The dielectric α -relaxation in polymer films: a comparison between experiments and atomistic simulations. Europhys Lett 104(6):66004
34. Helfand E, Tagami Y (1972) Theory of the interface between immiscible polymers. II. J Chem Phys 56(7):3592-3601
35. Ferry JD (1980) Viscoelastic properties of polymers, 3rd edn. Wiley, New York
36. Riedel C, Alegría A, Tordjeman P, Colmenero J (2009) Rouse-model-based description of the dielectric relaxation of nonentangled linear 1,4-cis-polyisoprene. Macromolecules 42(21):8492-8499