Microstructure and electrical properties of Mn1+xCo 2-xO4 (0 ≤ x ≤ 1.5) spinels synthesized using EDTA-gel processes

Ceramics International

Volumn 40, Issue 9 PART A, 2014, Pages 13873-13882

  Brylewski, T ^a   Kucza, W ^a   Adamczyk, A ^a   Kruk, A ^a   Stygar, M ^a   Bobruk, M ^a   Dabrowa J ^a  

^a AGH UNIVERSITY OF SCIENCE AND TECHNOLOGY   (Poland)

Author keywords

C. Electrical conductivity; Cobalt manganese ceramics; D. Spinels; Metallic interconnects; Solid Oxide Fuel Cell (SOFC)

Indexed keywords

COBALT; CONDUCTIVE FILMS; ELECTRIC CONDUCTIVITY; MANGANESE;

D. SPINELS; ELECTRICAL CONDUCTIVITY; FERRITIC STAINLESS STEEL; INCREASING TEMPERATURES; INTERMEDIATE TEMPERATURE SOLID OXIDE FUEL CELL; METALLIC INTERCONNECTS; SPINEL SOLID SOLUTIONS; WIDE TEMPERATURE RANGES;

SOLID OXIDE FUEL CELLS (SOFC);

EID: 84905913541     PISSN: 02728842     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ceramint.2014.05.106     Document Type: Article

References (44)

1. J.W. Fergus Metallic interconnects for solid oxide fuel cells Mater. Sci. Eng. A 397 2005 271 283
2. W.J. Quadakkers, J. Piron-Abellan, V. Shemet, and L. Singheiser Metallic interconnectors for solid oxide fuel cells - a review Mater. High Temp. 20 2003 115 127
3. Z. Yang, K.S. Weil, D.M. Paxton, and J.W. Stevenson Selection and evaluation of heat-resistance alloys for SOFC interconnect applications J. Electrochem. Soc. 150 2003 A1188 A1201
4. T. Brylewski, M. Nanko, T. Maruyama, and K. Przybylski Application of Fe-16Cr ferritic alloy to interconnector for a solid oxide fuel cell Solid State Ion. 143 2001 131 140
5. Z.-Y. Chen, L.-J. Wang, F.-S. Li, and K.-C. Chou Oxidation mechanism of Fe-16Cr alloy as SOFC interconnect in dry/wet air J. Alloys Compd. 574 2013 437 442
6. A.W.B. Skilbred, and R. Haugsrud The effect of water vapour on the corrosion of Sandvik Sanergy HT under dual atmosphere conditions Oxid. Met. 79 2013 639 654
7. K. Hilpert, D. Das, M. Miller, D.H. Peck, and R. Weiβ Chromium vapor species over solid oxide fuel cell interconnect materials and their potential for degradation processes J. Electrochem. Soc. 143 1996 3642 3647
8. H. Kurokawa, C.P. Jacobson, L.C. DeJonghe, and S. Visco Chromium vaporization of bare and of coated iron-chromium alloys at 1073 K Solid State Ion. 178 2007 287 296
9. N. Shaigan, W. Qu, D.G. Ivey, and W. Chen A review of recent progress in coatings, surface modifications and alloy developments for solid oxide fuel cell ferritic stainless steel interconnects J. Power Sources 195 2010 1529 1542
10. X. Chen, P.Y. Hou, C.P. Jacobson, S.J. Visco, and L.C.D. Jonghe Protective coating on stainless steel interconnect for SOFCs: oxidation kinetics and electrical properties Solid State Ion. 176 2005 425 433
11. B. Hua, J. Pu, W. Gong, J. Zhang, F. Lu, and L. Jian Cyclic oxidation of Mn-Co spinel coated SUS 430 alloy in the cathodic atmosphere of solid oxide fuel cells J. Power Sources 185 2008 419 422
12. Z. Yang, G. Xia, S.P. Simner, and J.W. Stevenson Thermal growth and performance of manganese cobaltite spinel protection layers on ferritic stainless steel SOFC interconnects J. Electrochem. Soc. 152 2005 A1896 A1901
13. 4 spinel coatings on ferritic stainless steels for SOFC interconnect applications Int. J. Hydrog. Energy 32 2007 3648 3654
14. 4: influence of the calcination temperature Ceram. Int. 40 2014 7185 7193
15. Z. Yang, G.-G. Xia, G.D. Maupin, and J.W. Stevenson Conductive protection layers on oxidation resistant alloys for SOFC interconnect applications Surf. Coat. Technol. 201 2006 4476 4483
16. P.E. Gannon, V.I. Gorokhovsky, M.C. Deibert, R.J. Smith, A. Kayani, P.T. White, S. Sofie, Z. Yang, D. McCready, S. Visco, C. Jacobson, and H. Kurokawa Enabling inexpensive metallic alloys as SOFC interconnects: an investigation into hybrid coating technologies to deposit nanocomposite functional coatings on ferritic stainless steels Int. J. Hydrog. Energy 32 2007 3672 3681
17. 4 spinel protection layers on ferritic stainless steels for SOFC interconnect applications Electrochem. Solid-State Lett. 8 2005 A168 A170
18. 3 cathode materials for solid oxide fuel cells J. Electrochem. Soc. 147 2000 3251 3256
19. Z. Yang, G.-G. Xia, P. Singh, and J.W. Stevenson Electrical contacts between cathodes and metallic interconnects in solid oxide fuel cells J. Power Sources 155 2006 246 252
20. 4 spinel protection layers for SOFC interconnects Adv. Solid Oxide Fuel Cells II: Ceram. Eng. Sci. Proc. 27 4 2007 231 240
21. A. Petric, and H. Ling Electrical conductivity and thermal expansion of spinels at elevated temperatures J. Am. Ceram. Soc. 90 2007 1515 1520
22. E. Aukrust, and A. Muan Phase relations in the system cobalt oxide-manganese oxide in air J. Am. Ceram. Soc. 46 1963 511
23. M. Lenglet, and B. Lefez Infrared optical properties of cobalt(II) spinels Solid State Commun. 98 1996 689 694
24. 4 Miner. Petrol. 37 1987 15 23
25. 4 sintered classically and by spark plasma sintering (SPS) J. Solid State Chem. 182 2009 396 401
26. 4 (0≤x≤3) dense ceramics using neutron diffraction data Solid State Sci. 12 2010 379 386
27. 4 (1.4
28. 4 (0≤x≤1) determined by thermal analysis J. Therm. Anal. Calorim. 101 2010 137 142
29. 4 system J. Mater. Sci. 7 1972 441 444
30. 4 (0≤x≤3) ceramics: an interesting system for negative temperature coefficient thermistors Int. J. Appl. Ceram. Technol. 10 2013 175 185
31. B.T. Kolomiets, J. Sheftel, and E. Kurlina Electrical properties of some compound oxide semiconductors Sov. Phys. Tech. Phys. 2 1957 40 58
32. D.G. Wickham, and W.J. Croft Crystallographic and magnetic properties of several spinels containing trivalent ja-1044 manganese J. Phys. Chem. Solids 7 1958 351 360
33. E.H. Jabry, A. Rousset, and A. Lagrange Preparation and characterization of manganese and cobalt based semiconducting ceramics Phase Transform. 13 1988 63 71
34. 4 system Electrochem. Acta 44 1998 1491 1497
35. T. Brylewski, A. Kruk, A. Adamczyk, W. Kucza, M. Stygar, and K. Przybylski Synthesis and characterization of the manganese cobaltite spinel prepared using two soft chemical methods Mater. Chem. Phys. 137 2012 310 316
36. K.S. Irani, A.P.B. Sinha, and A.B. Biswas Effect of temperature on the structure of manganites J. Phys. Chem. Solids 23 1962 711 727
37. M. Kakihana Sol-gel preparation of high temperature superconducting oxides J. Sol-Gel Sci. Technol. 6 1996 7 55
38. S. Chevalier, G. Caboche, K. Przybylski, and T. Brylewski Effect of nano-layered coatings on the electrical conductivity of oxide scale grown on ferritic steels J. Appl. Electrochem. 39 2009 529 534
39. R.D. Shannon Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides Acta Crystallogr. A 32 1976 751 767
40. W.F. Wei, W.X. Chen, and D.G. Ivey Rock salt-spinel structural transformation in anodically electrodeposited Mn-Co-O nanocrystals Chem. Mater. 20 2008 1941 1947
41. E.J.W. Verwey Semiconducting Materials 1951 Butterworths, Scientific Publications London
42. Z. Lu, J. Zhu, E.A. Payzant, and M.P. Paranthaman Electrical conductivity of the manganese chromite spinel solid solution J. Am. Ceram. Soc. 88 2005 1050 1053
43. E.D. Macklen Electric conductivity and cation distribution in nickel manganite J. Phys. Chem. Solids 47 1986 1073 1079
44. 4 J. Am. Ceram. Soc. 71 1988 379 385