Kinetics and particle size control in non-stirred precipitation polymerization of N-isopropylacrylamide

Colloid and Polymer Science

Volumn 292, Issue 8, 2014, Pages 1743-1756

  Virtanen, O L J ^a   Richtering, W ^a  

^a RWTH AACHEN UNIVERSITY   (Germany)

Author keywords

Kinetics; Microgels; N isopropylacrylamide; Particle size; Precipitation polymerization

Indexed keywords

ACRYLIC MONOMERS; ENZYME KINETICS; GELS; KINETICS; PARTICLE SIZE; POLYMERIZATION; SYNTHESIS (CHEMICAL);

INITIATOR CONCENTRATION; LOW TEMPERATURE SYNTHESIS; MICRO-GELS; N-ISOPROPYLACRYLAMIDES; POLY(N-ISOPROPYLACRYLAMIDE) MICROGELS; POLYMERIZATION KINETICS; PRECIPITATION POLYMERIZATIONS; TEMPERATURE-SENSITIVE;

REACTION KINETICS;

EID: 84905906070     PISSN: 0303402X     EISSN: 14351536     Source Type: Journal    
DOI: 10.1007/s00396-014-3208-x     Document Type: Article

References (38)

1. Pelton RH, Chibante P (1986) Preparation of aqueous lattices with N-isopropylacrylamide. Colloids Surf 20:247-256
2. Meyer S, Richtering W (2005) Influence of polymerization conditions on the structure of temperature-sensitive poly(N-isopropylacrylamide) microgels. Macromolecules 38:1517-1519 (Pubitemid 40308217)
3. Still T, Chen K, Alsayed AM et al (2013) Synthesis of micrometersize poly(N-isopropylacrylamide) microgel particles with homogeneous crosslinker density and diameter control. J Colloid Interf Sci 405:96-102
4. Meng Z, Smith MH, Lyon LA (2009) Temperature-programmed synthesis of micron-sized multi-responsive microgels. Colloid Polym Sci 287:277-285
5. Wiese S, Spiess AC, Richtering W (2012) Microgel-stabilized smart emulsions for biocatalysis. Angew Chem Int Ed 52:576-579
6. Kiser PF, Wilson G, Needham D (2000) Lipid-coated microgels for the triggered release of doxorubicin. J Control Release 68:9-22 (Pubitemid 30407058)
7. Hervás Pérez JP, Sánchez-Paniagua López M, López-Cabarcos E, López-Ruiz B (2006) Amperometric tyrosinase biosensor based on polyacrylamide microgels. Biosens Bioelectron 22:429-439
8. Serpe MJ, Kim J, Lyon LA (2004) Colloidal hydrogel microlenses. Adv Mater 16:184-187
9. Schild HG (1992) Poly(N-isopropylacrylamide): experiment, theory and application. Prog Polym Sci 17:163-249
10. Gao J, Frisken BJ (2005) Influence of secondary components on the synthesis of self-cross-linked N-isopropylacrylamide microgels. Langmuir 21:545-551 (Pubitemid 40168838)
11. Pelton R (2000) Temperature-sensitive aqueous microgels. Adv Colloid Interf 85:1-33
12. Pich A, Richtering W (2010) Microgels by precipitation polymerization: synthesis, characterization and functionalization. Adv Polym Sci 234:1-37
13. Pelton RH, Pelton HM, Morphesis A, Rowell RL (1989) Particle sizes and electrophoretic mobilities of poly(N-isopropylacrylamide) latex. Langmuir 5:816-818
14. McPhee W, Tam KC, Pelton R (1993) Poly(N-isopropylacrylamide) latices preparedwith sodiumdodecyl sulfate. J Colloid Interf Sci 156:24-30
15. Tam KC, Ragaram S, Pelton RH (1994) Interaction of surfactants with poly(N-isopropylacrylamide) microgel latexes. Langmuir 10:418-422
16. Wu X, Pelton RH, Hamielec AE et al (1994) The kinetics of poly(N-isopropylacrylamide) microgel latex formation. Colloid Polym Sci 272:467-477
17. Acciaro R, Gilányi T, Varga I (2011) Preparation of monodisperse poly(N-isopropylacrylamide) microgel particles with homogenous cross-link density distribution. Langmuir 27:7917-7925
18. Duracher D, Elaissari A, Pichot C (1999) Preparation of poly(N-isopropylmethacrylamide) latexes Kinetic studies and characterization. J Polym Sci A1(37):1823-1837
19. Flory PJ (1953) Principles of polymer chemistry. Cornell University, New York
20. Smith WV, Ewart RH (1948) Kinetics of emulsion polymerization. J Chem Phys 16:592-599
21. Thomas WM, Pellon JJ (1954) Kinetics of acrylonitrile polymerization in bulk. J Polym Sci 13:329-353
22. Ueda M, Shouji S, Ogata T et al (1984) Radical-initiated homo-and copolymerization of α-fluoroacrylamide "living" radicals in a homogeneous system. Macromolecules 17:2800-2804
23. Sato T, Miyamoto J, Otsu T (1984) Long-lived polymer radicals. VI. Polymerization of N-methylmethacrylamide with formation of living propagation radicals. J Polym Sci A1 22(12):3921-3932
24. Pelton RH (2010) Poly(N-isopropylacrylamide) (PNIPAM) is never hydrophobic. J Colloid Interf Sci 348:673-674
25. Stieger M, Pedersen JS, Richtering W, Lindner P (2004) Small-angle neutron scattering study of structural changes in temperature sensitive microgel colloids. J Chem Phys 120:6197-6206
26. Burchard W, Richtering W (1989) Dynamic light scattering from polymer solutions. Prog Coll Pol Sci S 80:151-163
27. Lindner P, Zemb T (2002) Neutrons, X-rays and light: scattering methods applied to soft condensed matter. North Holland Delta Series, Amsterdam
28. Hansen J, Maier D, Honerkamp J et al (1999) Size distributions out of static light scattering: inclusion of distortions from the experimental setup, e.g., a SOFICA-type goniometer. J Colloid Interf Sci 215:72-84 (Pubitemid 29394538)
29. Pusey PN (1991) Colloidal suspensions. In: Hansen JP, Levesque D, Zinn-Justin J (eds) Liquids, freezing and glass transition. Elsevier, Amsterdam, pp 763-942
30. Evans DF, Wennerström H (1999) The colloidal domain: where physics, chemistry, biology, and technology meet, 2nd edn. Wiley, New Jersey
31. Rubinstein M, Colby RH (2003) Polymer physics. Oxford University Press, New York
32. Burchard W, Schmidt M, Stockmayer WH (1980) Information on polydispersity and branching from combined quasi-elastic and intergrated scattering. Macromolecules 13:1265-1272
33. Burchard W, Ross-Murphy S (1994) Physical Techniques for the Study of Food Biopolymers. Edited by SB Ross Murphy. Blackie Academic, Glasgow
34. Senff H, Richtering W (2000) Influence of cross-link density on rheological properties of temperature-sensitive microgel suspensions. Colloid Polym Sci 278:830-840
35. Schätzel K (1991) Suppression of multiple scattering by photon cross-correlation techniques. J Mod Optic 38:1849-1865
36. Odian G (2004) Principles of polymerization, 4th edn. Wiley, New Jersey
37. Privman V, Goia D, Park J, Matijevi cacute E (1999) Mechanism of formation of monodispersed colloids by aggregation of nanosize precursors. J Colloid Interf Sci 213:36-45 (Pubitemid 29394399)
38. Feeney PJ, Napper DH, Gilbert RG (1984) Coagulative nucleation and particle size distributions in emulsion polymerization. Macromolecules 17:2520-2529