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Angewandte Chemie - International Edition

Volumn 53, Issue 33, 2014, Pages 8700-8704

Rationalization of an unusual solvent-induced inversion of enantiomeric excess in organocatalytic selenylation of aldehydes

(4) Burés, Jordi a,b Dingwall, Paul b Armstrong, Alan b Blackmond, Donna G a,b

a SCRIPPS RESEARCH INSTITUTE (United States)

b IMPERIAL COLLEGE LONDON (United Kingdom)

Author keywords

enantioselectivity; kinetics; organocatalysis; reaction mechanisms; solvent effects

Indexed keywords

ALDEHYDES; CATALYSIS; ENZYME KINETICS; RATE CONSTANTS; REACTION KINETICS; SOLVENTS;

BOND-FORMING STEP; CATALYTIC CYCLES; ENANTIOMERIC EXCESS; ORGANOCATALYSIS; ORGANOCATALYTIC; REACTION MECHANISM; SILYL ETHERS; SOLVENT EFFECTS;

ENANTIOSELECTIVITY;

EID: 84905870016 PISSN: 14337851 EISSN: 15213773 Source Type: Journal
DOI: 10.1002/anie.201404327 Document Type: Article

Times cited : (34)

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