Influence of step geometry on the reconstruction of stepped platinum surfaces under coadsorption of ethylene and CO

Journal of Physical Chemistry Letters

Volumn 5, Issue 15, 2014, Pages 2626-2631

  Zhu, Zhongwei ^a,b   Barroo, Cédric ^b,c   Lichtenstein, Leonid ^c   Eren, Baran ^c   Wu, Cheng Hao ^a,c   Mao, Baohua ^b,c   Visart De Bocarmé, Thierry ^d   Liu, Zhi ^b,c,e   Kruse, Norbert ^c,e   Salmeron, Miquel ^b,f   Somorjai, Gabor A ^a,b  

^a UNIVERSITY OF CALIFORNIA   (United States)

^b LAWRENCE BERKELEY NATIONAL LABORATORY   (United States)

^c UNIVERSITÉ LIBRE DE BRUXELLES   (Belgium)

^d SHANGHAITECH UNIVERSITY   (China)

^e Washington State University   (United States)

^f University of California Berkeley   (United States)

Author keywords

ambient pressure X ray photoelectron spectroscopy; high pressure scanning tunneling microscopy; platinum; step orientation; surface reconstruction

Indexed keywords

ADSORBATES; ETHYLENE; SCANNING TUNNELING MICROSCOPY; SURFACE RECONSTRUCTION; X RAY PHOTOELECTRON SPECTROSCOPY;

AMBIENT-PRESSURE X-RAY PHOTOELECTRON SPECTROSCOPIES; ATOMIC ARRANGEMENT; CLUSTER STRUCTURE; DIFFERENT SHAPES; HIGH-PRESSURE SCANNING TUNNELING MICROSCOPIES; RESTRUCTURING PROCESS; STEPPED PLATINUM SURFACE; TORR PRESSURE RANGES;

PLATINUM;

EID: 84905718023     PISSN: None     EISSN: 19487185     Source Type: Journal    
DOI: 10.1021/jz501341r     Document Type: Article

References (44)

1. Somorjai, G. A.; Li, Y. Introduction to Surface Chemistry and Catalysis, 2 nd ed.; John Wiley & Sons, Inc.: Hoboken, NJ, 2010.
2. Vattuone, L.; Savio, L.; Rocca, M. Bridging the Structure Gap: Chemistry of Nanostructured Surfaces at Well-Defined Defects Surf. Sci. Rep. 2008, 63, 101-168
3. Yates, J. J. T. Surface Chemistry at Metallic Step Defect Sites J. Vac. Sci. Technol., A 1995, 13, 1359-1367
4. Abild-Pedersen, F.; Lytken, O.; Engbæk, J.; Nielsen, G.; Chorkendorff, I.; Nørskov, J. K. Methane Activation on Ni(111): Effects of Poisons and Step Defects Surf. Sci. 2005, 590, 127-137
5. Kim, J.; Samano, E.; Koel, B. E. CO Adsorption and Reaction on Clean and Oxygen-Covered Au(211) Surfaces J. Phys. Chem. B 2006, 110, 17512-17517
6. 2 Adsorption on Pt(533): Step Mediated Molecular Chemisorption and Dissociation J. Chem. Phys. 2000, 113, 10333-10343
7. Vang, R. T.; Honkala, K.; Dahl, S.; Vestergaard, E. K.; Schnadt, J.; Lægsgaard, E.; Clausen, B. S.; Nørskov, J. K.; Besenbacher, F. Controlling the Catalytic Bond-Breaking Selectivity of Ni Surfaces by Step Blocking Nat. Mater. 2005, 4, 160-162
8. Zambelli, T.; Wintterlin, J.; Trost, J.; Ertl, G. Identification of the "Active Sites" of a Surface-Catalyzed Reaction Science 1996, 273, 1688-1690
9. Nørskov, J. K.; Bligaard, T.; Hvolbæk, B.; Abild-Pedersen, F.; Chorkendorff, I.; Christensen, C. H. The Nature of the Active Site in Heterogeneous Metal Catalysis Chem. Soc. Rev. 2008, 37, 2163-2171
10. Gee, A. T.; Hayden, B. E.; Mormiche, C.; Kleyn, A. W.; Riedmuller, B. The Dynamics of the Dissociative Adsorption of Methane on Pt(533) J. Chem. Phys. 2003, 118, 3334-3341
11. Xu, J.; Henriksen, P.; Yates, J. J. T. Direct Spectroscopic Observation of the Reactive Catalytic Site for CO Oxidation on Pt(335) J. Chem. Phys. 1992, 97, 5250-5252
12. Hendriksen, B. L. M.; Ackermann, M. D.; van Rijn, R.; Stoltz, D.; Popa, I.; Balmes, O.; Resta, A.; Wermeille, D.; Felici, R.; Ferrer, S. The Role of Steps in Surface Catalysis and Reaction Oscillations Nat. Chem. 2010, 2, 730-734
13. -5 Torr J. Phys. Chem. B 2005, 109, 21847-21857
14. Bernasek, S. L.; Siekhaus, W. J.; Somorjai, G. A. Molecular-Beam Study of Hydrogen-Deuterium Exchange on Low- and High-Miller-Index Platinum Single-Crystal Surfaces Phys. Rev. Lett. 1973, 30, 1202-1204
15. 2 Exchange Reaction on Pt(111) and Pt(332) Crystal Surfaces J. Chem. Phys. 1979, 70, 2807-2818
16. 2 Molecular Beam Phys. Rev. B 2007, 75, 233413
17. Zhu, Z.; Tao, F.; Zheng, F.; Chang, R.; Li, Y.; Heinke, L.; Liu, Z.; Salmeron, M.; Somorjai, G. A. Formation of Nanometer-Sized Surface Platinum Oxide Clusters on a Stepped Pt(557) Single Crystal Surface Induced by Oxygen: A High-Pressure STM and Ambient-Pressure XPS Study Nano Lett. 2012, 12, 1491-1497
18. 2 Activation on Ru(0001) Phys. Rev. Lett. 1999, 83, 1814-1817
19. Kuzume, A.; Herrero, E.; Feliu, J. M. Oxygen Reduction on Stepped Platinum Surfaces in Acidic Media J. Electroanal. Chem. 2007, 599, 333-343
20. Spendelow, J. S.; Xu, Q.; Goodpaster, J. D.; Kenis, P. J. A.; Wieckowski, A. The Role of Surface Defects in CO Oxidation, Methanol Oxidation, and Oxygen Reduction on Pt(111) J. Electrochem. Soc. 2007, 154, F238-F242
21. Tao, F.; Dag, S.; Wang, L. W.; Liu, Z.; Butcher, D. R.; Bluhm, H.; Salmeron, M.; Somorjai, G. A. Break-Up of Stepped Platinum Catalyst Surfaces by High CO Coverage Science 2010, 327, 850-853
22. Hahn, E.; Schief, H.; Marsico, V.; Fricke, A.; Kern, K. Orientational Instability of Vicinal Pt Surfaces Close to (111) Phys. Rev. Lett. 1994, 72, 3378-3381
23. Sander, M.; Imbihl, R.; Schuster, R.; Barth, J. V.; Ertl, G. Microfacetting of Pt(210) Induced by Oxygen-Adsorption and by Catalytic Co Oxidation Surf. Sci. 1992, 271, 159-169
24. Visart de Bocarmé, T.; Bär, T.; Kruse, N. Field Ion Microscopy Study of the Structural Changes in Rh Crystals during the Reaction of Oxygen-Hydrogen Gas Mixtures Surf. Sci. 2000, 454-456, 320-325
25. Medvedev, V. K.; Suchorski, Y.; Voss, C.; Visart de Bocarmé, T.; Bär, T.; Kruse, N. Oxygen-Induced Reconstruction and Surface Oxidation of Rhodium Langmuir 1998, 14, 6151-6157
26. Van Hove, M. A.; Somorjai, G. A. A New Microfacet Notation for High-Miller-Index Surfaces of Cubic Materials with Terrace, Step and Kink Structures Surf. Sci. 1980, 92, 489-518
27. Klikovits, J.; Schmid, M.; Merte, L. R.; Varga, P.; Westerström, R.; Resta, A.; Andersen, J. N.; Gustafson, J.; Mikkelsen, A.; Lundgren, E. Step-Orientation-Dependent Oxidation: From 1D to 2D Oxides Phys. Rev. Lett. 2008, 101, 266104
28. Chen, P.; Kung, K. Y.; Shen, Y. R.; Somorjai, G. A. Sum Frequency Generation Spectroscopic Study of CO/Ethylene Coadsorption on the Pt(111) Surface and CO Poisoning of Catalytic Ethylene Hydrogenation Surf. Sci. 2001, 494, 289-297
29. 2 Catalyst: Ambiguities in the Interpretation of Difference Spectra Surf. Sci. 1999, 437, 9-17
30. Rioux, R. M.; Hoefelmeyer, J. D.; Grass, M.; Song, H.; Niesz, K.; Yang, P.; Somorjai, G. A. Adsorption and Co-adsorption of Ethylene and Carbon Monoxide on Silica-Supported Monodisperse Pt Nanoparticles: Volumetric Adsorption and Infrared Spectroscopy Studies Langmuir 2007, 24, 198-207
31. Lundwall, M. J.; McClure, S. M.; Goodman, D. W. Probing Terrace and Step Sites on Pt Nanoparticles Using CO and Ethylene J. Phys. Chem. C 2010, 114, 7904-7912
32. Tang, D. C.; Hwang, K. S.; Salmeron, M.; Somorjai, G. A. High Pressure Scanning Tunneling Microscopy Study of CO Poisoning of Ethylene Hydrogenation on Pt(111) and Rh(111) Single Crystals J. Phys. Chem. B 2004, 108, 13300-13306
33. Tao, F.; Tang, D. C.; Salmeron, M.; Somorjai, G. A. A New Scanning Tunneling Microscope Reactor Used for High-Pressure and High-Temperature Catalysis Studies Rev. Sci. Instrum. 2008, 79, 084101
34. Grass, M. E.; Karlsson, P. G.; Aksoy, F.; Lundqvist, M.; Wannberg, B.; Mun, B. S.; Hussain, Z.; Liu, Z. New Ambient Pressure Photoemission Endstation at Advanced Light Source Beamline 9.3.2 Rev. Sci. Instrum. 2010, 81, 053106
35. Longwitz, S. R.; Schnadt, J.; Vestergaard, E. K.; Vang, R. T.; Lægsgaard, E.; Stensgaard, I.; Brune, H.; Besenbacher, F. High-Coverage Structures of Carbon Monoxide Adsorbed on Pt(111) Studied by High-Pressure Scanning Tunneling Microscopy J. Phys. Chem. B 2004, 108, 14497-14502
36. Land, T. A.; Michely, T.; Behm, R. J.; Hemminger, J. C.; Comsa, G. Direct Observation of Surface Reactions by Scanning Tunneling Microscopy: Ethylene → Ethylidyne → Carbon Particles → Graphite on Pt(111) J. Chem. Phys. 1992, 97, 6774-6783
37. Norton, P. R.; Goodale, J. W.; Selkirk, E. B. Adsorption of CO on Pt(111) Studied by Photoemission, Thermal Desorption Spectroscopy and High Resolution Dynamic Measurements of Work Function Surf. Sci. 1979, 83, 189-227
38. Montano, M.; Bratlie, K. M.; Salmeron, M.; Somorjai, G. A. Hydrogen and Deuterium Exchange on Pt(111) and Its Poisoning by Carbon Monoxide Studied by Surface Sensitive High-Pressure Techniques J. Am. Chem. Soc. 2006, 128, 13229-13234
39. Freyer, N.; Pirug, G.; Bonzel, H. P. C(1s) Spectroscopy of Hydrocarbons Adsorbed on Pt(111) Surf. Sci. 1983, 126, 487-494
40. Zhu, Z.; Butcher, D. R.; Mao, B.; Liu, Z.; Salmeron, M.; Somorjai, G. A. In Situ Scanning Tunneling Microscopy and X-ray Photoelectron Spectroscopy Studies of Ethylene-Induced Structural Changes on the Pt(100)-hex Surface J. Phys. Chem. C 2013, 117, 2799-2804
41. Brown, W. A.; Kose, R.; King, D. A. Calorimetric Measurements of the Adsorption Heat for Ethene on Pt(211) and Pt(311) Surf. Sci. 1999, 440, 271-278
42. Ertl, G.; Neumann, M.; Streit, K. M. Chemisorption of CO on the Pt(111) Surface Surf. Sci. 1977, 64, 393-410
43. Axnanda, S.; Scheele, M.; Crumlin, E.; Mao, B.; Chang, R.; Rani, S.; Faiz, M.; Wang, S.; Alivisatos, A. P.; Liu, Z. Direct Work Function Measurement by Gas Phase Photoelectron Spectroscopy and Its Application on PbS Nanoparticles Nano Lett. 2013, 13, 6176-6182
44. Illas, F.; Zurita, S.; Rubio, J.; Márquez, A. M. Origin of the Vibrational Shift of CO Chemisorbed on Pt(111) Phys. Rev. B 1995, 52, 12372-12379