A mechanistic study on the reaction pathways leading to benzene and naphthalene in cellulose vapor phase cracking

Biomass and Bioenergy

Volumn 69, Issue , 2014, Pages 144-154

  Norinaga, Koyo ^a   Yang, Huamei ^a   Tanaka, Ryota ^a   Appari, Srinivas ^a   Iwanaga, Keita ^a   Takashima, Yuka ^a   Kudo, Shinji ^a   Shoji, Tetsuya ^b   Hayashi, Jun ichiro ^a  

^a KYUSHU UNIVERSITY   (Japan)

^b CENTRAL RESEARCH INSTITUTE OF ELECTRIC POWER INDUSTRY   (Japan)

Author keywords

Aromatic hydrocarbons; Biomass; Cellulose; Chemical kinetics; Pyrolysis; Tar formation

Indexed keywords

ACETYLENE; AROMATIC HYDROCARBONS; BENZENE; BIOMASS; CELLULOSE; CRACKS; ETHYLENE; FREE RADICAL REACTIONS; KINETIC PARAMETERS; KINETIC THEORY; LIGHTING; PHASE INTERFACES; PYROLYSIS; REACTION KINETICS;

CELLULOSE PYROLYSIS; CONCENTRATION PROFILES; DETAILED CHEMICAL KINETIC; GAS-PHASE REACTIONS; HIGH TEMPERATURE; MECHANISTIC STUDIES; MULTICOMPONENT MIXTURE; REACTION PATHWAYS;

NAPHTHALENE;

AROMATIC HYDROCARBON; CELLULOSE; CONCENTRATION (COMPOSITION); EXPERIMENTAL STUDY; LOW TEMPERATURE; MATHEMATICAL ANALYSIS; NUMERICAL MODEL; PYROLYSIS; REACTION KINETICS; TEMPERATURE EFFECT;

EID: 84905246557     PISSN: 09619534     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.biombioe.2014.07.008     Document Type: Article

References (35)

1. Huber G.W., Iborra S., Corma A. Synthesis of transportation fuels from biomass: chemistry, catalysts, and engineering. Chem Rev 2006, 106(9):4044-4098.
2. Chiaramonti D., Oasmaa A., Solantausta Y. Power generation using fast pyrolysis liquids from biomass. Renew Sustain Energ Rev 2007, 11(6):1056-1086.
3. Goyal H.B., Seal D., Saxena R.C. Bio-fuels from thermochemical conversion of renewable resources: a review. Renew Sustain Energ Rev 2008, 12(2):504-517.
4. Zhang L., Xu C., Champagne P. Overview of recent advances in thermo-chemical conversion of biomass. Energ Convers Manag 2010, 51(5):969-982.
5. Kinoshita C.M., Wang Y., Zhou J. Tar formation under different biomass gasification conditions. J Anal Appl Pyrol 1994, 29(2):169-181.
6. Coll R., Salvadó J., Farriol X., Montané D. Steam reforming model compounds of biomass gasification tars: conversion at different operating conditions and tendency towards coke formation. Fuel Process Technol 2001, 74(1):19-31.
7. Devi L., Ptasinski K.J., Janssen F.J.J.G. A review of the primary measures for tar elimination in biomass gasification processes. Biomass Bioenerg 2002, 24(2):125-140.
8. Han J., Kim H. The reduction and control technology of tar during biomass gasification/pyrolysis: an overview. Renew Sustain Energ Rev 2008, 12(2):397-416.
9. Li C., Suzuki K. Tar property, analysis, reforming mechanism and model for biomass gasification-An overview. Renew Sustain Energ Rev 2009, 13(3):594-604.
10. Zhou S., Garcia-Perez M., Pecha B., McDonald A.G., Kersten S.R.A., Westerhof R.J.M. Secondary vapor phase reactions of lignin-derived oligomers obtained by fast pyrolysis of pine wood. Energ Fuel 2013, 27(3):1428-1438.
11. Hajaligol M.R., Howard J.B., Longwell J.P., Peters W.A. Product compositions and kinetics for rapid pyrolysis of cellulose. Ind Eng Chem Process Des Dev 1982, 21(3):457-465.
12. Funazukuri T., Hudgins R.R., Silveston P.L. Product distribution in pyrolysis of cellulose in a microfluidized bed. J Anal Appl Pyrol 1986, 9(2):139-158.
13. Norinaga K., Shoji T., Kudo S., Hayashi J.I. Detailed chemical kinetic modelling of vapour-phase cracking of multi-component molecular mixtures derived from the fast pyrolysis of cellulose. Fuel 2013, 103(1):141-150.
14. Lin Y.C., Cho J., Tompsett G.A., Westmoreland P.R., Huber G.W. Kinetics and mechanism of cellulose pyrolysis. J Phys Chem C 2009, 113(46):20097-20107.
15. Shen D.K., Gu S. The mechanism for thermal decomposition of cellulose and its main products. Bioresour Technol 2009, 100(24):6496-6504.
16. Mašek O., Konno M., Hosokai S., Sonoyama N., Norinaga K., Hayashi J.-I. A study on pyrolytic gasification of coffee grounds and implications to allothermal gasification. Biomass Bioenerg 2008, 32(1):78-89.
17. Shoji T., Norinaga K., Mašek O., Hayashi J.I. Numerical simulation of secondary gas phase reactions of coffee grounds with a detailed chemical kinetic model. Nihon Enerugi Gakkaishi/J Japan Inst Energ 2010, 89(10):955-961.
18. Richter H., Howard J.B. Formation and consumption of single-ring aromatic hydrocarbons and their precursors in premixed acetylene, ethylene and benzene flames. Phys Chem Chem Phys 2002, 4(11):2038-2055.
19. Sheng C.Y., Dean A.M. Importance of gas-phase kinetics within the anode channel of a solid-oxide fuel Cell. J Phys Chem A 2004, 108(17):3772-3783.
20. Marinov N.M. A detailed chemical kinetic model for high temperature ethanol oxidation. Int J Chem Kinet 1999, 31(2-3):183-220.
21. Lifshitz A., Bidani M. Thermal reactions of cyclic ethers at high temperatures. 5. Pyrolysis of 2,3-dihydrofuran behind reflected shocks. J Phys Chem 1989, 93(3):1139-1144.
22. Lifshitz A., Bidani M., Bidani S. Thermal reactions of cyclic ethers at high temperatures. 3. Pyrolysis of furan behind reflected shocks. J Phys Chem 1986, 90(21):5373-5377.
23. Lifshitz A., Bidani M., Bidani S. Thermal reactions of cyclic ethers at high temperatures. 4. Pyrolysis of 2,5-dihydrofuran behind reflected shocks. J Phys Chem 1986, 90(22):6011-6014.
24. Lifshitz A., Bidani M., Bidani S. Thermal reactions of cyclic ethers at high temperatures. 2. Pyrolysis of tetrahydrofuran behind reflected shocks. J Phys Chem 1986, 90(15):3422-3429.
25. Lifshitz A., Bidani M., Tamburu C. Decomposition of crotonaldehyde at elevated temperatures. Studies with a single-pulse shock tube. J Phys Chem 1989, 93(3):7161-7165.
26. Lifshitz A., Suslensky A., Tamburu C. Thermal reactions of 2,3-dihydrobenzofuran: experimental results and computer modeling. Symp Combust 2000, 28(2):1733-1739.
27. Lifshitz A., Tamburu C., Shashua R. Thermal decomposition of 2,5-dimethylfuran. Experimental results and computer modeling. J Phys Chem A 1998, 102(52):10655-10670.
28. Ranzi E., Cuoci A., Faravelli T., Frassoldati A., Migliavacca G., Pierucci S., et al. Chemical kinetics of biomass pyrolysis. Energ Fuel 2008, 22(6):4292-4300.
29. Matheu D.M., Dean A.M., Grenda J.M., Green W.H. Mechanism generation with integrated pressure dependence: a new model for methane pyrolysis. J Phys Chem A 2003, 107(41):8552-8565.
30. Sternberg J.C., Gallaway W.S., Jones D.T.L. The mechanism of response of flame ionization detectors. Gas chromatography 1962, Academic Press, New York. G. Chromatography, N. Brenner, J.E. Callen, M.D. Weiss (Eds.).
31. Deutschmann O, Tischer S, Kleditzsch S, Janardhanan V, Correa C, Chatterjee D, etal. DETCHEM Software package, 2.5 ed., [Cited 2014 July 4] Available from: Karlsruhe 2014. http://www.detchem.com.
32. Warnatz J., Maas U., Dibble R.W. Combustion 2000, Springer-Verlag, Heidelberg, New York. 3rd ed.
33. Norinaga K., Deutschmann O. Detailed kinetic modeling of gas-phase reactions in the chemical vapor deposition of carbon from light hydrocarbons. Ind Eng Chem Res 2007, 46(11):3547-3557.
34. Norinaga K., Deutschmann O., Saegusa N., Hayashi J. Analysis of pyrolysis products from light hydrocarbons and kinetic modeling for growth of polycyclic aromatic hydrocarbons with detailed chemistry. J Anal Appl Pyrol 2009, 86(1):148-160.
35. Patwardhan P.R., Satrio J.A., Brown R.C., Shanks B.H. Product distribution from fast pyrolysis of glucose-based carbohydrates. J Anal Appl Pyrol 2009, 86(2):323-330.