Influence of the nature of the electrode material and process variables on the kinetics of the chlorine evolution reaction. the case of IrO 2-based electrocatalysts

Electrochimica Acta

Volumn 139, Issue , 2014, Pages 180-189

  Rosestolato, Davide ^a   Fregoni, Jacopo ^a   Ferro, Sergio ^a   De Battisti, Achille ^a  

^a UNIVERSITY OF FERRARA   (Italy)

Author keywords

adsorbed intermediates; adsorption isotherm; Chlorine Evolution Reaction; iridium oxide; kinetics

Indexed keywords

ADSORPTION; ADSORPTION ISOTHERMS; ANODES; CHLORINE; CHLORINE COMPOUNDS; ELECTROCATALYSTS; ENZYME KINETICS; KINETICS; PHYSICAL VAPOR DEPOSITION; PROTONS; REACTION INTERMEDIATES; SOL-GELS; TITANIUM OXIDES;

ADSORBED INTERMEDIATES; CHLORINE EVOLUTION; DIMENSIONALLY STABLE ANODES; ELECTRODE SURFACE MODIFICATIONS; EXPERIMENTAL CONDITIONS; IMPEDANCE SPECTROSCOPY; IRIDIUM OXIDES; RF-MAGNETRON SPUTTERING;

REACTION KINETICS;

EID: 84905220850     PISSN: 00134686     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.electacta.2014.07.037     Document Type: Article

References (41)

1. H.B. Beer, Electrode having platinum metal oxide coating thereon, and method of use thereof. US 3711385 (1973).
2. H.B. Beer, Electrode and coating therefor. US 3632498 (1972).
3. A. Scrutton, L. Denis, Electrodes for electrochemical processes, US 3773554 (1973).
4. J.F. Gauger, J.M., Hinden, M. Katz, Electrode coating with platinum-group metal catalyst and semi-conducting polymer, US 4402996 (1983).
5. D. Galizzioli, F. Tandardini, and S. Trasatti Ruthenium dioxide: a new electrode material. I. Behaviour in acid solutions of inert electrolytes J. Appl. Electrochem. 4 1974 57
6. S. Pizzini, G. Buzzanca, C. Mari, L. Rossi, and S. Torchio Preparation, structure and electrical properties of thick ruthenium dioxide films Materials Research Bulletin 7 1972 449
7. K.J. O'Leary, and T.J. Navin Morphology of dimensionally stable anodes 1974 Chlorine Bicenten. Symp., Electrochem. Soc. Inc. Princeton, N.J. 174 186
8. H.J. Vanderbroele Kinetic investigation of chlorine evolution in the electrolysis of molten salts Rev. Fac. Cienc. Quim., Univ. Nacl. La Plata 34 1964 215
9. L.I. Krishtalik, and Z.A. Rotenberg Overvoltage in the anodic evolution of chlorine on graphite. II. Kinetic dependence in different regions of potentials Zhurnal Fizicheskoi Khimii 39 1965 907
10. S. Trasatti, and G. Buzzanca Ruthenium dioxide: a new interesting electrode material. Solid state structure and electrochemical behavior J. Electroanal. Chem. 29 1971 App.1
11. G. Bianchi Fundamental and applied aspects of the electrochemistry of chlorine J. Appl. Electrochem. 1 1971 231
12. G. Faita, and G. Fiori Anodic discharge of chloride ions on oxide electrodes J. Appl. Electrochem. 2 1972 31
13. S. Trasatti Progress in the understanding of the mechanism of chlorine evolution at oxide electrodes Electrochim. Acta 32 1987 369
14. H. Ohtaki, and T. Radnai Structure and dynamics of hydrated ions Chem. Rev. 93 1993 1157
15. H.A. Hansen, I.C. Man, F. Studt, F. Abild-Pedersen, T. Bligaard, and J. Rossmeisl Electrochemical chlorine evolution at rutile oxide (110) surfaces Phys. Chem. Chem. Phys. 12 2010 283
16. 2(110): ab initio atomistic thermodynamics study - Pourbaix diagrams Electrochim. Acta 120 2014 460
17. 2-based catalysts: A comparative review Electrochim. Acta 93 2013 314
18. P. Barricelli, M., Boccardo, G. Maranelli, IT PD 2008A000104 (2008).
19. A. Morozov, A. De Battisti, S., Ferro, G. Martelli, EP 1656471 B1 (2009).
20. D. Rosestolato, S., Neodo, S., Ferro, G., Battaglin, V., Rigato, A. De Battisti, New insights on structural and electrochemical properties of iridium oxide-based electrocatalysts prepared by sol-gel and reactive sputtering deposition, submitted.
21. S. Trasatti, and G. Lodi Electrodes of Conductive Metallic Oxides, Part B 535 1981 Elsevier
22. S. Trasatti Physical electrochemistry of ceramic oxides Electrochim. Acta 36 1991 225
23. 2 J. Electrochem. Soc. 120 1973 231
24. L.D. Burke, and J.F. O'Neill Electrochromism in anodic iridium oxide films: II. pH effects on corrosion stability and the mechanism of coloration and bleaching J. Electroanal. Chem. 101 1979 341
25. R.G. Érenburg, L.I. Krishtalik, and I.P. Yaroshevskaya Mechanism of chlorine deposition on a ruthenium oxide-titanium oxide electrode Elektrokhimiya 11 1975 1068
26. R.G. Érenburg, L.I. Krishtalik, and I.P. Yaroshevskaya Kinetics of the evolution and ionization of chlorine on ruthenium oxide and ruthenium oxide-titanium oxide electrodes Élektrokhimiya 11 1975 1072
27. R.G. Érenburg, L.I. Krishtalik, and I.P. Yaroshevskaya Separation and ionization of chlorine on oxide ruthenium-titanium electrodes at increased current densities Élektrokhimiya 11 1975 1236
28. L.I. Krishtalik Kinetics and mechanism of anodic chlorine and oxygen evolution reactions on transition metal oxide electrodes Electrochim. Acta 26 1981 329
29. 2 electrodes Electrochim. Acta 24 1979 521
30. R.G. Érenburg, L.I. Krishtalik, and N.P. Rogozhina Effect of pH on the kinetics of a chlorine reaction on ruthenium dioxide-titanium dioxide anodes Elektrokhimiya 20 1984 1183
31. B.V. Tilak, and B.E. Conway Analytical relations between reaction orders and Tafel slopes derivatives for electrocatalytic reactions involving chemisorbed intermediates Electrochim. Acta 37 1992 51
32. J.E.B. Randles Kinetics of rapid electrode reactions Discuss. Faraday Soc. 1 1947 11
33. G.J. Brug, A.L.G. Van den Eeden, M. Sluyters-Rehbach, and J.H. Sluyers The analysis of electrode impedances complicated by the presence of a constant phase element J. Electroanal. Chem. 176 1984 275
34. S. Gottesfeld, and J.D. McIntyre Electrochromism in Anodic Iridium Oxide Films: II. pH Effects on Corrosion Stability and the Mechanism of Coloration and Bleaching J. Electrochem. Soc. 126 1979 742
35. 2 J. Appl. Electrochem. 30 2000 625
36. L. Ping, L. Quinfeng, X. Likun, X. Lili, and S. Hongging Electrochemical Impedance Spectroscopy (EIS) Study of Ru-La Oxide Coatings in NaCl Solution Acta Chimica Sinica 70 2012 1166
37. L.J.J. Janssen, L.M.C. Starmans, J.G. Visser, and E. Barandrecht Mechanism of the chlorine evolution on a ruthenium oxide/titanium oxide electrode and on a ruthenium electrode Electrochim. Acta 22 1977 1093
38. L.J.J. Janssen Kinetics and mechanism of chlorine evolution on metal oxide electrodes C. Jackson, Modern Chlor-Alkali Technology 271 1983 Ellis Horwood Chichester
39. M. Thomassen, C. Karlsen, B. Børresen, and R. Tunold Kinetic investigation of the chlorine reduction reaction on electrochemically oxidised ruthenium Electrochim. Acta 51 2006 2909
40. T. Arikado, C. Iwakura, and H. Tamura Some oxide catalysts for the anodic evolution of chlorine: reaction mechanism and catalytic activity Electrochim. Acta 23 1978 9
41. S. Ardizzone, and S. Trasatti Interfacial properties of oxides with technological impact in electrochemistry Advances in Colloid and Interface Science 64 1996 173