Dramatically different kinetics and mechanism at solid/liquid and solid/gas interfaces for catalytic isopropanol oxidation over size-controlled platinum nanoparticles

Journal of the American Chemical Society

Volumn 136, Issue 29, 2014, Pages 10515-10520

  Wang, Hailiang ^a,b   Sapi, Andras ^a,b   Thompson, Christopher M ^a,b   Liu, Fudong ^a,b   Zherebetskyy, Danylo ^b   Krier, James M ^a,b   Carl, Lindsay M ^a,b   Cai, Xiaojun ^a,b   Wang, Lin Wang ^b   Somorjai, Gabor A ^a,b  

^a UNIVERSITY OF CALIFORNIA   (United States)

^b LAWRENCE BERKELEY NATIONAL LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACETONE; ACTIVATION ENERGY; CATALYSTS; CATALYTIC OXIDATION; GASES; LIQUIDS; NANOPARTICLES; OXIDATION; PLATINUM; SYNTHESIS (CHEMICAL);

CATALYST NANO PARTICLES; COMPUTATIONAL CALCULATIONS; KINETICS AND MECHANISM; LIQUID AND GAS PHASIS; LIQUID-PHASE REACTION; PLATINUM NANO-PARTICLES; SOLID/LIQUID INTERFACES; SUM FREQUENCY GENERATION VIBRATIONAL SPECTROSCOPIES;

PHASE INTERFACES;

2 PROPANOL; PLATINUM NANOPARTICLE; WATER;

ALCOHOL OXIDATION; ARTICLE; CATALYSIS; CATALYST; ENERGY; GAS; LIQUID; PARTICLE SIZE; PHASE TRANSITION; SOLID; SPECTROSCOPY; TRANSMISSION ELECTRON MICROSCOPY; TURNOVER TIME;

EID: 84904907136     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja505641r     Document Type: Article

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