Development and validation of a sensitive thermal desorption-gas chromatography-mass spectrometry (TD-GC-MS) method for the determination of phosgene in air samples

Analytical and Bioanalytical Chemistry

Volumn 406, Issue 21, 2014, Pages 5137-5145

  Juillet, Y ^a   Dubois, C ^a   Bintein, F ^a   Dissard, J ^a   Bossee A ^a  

^a Delegation Generale pour l'Armement   (France)

Author keywords

Air sampling; Derivatization; Phosgene; Tenax tube; Thermal desorption

Indexed keywords

CHEMICAL WARFARE; GAS CHROMATOGRAPHY; THERMAL DESORPTION; TUBES (COMPONENTS);

AIR SAMPLING; CHEMICAL WARFARE AGENTS; CHEMICAL WEAPONS CONVENTION; CHROMATOGRAPHY-MASS SPECTROMETRY; DERIVATIZATIONS; GAS CHROMATOGRAPHY-MASS SPECTROMETRIES (GC-MS); PHOSGENE; RELATIVE STANDARD DEVIATIONS; AIR SAMPLES; TD-GC-MS;

AIR QUALITY; THERMAL DESORPTION;

3,4-DIMERCAPTOTOLUENE; AIR POLLUTANT; CHEMICAL WARFARE AGENT; ETHYLAMINE; HEXANE; PHOSGENE; SOLVENT; THIOL DERIVATIVE; TOLUENE; TRIETHYLAMINE;

AIR POLLUTANT; ANALOGS AND DERIVATIVES; ANALYSIS; CHEMISTRY; ENVIRONMENTAL MONITORING; HEAT; HUMAN; LIMIT OF DETECTION; MASS FRAGMENTOGRAPHY; PROCEDURES;

AIR POLLUTANTS; CHEMICAL WARFARE AGENTS; ENVIRONMENTAL MONITORING; ETHYLAMINES; GAS CHROMATOGRAPHY-MASS SPECTROMETRY; HEXANES; HOT TEMPERATURE; HUMANS; LIMIT OF DETECTION; PHOSGENE; SOLVENTS; SULFHYDRYL COMPOUNDS; TOLUENE;

EID: 84904798862     PISSN: 16182642     EISSN: 16182650     Source Type: Journal    
DOI: 10.1007/s00216-014-7809-5     Document Type: Article

References (25)

1. INRS (2008) Fiche toxicologique FT72, INRS, edition
2. Oh LM, Grant Spoors P, Goodman RM (2004) Tetrahedron Lett 45(24):4769-4771
3. Huagong G (2009) Gen Rev 37(7):146-148
4. Fitzgerald GJ (2008) Am J Public Health 98(4):611-625
5. Dhara VR, Dhara R (2002) Arch Environ Health 57(5):391-404
6. World Health Organization (1998) Phosgene, health and safety guide, WHO, Geneva
7. Battin-Leclerc F, Baronnet F, Paternotte G, Leclerc JP, Gourhan R (2000) J Analytic and Applied Pyrolysis 53:95-105
8. Threshold Limit Values for Chemical Substances and Biological Exposure Indices (1992) American Conference of Government Industrial Hygienists, Cincinnati, OH
9. Fiche Metropol (2004) phosgène par chromatographie en phase gazeuse, Fiche 075
10. US Environmental Protection Agency (1986) EPA method TO-6. EPA, Washington
11. Massil SE, Ovadia D (1991) J Chrom A 538:435-440
12. Rando RK, Poovey HG, Chang SN (1993) J Liquid Chrom 16(15):3291-3309
13. Schoene K, Bruckert HJ, Steinhanses J (1993) Anal Chem 345:688-694
14. Hendershott JP (1986) Am Ind Hyg Assoc J 47(12):742-746
15. Carrick W, Cooper DB, Muir B (2001) J Chrom A 925:241-249
16. Oostdijk JP, Degenhardt CEAM, Trap HC, Langenberg JP (2007) J Chrom A 1150:62-69
17. Terzic O, Swahn I, Cretu G, Palit M, Mallard G (2012) J Chrom A 1225(17):182-192
18. Terzic O, Bartenbach S, de Voogt P (2013) J Chrom A 1304:34-41
19. Vaninnen P (2011) Recommended operating procedures for analysis in the verification of chemical disarmament, Edition, Ministry for Foreign Affairs of Finland
20. Juillet Y, Le Moullec S, Begos A, Bellier B (2005) Analyst 130(6):977-982
21. Lattin FGF, Mehta UD, Jakubowski EM, Tinsley L, Paul DG (1994) In: Proc ERDEC Sci Conf Chem Biol. Def. Res, p 181
22. Black R, Muir B (2003) J Chrom A 1000:253-281
23. Black R, Muir B (2005) J Chrom A 1098:156-165
24. Muir B, Slater BJ, Cooper DB, Timperley CM (2004) J Chrom A 1028:313-320
25. OPCW (2013) Work instruction for the reporting of the results of the OPCW proficiency tests, QDOC/LAB/WI/PT04, issue 1, revision 2