Anodic oxidation of butan-1-ol on Pd and Pt electrodes in alkaline medium

Journal of Applied Electrochemistry

Volumn 44, Issue 7, 2014, Pages 857-866

  Mukherjee, Parthasarathi ^a   Bhattacharya, Swapan Kumar ^a  

^a JADAVPUR UNIVERSITY   (India)

Author keywords

Butan 1 ol electro oxidation; Catalytic activity of Pt and Pd; FTIR study of products; Mechanism of oxidation; Order

Indexed keywords

ANODIC OXIDATION; CATALYST ACTIVITY; CYCLIC VOLTAMMETRY; ELECTROCATALYSTS; ELECTRODES; ELECTROOXIDATION; REACTION INTERMEDIATES;

ADSORBED INTERMEDIATES; ANODIC CURRENT DENSITY; CONVENTIONAL CATALYST; DIFFERENT MECHANISMS; FT-IR STUDY; MECHANISM OF OXIDATION; ORDER; REVERSIBLE ELECTRODES;

PLATINUM;

EID: 84904763115     PISSN: 0021891X     EISSN: None     Source Type: Journal    
DOI: 10.1007/s10800-014-0694-y     Document Type: Article

References (50)

1. Barragan VM, Heinzel A (2002) Estimation of the membrane methanol diffusion coefficient from open circuit voltage measurements in a direct methanol fuel cell. J Power Sources 104:66-72
2. Tang HL, Wang SL, Pan M, Jiang SP, Ruan YZ (2007) Performance of direct methanol fuel cells prepared by hot-pressed MEA and catalyst-coated membrane (CCM). J Electrochim Acta 52:3714-3718
3. Heinzel A, Barragan VM (1999) A review of the state of the art of the methanol crossover in direct methanol fuel cell. J Power Sources 84:70-74
4. Ren X, Springen TE, Zawodzmski TA, Gottegfeld S (2000) Methanol transport through Nafion membranes. Electro-osmotic drag effects on potential step measurements. J Electrochem Soc 147(2):466-474
5. Dillion R, Srinivasan S, Arico AS, Antonucci V (2004) International activities in DMFC R&D: status of technologies and potential applications. J Power Sources 127:112-126
6. Paul P, Bagchi J, Bhattayacharya SK (2006) Electrochemical oxidation of ethanol on thin coating on platinum based material on nickel support. Indian J Chem 45:1144-1152
7. Mauritz KA, Moore RB (2004) State of understanding of nafion. Chem Rev 104:4535-4586
8. Ye J, Liu J, Xu C, Jiang SP, Tong Y (2007) Electrooxidation of 2-propanol on Pt, Pd and Au in alkaline medium. Electrochem Commun 9:2760-2763
9. Liu J, Ye J, Xu C, Jiang SP, Tong Y (2008) Electro-oxidation of methanol, 1-propanol and 2-propanol on Pt and Pd in alkaline medium. J Power Sources 177:67-70
10. Takky D, Beden B, Leger JM, Lamy C (1988) Evidence for the effect of molecular structure on the electrochemical reactivity of alcohols: part III. Electro-oxidation of the butanol isomers on platinum single crystals in an alkaline medium. J Electroanal Chem 256:127-136
11. 2/C catalysts. J Power Sources 142:27-29
12. Tripkovic AV, Popovic KD, Lovic JD, Jovanovic VM, Kowal A (2004) Methanol oxidation at platinum electrodes in alkaline solution: comparison between supported catalysts and model systems. J Electroanal Chem 572:119-128
13. Rodrigues IA, Nart FC (2006) 2-Propanol oxidation on platinum and platinum-rhodium electrodeposits. J Electroanal Chem 590:145-151
14. Otomo J, Li XE, Kobayashi T, Wen CJ, Nagamoto H, Takahashi H (2004) AC-impedance spectroscopy of anodic reactions with adsorbed intermediates: electro-oxidations of 2-propanol and methanol on carbon-supported Pt catalyst. J Electroanal Chem 573:99-109
15. 2/C anode electrocatalyst for direct methanol fuel cells. J Power Source 156:345-354
16. Zhang LL, Lu TH, Bao JC, Tag YW, Li C (2006) Preparation method of an ultra fine carbon supported Pd catalyst as an anodic catalyst in a direct formic acid fuel cell. Electrochem Commun 8:1625-1627
17. Ji XB, Banks CE, Xi W, Wilkinas SJ, Compton RG (2006) Edge plane sites on highly ordered pyrolytic graphite as templates for making palladium nanowires via electrochemical decoration. J Phys Chem B 110:22306-22309
18. Savadogo O, Lee K, Oishi K, Mitsushima S, Kamiya N, Ota KI (2004) New palladium alloys catalyst for the oxygen reduction reaction in an acid medium. Electrochem Commun 6:105-109
19. Bagchi J, Bhattayacharya SK (2008) Studies of the electrocatalytic activity of binary palladium ruthenium anode catalyst on Ni support for ethanol alkaline fuel cells. Trans Met Chem 33:113-120
20. Beden B, Leger JM, Lamy C, Bockris JOM, Conway BE, White RE (eds) (1992) Modern aspect of electrochemistry (chapter 2), vol 22. Plenum Press, New York
21. Prabhuram J, Manoharan R (1998) Investigation of methanol oxidation on unsupported platinum electrodes in strong alkali and strong acid. J Power Sources 74:54-61
22. Tripkovic AV, Popovic KD, Momcilovic JD, Drazic DM (1996) Kinetic and mechanistic study of methanol oxidation on a Pt(111) surface in alkaline media. J Electroanal Chem 418:9-20
23. Tripkovic AV, Popovic KD, Momcilovic JD, Drazic DM (1998) Kinetic and mechanistic study of methanol oxidation on a Pt(100) surface in alkaline media. J Electroanal Chem 448:173-181
24. Tripkovic AV, Popovic KD, Momcilovic JD, Drazic DM (1998) Kinetic and mechanistic study of methanol oxidation on a Pt(110) surface in alkaline media. Electrochim Acta 44:1135-1145
25. Tripkovic AV, Popovic KDj, Lovic JD (2001) The influence of the oxygen-containing species on the electrooxidation of the C1-C4 alcohols at some platinum single crystal surfaces in alkaline solution. Electrochim Acta 46:3163-3173
26. Yu EH, Scott K, Reeve RW (2003) A study of the anodic oxidation of methanol on Pt in alkaline solutions. J Electroanal Chem 547:17-24
27. Garden M, Kotowski J, Czerwinski A (2000) The study of electrochemical palladium behavior using the quartz crystal microbalance. J Solid State Electrochem 4:273-278
28. Garden M, Czerwinski A (2008) EQCM studies on Pd-Ni alloy oxidation in basic solution. J Solid State Electrochem 12:375-385
29. Liang ZX, Zhao TS, Xu JB, Zhu LD (2009) Mechanism study of the ethanol oxidation reaction on palladium in alkaline media. Electrochim Acta 54:2203-2208
30. Hildenbrad DL, Lau KH (2000) Dissociation energy of the PdO molecule. Chem Phys Lett 319:95-98
31. Yatsuhisa N (2002) Standard enthalpy of formation of platinum hydrous oxide. J Therm Anal Calorim 69:831-839
32. Trasatti S, Petrii OA (1991) Real surface area measurements in electrochemistry. Pure Appl Chem 63(5):711-734
33. Singh RN, Singh A (2009) Electrocatalytic activity of binary and ternary composite films of Pd, MWCNT and Ni, part II: methanol electrooxidation in 1 M KOH. Int J Hydrogen Energy 34(4):2052-2057
34. Mahapatra SS, Dutta J (2011) Characterization of Pt-Pd/C electrocatalyst for methanol oxidation in alkaline medium. Int J Electrochem. doi: 10.4061/2011/563495
35. Morin MC, Lamy C, Leger JM (1990) Structural effects in electrocatalysis: oxidation of ethanol on platinum single crystal electrodes. Effect of pH. J Elerctronal Chem 283:287-302
36. Huang JC, Liu ZL, He CB, Gan LM (2005) Synthesis of PtRu nanoparticles from the hydrosilylation reaction and application as catalyst for direct methanol fuel cell. J Phys Chem B 109:16644-16649
37. Bard AJ, Faulkner LR (1980) Electrochemical methods: fundamentals and applications (chapter 11: electrode reactions with coupled homogeneous chemical reactions). Wiley, New York
38. Shen PK, Xu CW (2006) Alcohol oxidation on nanocrystalline oxide Pd/C promoted electrocatalysts. Electrochem Commun 8:184-188
39. Liu HP, Ye JP, Xu CW, Jiang SP, Tong YX (2007) Kinetics of ethanol electrooxidation at Pd electrodeposited on Ti. Electrochem Commun 9:2334-2339
40. Nie M, Tang HL, Wei ZD, Ziang SP, Shen PK (2007) Highly efficient AuPd-WC/C electrocatalyst for ethanol oxidation. Electrochem Commun 9:2375-2379
41. Xu CW, Cheng LQ, Shen PK, Liu YL (2007) Methanol and ethanol electrooxidation on Pt and Pd supported on carbon microspheres in alkaline media. Electrochem Commun 9:997-1001
42. Zheng HT, Li YL, Chen SX, Shen PK (2006) Effect of support on the activity of Pd electrocatalyst for ethanol oxidation. J Power Source 163:371-375
43. Bagchi J, Bhattacharya SK (2007) Electrocatalytic activity of binary palladium ruthenium anode catalyst on Ni-support for ethanol alkaline fuel cells. Transit Met Chem 32:47-55
44. Zhou ZY, Wang Q, Lin JL, Tian N, Sun SG (2010) In situ FTIR spectroscopic studies of electrooxidation of ethanol on Pd electrode in alkaline media. Electrochim Acta 55:7995-7999
45. 4 alcohol on a platinum electrode in acid solutions part I. Reaction mechanism of 1-butanol oxidation. J Electroanal Chem 436:65-72
46. Nakomoto K (1986) Infrared and Raman spectra of inorganic and co-ordination compounds. Wiley, New York
47. Andrzej K, Simon NP, Richard JN (1997) Nickel hydroxide electrocatalysts for alcohol oxidation reactions: an evaluation by infrared spectroscopy and electrochemical methods. Catal Today 38:483-492
48. Lin-Vien D, Colthup NB, Fately WG, Grasselli JG (1991) The hand book of infrared and Raman characteristic frequencies of organic molecules. Academic Press, New York
49. Bianchini C, Shen PK (2009) Palladium-based electrocatalysts for alcohol oxidation in half cells and in direct alcohol fuel cells. Chem Rev 109:4183-4206
50. Bagchi J, Bhattacharya SK (2007) The effect of composition of Ni-supported Pt-Ru binary anode catalysts on ethanol oxidation for fuel cells. J Power Sources 163:661-670