Enhanced electrooxidation of methanol, ethylene glycol, glycerol, and xylitol over a polypyrrole/manganese oxyhydroxide/palladium nanocomposite electrode

Journal of Applied Electrochemistry

Volumn 44, Issue 8, 2014, Pages 893-902

  Kannan, Ramanujam ^a   Kim, Ae Rhan ^a   Yoo, Dong Jin ^a  

^a Chonbuk National University   (South Korea)

Author keywords

Electrocatalyst; Electrooxidation; Manganese oxyhydroxide; Palladium; Polypyrrole

Indexed keywords

CATALYST ACTIVITY; CATALYST POISONING; ELECTROCATALYSTS; ELECTRODES; ETHYLENE GLYCOL; GLYCEROL; METAL NANOPARTICLES; METHANOL; NANOCOMPOSITES; PALLADIUM; POLYOLS; POLYPYRROLES; REACTION INTERMEDIATES; SUGAR SUBSTITUTES;

ALCOHOL ELECTRO OXIDATIONS; CATALYTIC PERFORMANCE; ELECTRO-OXIDATION REACTION; ELECTROCATALYTIC ACTIVITY; MANGANESE OXYHYDROXIDE; MAXIMUM POWER DENSITY; METHANOL ELECTROOXIDATION; NANOCOMPOSITE ELECTRODES;

ELECTROOXIDATION;

EID: 84904716834     PISSN: 0021891X     EISSN: None     Source Type: Journal    
DOI: 10.1007/s10800-014-0706-y     Document Type: Article

References (31)

1. Bianchini C, Shen PK (2009) Palladium-based electrocatalysts for alcohol oxidation in half cells and in direct alcohol fuel cells. Chem Rev 109:4183-4206
2. Yu EH, Krewer U, Scott K (2010) Principles and materials aspects of direct alkaline fuel cells. Energies 3:1499-1528
3. Wang YJ, Wilkinson DP, Zhang J (2011) Noncarbon support materials for polymer electrolyte membrane fuel cell electrocatalysts. Chem Rev 111:7625-7651
4. Brouzgou A, Song SQ, Tsiakaras P (2012) Low and non platinum electrocatalyst for PEMFCs: current status, challenges and prospects. Appl Catal B Environ 127:371-388
5. Brouzgou A, Podias A, Tsiakaras P (2013) PEMFCs and AEMFCs directly fed with ethanol: a current status comparative review. J Appl Electrochem 43(2):119-136
6. Serov A, Kwak C (2010) Recent achievements in direct ethylene glycol fuel cells (DEGFC). Appl Catal B Environ 97:1-12
7. Xu C, Liu Y, Yuan D (2007) Pt and Pd supported on carbon microspheres for alcohol electrooxidation in alkaline media. Int J Electrochem Sci 2:674-680
8. Kohlmuller H (1976) Anodic oxidation of ethylene glycol with noble metal alloy catalysts. J Power Sources 1:249-256
9. Janssen MMP, Moolhuysen J (1976) Binary systems of platinum and a second metal as oxidation catalysts for methanol fuel cell. Electrochim Acta 21:869-878
10. 3OH in NaOH solution. J Electroanal Chem 260:167-179
11. Manaoharan R, Prabhuram J (2001) Possibilities of prevention of formation of poisoning species on direct methanol fuel cell anodes. J Power Sources 96:220-225
12. Musthafa OTM, Sampath S (2008) High performance platinized titanium nitride catalyst for methanol oxidation. Chem Commun 7:67-69
13. Jeon MK, Daimon H, Lee KR, Nakahara A, Woo SI (2007) CO tolerant Pt/WC methanol electro-oxidation catalyst. Electrochem Commun 9:2692-2695
14. Yan Z, Zhang M, Xie J, Shen PK (2012) Vanadium carbide and graphite promoted Pd electrocatalyst for ethanol oxidation in alkaline media. J Power Sources 243:336-342
15. Pandey RK, Lakshminarayanan V (2009) Electro-oxidation of formic acid, methanol and ethanol on electrodeposited Pd-Polyaniline nanofiber films in acidic and alkaline medium. J Phys Chem C 113:21596-21603
16. 2 supported palladium-a facile nanocatalyst for the electrooxidation of methanol. Mater Focus 2:267-271
17. 4)-promoted Pd/C electrocatalysts for alcohol electrooxidation in alkaline media. Electrochim Acta 53:2610-2618
18. 2 nanotubes composites as catalysts for methanol oxidation in alkaline solution. J Power Sources 175:217-220
19. Deab MSE (2011) Platinum nanoparticles-manganese oxide nanorods as novel binary catalysts for formic acid oxidation. J Adv Res 3:65-71
20. Kannan R, Karunakaran K, Vasanthkumar S (2011) PdNi-coated manganite nanorods as catalyst for electrooxidation of methanol in alkaline medium. Appl Nanosci 2:149-155
21. Kannan R, Karunakaran K, Vasanthkumar S (2012) PdNi-decorated manganite nanocatalyst for electrooxidation of ethylene glycol in alkaline medium. Ionics 18:803-809
22. Kannan R, Karunakaran K, Vasanthkumar S (2012) Nanostructured OMO type manganese oxide - as novel support for palladium towards electrooxidation of methanol and ethylene glycol. J New Mater Electrochem Syst 15:249-254
23. 2/C anode catalyst for direct methanol fuel cells. Appl Catal B Environ 84:773-782
24. 2-graphene hybrid as an alternative cathodic catalyst to platinum in microbial fuel cells. J Power Sources 216:187-191
25. 4-modified multi-walled carbon nanotubes. Int J Hydrog Energy 37:11167-11175
26. 2-carbon nanocomposite supported gold catalyst for anode glucose oxidation. J Power Sources 221:1-5
27. Wei L, Fan YJ, Ma JH, Tao LH, Wang RX, Zhong JP, Wang H (2013) Highly dispersed Pt nanoparticles supported on manganese oxide-poly(3,4- ethylenedioxythiophene)-carbon nanotubes composite for enhanced methanol electrooxidation. J Power Sources 238:157-164
28. Gharibi H, Kakaei K, Zhiani M (2010) Platinum nanoparticles supported by a Vulcan XC-72 and PANI doped with trifluoromethane sulfonic acid substrate as a new electrocatalyst for direct methanol fuel cells. J Phys Chem 114:5233-5240
29. Liang ZX, Zhao TS, Xu JB, Zhu LD (2009) Mechanism study of the ethanol oxidation on palladium in alkaline media. Electrochim Acta 54:2203-2208
30. Pattabiraman R (1997) Electrochemical investigations on carbon supported palladium catalysts. Appl Catal A Gen 153:9-20
31. Deab MSE, Awad MI, Mohammad AM, Ohsaka T (2007) Enhanced water electrolysis: electrocatalytic generation of oxygen gas at manganese oxide nanorods modified electrodes. Electrochem Commun 9:2082-2087