The influence of bis-EMA vs bis GMA on the degree of conversion and water susceptibility of experimental composite materials

Acta Odontologica Scandinavica

Volumn 72, Issue 6, 2014, Pages 440-447

  Cornelio, Roberto Belloti ^a   Wikant, Aksel ^a   Mjosund, Hanne ^a   Kopperud, Hilde Molvig ^b   Haasum, Johan ^c   Gedde, Ulf Wiel ^c   Örtengren, Ulf Thore ^a  

^a UNIVERSITY OF TROMSØ   (Norway)

^b Nordisk Institutt for Odontologiske Materialer   (Norway)

^c ROYAL INSTITUTE OF TECHNOLOGY   (Sweden)

Author keywords

Bis EMA; Dental composites; Energy density; FT Raman spectroscopy; Hydrogen bonds

Indexed keywords

2,2-DI(4-METHACRYLOXYPHENYL)PROPANE; BENZHYDRYL DERIVATIVE; BISPHENOL A BIS(2 HYDROXYPROPYL) ETHER DIMETHACRYLATE; DENTAL MATERIAL; METHACRYLIC ACID DERIVATIVE; WATER;

CHEMISTRY; FOURIER ANALYSIS; RAMAN SPECTROMETRY; SOLUBILITY;

BENZHYDRYL COMPOUNDS; BISPHENOL A-GLYCIDYL METHACRYLATE; DENTAL MATERIALS; FOURIER ANALYSIS; METHACRYLATES; SOLUBILITY; SPECTRUM ANALYSIS, RAMAN; WATER;

EID: 84904633632     PISSN: 00016357     EISSN: 15023850     Source Type: Journal    
DOI: 10.3109/00016357.2013.856467     Document Type: Article

References (40)

1. Emami N, Soderholm KJ. How light irradiance and curing time affect monomer conversion in light-cured resin composites. Eur J Oral Sci 2003;111:536-42
2. Emami N, Soderholm KJ, Berglund LA. Effect of light power density variations on bulk curing properties of dental composites. J Dent 2003;31:189-96
3. Anseth KS, Goodner MD, Reil MA, Kannurpatti AR, Newman SM, Bowman CN. The influence of comonomer composition on Dimethacrylate resin properties for dental composites. J Dent Res 1996;75:1607-12
4. Lovell LG, Newman SM, Bowman CN. The effects of light intensity, temperature, and comonomer composition on the polymerization behavior of dimethacrylate dental resins. J Dent Res 1999;78:1469-76
5. Kalachandra S, Sankarpandian M, Shobha HK, Taylor DF, McGrath JE. Influence of hydrogen bonding on properties of BIS-GMA analogues. J Mater Sci Mater Med 1997;8:283-6
6. Lemon MT, Jones MS, Stansbury JW. Hydrogen bonding interactions in methacrylate monomers and polymers. J Biomed Mater Res A 2007;83:734-46
7. Peutzfeldt A. Resin composites in Dentistry: The monomer systems. Eur J Oral Sci 1997;105:97-116
8. Odian G. Principles of polymerization. 4th ed. John Wiley & Sons, Inc., Hoboken, New Jersey, US 2004
9. Zhu S, Tian Y, Hamielec AE, Eaton DR. Radical trapping and termination in free-radical polymerization of methyl methacrylate. Macromolecules 1990;23:1144-50
10. Asmussen E. Factors affecting the quantity of remaining double bonds in restorative resin polymers. Scand J Dent Res 1982;90:490-6
11. Ruyter IE, Svendsen SA. Remaining methacrylate groups in composite restorative materials. Acta Odontol Scand 1978;36: 75-82
12. Bowen RL. Dental filling material comprising vinyl-silane treated fused silica and a binder consisting of reaction product of bisphenol and glycidyl methacrykate. US 3066112. 1962
13. Dickens S, Stansbury JW, Choi KM, Floyd CJE. Photopolymerization kinetics of methacrylate dental resins. Macromolecules 2003;36:6043-53
14. Lovell LG, Stansbury JW, Syrpes DC, Bowman CN. Effects of composition and reactivity on the reaction kinetis of dimethacrylate/dimethacrylate copolymerizations. Macromolecules 1999;32:3913-21
15. Davy KW, Kalachandra S, Pandain MS, Braden M. Relationship between composite matrix molecular structure and properties. Biomaterials 1998;19:2007-14
16. Goncalves F, Kawano Y, Pfeifer CS, Stansbury JW, Braga RR. Influence of BisGMA, TEGDMA, and BisEMA contents on viscosity, conversion, and flexural strength of experimental resins and composites. Eur J Oral Sci 2009; 117:442-6
17. Goncalves F, Pfeifer CS, Ferracane JL, Braga RR. Contraction stress determinants in Dimethacrylate composites. J Dent Res 2008;87:367-71
18. Sideridou I, Tserki V, Papanastasiou G. Effect of chemical structure on Degree of conversion in light-cured dimethacrylate-based dental resins. Biomaterials 2002;23:1819-29
19. Stansbury JW. Synthesis and evaluation of novel multifunctional oligomers for dentistry. J Dent Res 1992;71:434-7
20. Cornelio RB, Kopperud HM, Haasum J, Gedde UW, Örtengren U. Influence of different mould materials on the degree of conversion of dental composite resins. Braz J Oral Sci 2012;11:469-74
21. International Organization for Standardization. ISO 4049 (2009) Dentistry -Polymer -based restorative materials. Geneva, Switzerland: International Organization for Standardization; 2009
22. Cohen JW. Statistical power analysis for the behavioral sciences. 2nd ed. Hillsdale, NJ: Lawrence Erlbaum Associates; 1988
23. Shin WS, Li XF, Schwartz B, Wunder SL, Baran GR. Determination of the degree of cure of dental resins using Raman and FT-Raman spectroscopy. Dent Mater 1993;9:317-24
24. Stansbury JW, Dickens SH. Determination of double bond conversion in Dental resins by near infrared spectroscopy. Dent Mater 2001;17:71-9
25. Anseth KS, Bowman CN, Peppas NA. Polymerization kinetics and volume relaxation behavior of photopolymerized multifunctional monomers producing highly cross-linked networks. J Polym Sci Part A: Polymer Chemistry 1994;32: 139-47
26. Anseth KS, Kline LM, Walker TA, Anderson KJ, Bowman CN. Reaction behaviour and kinetic constants for photopolymerizations of multi(meth)acrylate monomers. Macromolecules 1995;28:2491-9
27. Stansbury JW, Dickens SH. Network formation and compositional drift during photo-initiated copolymerization of dimethacrylate monomers. Polymer 2001;42:6363-9
28. Beuerman S. The influence of hydrogen bondning on the propagation rate coefficient in free-radical polymerizations of hydroxypropyl methacrylate. Macromol Chem Phys 2003; 204:460-70
29. Beuerman S. Impact of hydrogen bondning on propagation kinetics in butyl methacrylate radical polymerization. Macromolecules 2004;37:1037-41
30. Örtengren U, Wellendorf H, Karlsson S, Ruyter IE. Water sorption and solubility of dental composites and identification of monomers released in an aqueous environment. J Oral Rehabil 2001;28:1106-15
31. Örtengren U, Elgh U, Spasenoska V, Milleding P, Haasum J, Karlsson S. Water sorption and flexural properties of a composite resin cement. Int J Prosthodont 2000;13:141-7
32. Braden M, Clarke RL. Water absorption characteristics of dental microfine composite filling materials. I. Proprietary materials. Biomaterials 1984;5:369-72
33. Braden M. Water absorption characteristics of dental microfine composite filling materials. II. Proprietary materials. Biomaterials 1984;5:373-5
34. Ferracane JL. Elution of leachable components from composites. J Oral Rehabil 1994;21:441-52
35. Sideridou I, Karabela MM. Sorption of water, ethanol or ethanol/water solutions by light cured dental dimethacrylate resins. Dent Mater 2011;27:1003-10
36. Sankarapandian M, Shobha HK, Kalachandra S, McGrath JE, Taylor DF. Characterization of some aromatic dimethacrylates for dental composite applications. JMater Sci Mater Med 1997;8:465-8
37. Göpferich A. Mechanisms of polymer degradation and erosion. Biomaterials 1996;17:103-14
38. Ferracane JL, Berge HX, Condon JR. In vitro aging of dental composites in water-effect of degree of conversion, filler volume, and filler/matrix coupling. J Biomed Mater Res 1998;42:465-72
39. Michelsen VB, Kopperud HB, Lygre GB, Bjorkman L, Jensen E, Kleven IS, et al. Detection and quantification of monomers in unstimulated whole saliva after treatment with resin-based composite fillings in vivo. Eur J Oral Sci 2012; 120:89-95
40. Kalachandra S, Kusy RP. Comparison of water sorption by methacrylate and dimethacrylate monomers and their corresponding polymers. Polymer 1991;32:2428-34