Thermal decomposition kinetics and mechanism of 1,1′-bicyclohexyl

Energy and Fuels

Volumn 28, Issue 7, 2014, Pages 4523-4531

  Yue, Lei ^a   Qin, Xiaomei ^a   Wu, Xi ^a   Guo, Yongsheng ^a   Xu, Li ^a   Xie, Hujun ^b   Fang, Wenjun ^a  

^a ZHEJIANG UNIVERSITY   (China)

^b ZHEJIANG GONGSHANG UNIVERSITY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION ENERGY; CYCLOHEXANE; INTEGRAL EQUATIONS; OLEFINS; ORGANIC SOLVENTS; RATE CONSTANTS; THERMODYNAMIC STABILITY;

APPARENT RATE CONSTANT; ARRHENIUS PARAMETERS; DECOMPOSITION PROCESS; DECOMPOSITION PRODUCTS; HYDROCARBON COMPOUNDS; PREEXPONENTIAL FACTOR; PRODUCT DISTRIBUTIONS; THERMAL DECOMPOSITION KINETICS;

DECOMPOSITION;

EID: 84904580070     PISSN: 08870624     EISSN: 15205029     Source Type: Journal    
DOI: 10.1021/ef501077n     Document Type: Conference Paper

References (28)

1. Edwards, T. Liquid fuels and propellants for aerospace propulsion: 1903-2003 J. Propul. Power 2003, 19, 1089-1105
2. Huang, H.; Spadaccini, L. J.; Sobel, D. R. Fuel-cooled thermal management for advanced aeroengines J. Eng. Gas Turbines Power 2004, 126, 284-293
3. Maurice, L. Q.; Lander, H.; Edwards, T.; Harrison, W. E. Advanced aviation fuels: a look ahead via a historical perspective Fuel 2001, 80, 747-756
4. Jiang, R. P.; Liu, G. Z.; Zhang, X. W. Thermal cracking of hydrocarbon aviation fuels in regenerative cooling microchannels Energy Fuels 2013, 27, 2563-2577
5. Venkataraman, R.; Eser, S. Characterization of solid deposits formed from short durations of jet fuel degradation: carbonaceous solids Ind. Eng. Chem. Res. 2008, 47, 9337-9350
6. Billaud, F.; Chaverot, P.; Berthelin, M.; Freund, E. Thermal decomposition of cyclohexane at approximately 810 °C Ind. Eng. Chem. Res. 1988, 27, 759-764
7. 5 ring hydrocarbons under supercritical conditions Energy Fuels 2012, 26, 5121-5134
8. Gough, R. V.; Widegren, J. A.; Bruno, T. J. Thermal decomposition kinetics of 1,3,5-triisopropylcyclohexane Ind. Eng. Chem. Res. 2013, 52, 8200-8205
9. Widegren, J. A.; Bruno, T. J. Thermal decomposition kinetics of propylcyclohexane Ind. Eng. Chem. Res. 2009, 48, 645-659
10. Yu, J.; Eser, S. Thermal decomposition of jet fuel model compounds under near-critical and supercritical conditions. 1. n -butylbenzene and n -butylcyclohexane Ind. Eng. Chem. Res. 1998, 37, 4591-4600
11. Yu, J.; Eser, S. Thermal decomposition of jet fuel model compounds under near-critical and supercritical conditions. 2. decalin and tetralin Ind. Eng. Chem. Res. 1998, 37, 4601-4608
12. Xing, Y.; Fang, W. J.; Xie, W. J.; Guo, Y. S.; Lin, R. S. Thermal cracking of JP-10 under pressure Ind. Eng. Chem. Res. 2008, 47, 10034-10040
13. Song, C. S.; Eser, S.; Schobert, H. H.; Hatcher, P. G. Pyrolytic degradation studies of a coal-derived and a petroleum-derived aviation jet fuel Energy Fuels 1933, 7, 234-243
14. Sebastian, H. M.; Yao, J.; Lin, H. M.; Chao, K. C. Gas-liquid equilibrium of the hydrogen/bicyclohexyl systems at elevated temperature and pressures J. Chem. Eng. Data 1978, 23, 167-170
15. Proutiere, A.; Megnassan, E.; Hucteau, H. Refractive index and density variations in pure liquids. A new theoretical relation J. Phys. Chem. 1992, 96, 3485-3489
16. Ivanciuc, O.; Ivanciuc, T.; Filip, P. A.; Cabrol-Bass, D. Estimation of the liquid viscosity of organic compounds with a quantitative structure-property model J. Chem. Inf. Comput. Sci. 1999, 39, 515-524
17. Prugh, R. W. The relationship between flashpoint and LFL with application to hybrid mixtures Process Saf. Prog. 2008, 27, 156-163
18. NIST Standard Reference Database 69 (2001): NIST Chemistry WebBook, accessed via http://webbook.nist.gov/chemistry.
19. Zhang, L. L.; Guo, Y. S.; Xiao, J.; Gong, X. J.; Fang, W. J. Density, refractive index, viscosity, and surface tension of binary mixtures of exo -tetrahydrodicyclopentadiene with some n -alkanes from (293.15 to 313.15) K J. Chem. Eng. Data 2011, 56, 4268-4273
20. Vazhev, V. V.; Aldabergenov, M. K.; Vazheva, N. V. Estimation of flash points and molecular masses of alkanes from their IR spectra Pet. Chem. 2006, 46, 136-139
21. 11 n -alkanes J. Chem. Eng. Data 2013, 58, 2224-2232
22. Fabuss, B.; Kafesjian, R.; Smith, J. O.; Satterfield, C. N. Thermal decomposition rates of saturated cyclic hydrocarbons Ind. Eng. Chem. Proc. Res. Dev. 1964, 3, 248-254
23. 14 normal alkanes and their mixtures Ind. Eng. Chem. Res. 1997, 36, 585-591
24. Widegren, J. A.; Bruno, T. J. Thermal stability of RP-2 as a function of composition: the effect of linear, branched, and cyclic alkanes Energy Fuels 2013, 27, 5138-5143
25. Yue, L.; Lu, X.; Chi, H.; Guo, Y.; Xu, L.; Fang, W.; Li, Y.; Hu, S. Heat-sink enhancement of decalin and aviation kerosene prepared as nanofluids with palladium nanoparticles Fuel 2014, 121, 149-156
26. Uchiyama, M.; Tomioka, T.; Amano, A. Thermal decomposition of cyclohexene J. Phys. Chem. 1964, 68, 1878-1881
27. Tardy, D. C.; Ireton, R.; Gordon, A. S. Thermal decomposition of labeled cyclohexene. A complex reaction involving a forbidden 1,2-hydrogen elimination J. Am. Chem. Soc. 1979, 101, 1508-1514
28. Gaussian 09, Revison A.1; Frisch, M. J.; Trucks, G. W.; Schlegel, H. B.; Scuseria, G. E.; Robb, M. A.; Cheeseman, J. R.; Scalmani, G.; Barone, V.; Mennucci, B.; Petersson, G. A.; Nakatsuji, H.; Caricato, M.; Li, X.; Hratchian, H. P.; Izmaylov, A. F.; Bloino, J.; Zheng, G.; Sonnenberg, J. L.; Hada, M.; Ehara, M.; Toyota, K.; Fukuda, R.; Hasegawa, J.; Ishida, M.; Nakajima, T.; Honda, Y.; Kitao, O.; Nakai, H.; Vreven, T.; Montgomery, J. A.; Peralta, J.; Ogliaro, F.; Bearpark, M.; Heyd, J. J.; Brothers, E.; Kudin, K. N.; Staroverov, V. N.; Kobayashi, R.; Normand, J.; Raghavachari, K.; Rendell, A.; Burant, J. C.; Iyengar, S. S.; Tomasi, J.; Cossi, M.; Rega, N.; Millam, J. M.; Klene, M.; Knox, J. E.; Cross, J. B.; Bakken, V.; Adamo, C.; Jaramillo, J.; Gomperts, R.; Stratmann, R. E.; Yazyev, O.; Austin, A. J.; Cammi, R.; Pomelli, C.; Ochterski, J. W.; Martin, R. L.; Morokuma, K.; Zakrzewski, V. G.; Voth, G. A.; Salvador, P.; Dannenberg, J. J.; Dapprich, S.; Daniels, A. D.; Farkas, O.; Foresman, J. B.; Ortiz, J. V.; Cioslowski, J.; Fox, D. J. Gaussian, Inc.: Wallingford, CT, 2009.