Chiral monolayer-protected bimetallic Au-Ag nanoclusters: Alloying effect on their electronic structure and chiroptical activity

Journal of Physical Chemistry C

Volumn 118, Issue 28, 2014, Pages 15506-15515

  Kobayashi, Ryota ^a   Nonoguchi, Yoshiyuki ^b   Sasaki, Akito ^c   Yao, Hiroshi ^a  

^a UNIVERSITY OF HYOGO   (Japan)

^b NARA INSTITUTE OF SCIENCE AND TECHNOLOGY   (Japan)

^c RIGAKU CORPORATION   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ELECTRONIC STRUCTURE; ISOMERS; X RAY PHOTOELECTRON SPECTROSCOPY;

CHEMICAL COMPOSITIONS; ELECTROPHORETIC SEPARATIONS; GEOMETRICAL ISOMERS; OPTICAL ISOMERS; OPTICAL SPECTROSCOPY; PATTERN SIMILARITY; SMALL ANGLE X-RAY SCATTERING; STATISTICAL DISTRIBUTION;

NANOCLUSTERS;

EID: 84904565669     PISSN: 19327447     EISSN: 19327455     Source Type: Journal    
DOI: 10.1021/jp503676b     Document Type: Article

References (52)

1. Ferrando, R.; Jellinek, J.; Johnston, R. L. Nanoalloys: From Theory to Applications of Alloy Clusters and Nanoparticles Chem. Rev. 2008, 108, 845-910 (Pubitemid 351577853)
2. Toshima, N.; Yonezawa, T. Bimetallic Nanoparticles- Novel Materials for Chemical and Physical Applications New J. Chem. 1998, 22, 1179-1201 (Pubitemid 128710042)
3. Chaudhuri, R. G.; Paria, S. Core/Shell Nanoparticles: Classes, Properties, Synthesis Mechanisms, Characterization, and Applications Chem. Rev. 2012, 112, 2373-2433
4. Cortie, M. B.; McDonagh, A. M. Synthesis and Optical Properties of Hybrid and Alloy Plasmonic Nanoparticles Chem. Rev. 2011, 111, 3713-3735
5. n (M = Ag, Cu; n = 1-10) Clusters J. Phys. Chem. A 2011, 115, 569-576
6. Frenkel, A. I.; Machavariani, V. S.; Rubshtein, A.; Rosenberg, Y.; Voronel, A.; Stern, E. A. Local Structure of Disordered Au-Cu and Au-Ag Alloys Phys. Rev. B 2000, 62, 9364-9371 (Pubitemid 32336083)
7. Link, S.; Wang, Z. L.; El-Sayed, M. A. Alloy Formation of Gold-Silver Nanoparticles and the Dependence of the Plasmon Absorption on Their Composition J. Phys. Chem. B 1999, 103, 3529-3533 (Pubitemid 129702397)
8. Jin, R. Quantum Sized, Thiolate-Protected Gold Nanoclusters Nanoscale 2010, 2, 343-362
9. 18 Acc. Chem. Res. 2010, 43, 1289-1296
10. Jadzinsky, P. D.; Calero, G.; Ackerson, C. J.; Bushnell, D. A.; Kornberg, R. D. Structure of a Thiol Monolayer-Protected Gold Nanoparticle at 1.1 Å Resolution Science 2007, 318, 430-433 (Pubitemid 47614523)
11. Walter, M.; Akola, J.; Lopez-Acevedo, O.; Jadzinsky, P. D.; Calero, G.; Ackerson, C. J.; Whetten, R. L.; Grönbeck, H.; Häkkinen, H. A Unified View of Ligand-Protected Gold Clusters as Superatom Complexes Proc. Natl. Acad. Sci. U.S.A. 2008, 105, 9157-9162
12. Häkkinen, H. The Gold-Sulfur Interface at the Nanoscale Nat. Chem. 2012, 4, 443-455
13. - (n = 1, 2, 4, 6, 8, 10, 12) Bimetallic Nanoclusters J. Phys. Chem. C 2012, 116, 20617-20624
14. 18 Cluster J. Phys. Chem. C 2013, 117, 7914-7923
15. 25 Cluster by Ag Doping Chem. Commun. 2010, 46, 4713-4715
16. 60 Alloy Nanomolecules Nanoscale 2011, 3, 3064-3067
17. 6: A 13-Atom Alloy Quantum Cluster Angew. Chem., Int. Ed. 2012, 51, 2155-2159
18. Gottlieb, E.; Qian, H.; Jin, R. Atomic Level Alloying and De-alloying in Doped Gold Nanoparticles Chem.-Eur. J. 2013, 19, 4238-4243
19. Yao, H.; Miki, K.; Nishida, N.; Sasaki, A.; Kimura, K. Large Optical Activity of Gold Nanocluster Enantiomers induced by a Pair of Optically Active Penicillamines J. Am. Chem. Soc. 2005, 127, 15536-15543 (Pubitemid 41572528)
20. Yao, H. Optically Active Gold Nanoclusters Curr. Nanosci. 2008, 4, 92-97 (Pubitemid 351513465)
21. Yao, H.; Kobayashi, R. Chiral Monolayer-Protected Au-Pd Bimetallic Nanoclusters: Effect of Palladium Doping on their Chiroptical Responses J. Colloid Interface Sci. 2014, 419, 1-8
22. 38 Clusters Protected by Achiral Ligands Nat. Commun. 2012, 3, 798
23. Knoppe, S.; Bürgi, T. Chirality in Thiolate-Protected Gold Clusters Acc. Chem. Res. 2014, 47, 1318-1326
24. Farrag, M.; Tschurl, M.; Heiz, U. Chiral Gold and Silver Nanoclusters: Preparation, Size Selection, and Chiroptical Properties Chem. Mater. 2013, 25, 862-870
25. n Clusters Protected by Glutathione Monolayers (n = 18, 21, 25, 28, 32, 39): Isolation and Spectroscopic Characterization J. Am. Chem. Soc. 2004, 126, 6518-6519 (Pubitemid 38697329)
26. Sellers, H.; Ulman, A.; Shnidman, Y.; Eilers, J. E. Structure and Binding of Alkanethiolates on Gold and Silver Surfaces: Implications for Self-Assembled Monolayers J. Am. Chem. Soc. 1993, 115, 9389-9401
27. Kumar, S.; Bolan, M. D.; Bigioni, T. P. Glutathione-Stabilized Magic-Number Silver Cluster Compounds J. Am. Chem. Soc. 2010, 132, 13141-13143
28. 19 Anal. Chem. 2012, 84, 5304-5308
29. Negishi, Y.; Nobusada, K.; Tsukuda, T. Glutathione-Protected Gold Clusters Revisited: Bridging the Gap Between Gold(I)-Thiolate Complexes and Thiolate-Protected Gold Nanocrystals J. Am. Chem. Soc. 2005, 127, 5261-5270 (Pubitemid 40523484)
30. 18 Nanoclusters J. Phys. Chem. C 2012, 116, 26932-26937
31. 8 Clusters by Interfacial Synthesis Angew. Chem., Int. Ed. 2010, 49, 3925-3929
32. Weaver, J. F.; Hoflund, G. B. Surface Characterization Study of the Thermal Decomposition of AgO J. Phys. Chem. 1994, 98, 8519-8524
33. CRC Handbook of Chemistry and Physics, 77 th ed.; Lide, D. R., Ed.; CRC Press: Boca Raton, FL, 1996-1997.
34. Mallin, M. P.; Murphy, C. J. Solution-Phase Synthesis of Sub-10 nm Au-Ag Alloy Nanoparticles Nano Lett. 2002, 2, 1235-1237 (Pubitemid 135706502)
35. Kariuki, N. N.; Luo, J.; Maye, M. M.; Hassan, S. A.; Menard, T.; Naslund, H. R.; Lin, Y.; Wang, C.; Engelhard, M. H.; Zhong, C.-J. Composition-Controlled Synthesis of Bimetallic Gold-Silver Nanoparticles Langmuir 2004, 20, 11240-11246
36. - Alloy J. Phys. Chem. Lett. 2014, 5, 461-466
37. - Nanoparticles (M = Au, Ag) J. Phys. Chem. C 2008, 112, 19797-19800
38. Walter, M.; Moseler, M. Ligand-Protected Gold Alloy Clusters: Doping the Superatom J. Phys. Chem. C 2009, 113, 15834-15837
39. 24 Nanoparticles J. Am. Chem. Soc. 2005, 127, 12140-12143 (Pubitemid 41233742)
40. Muhammed, M. A.; Shaw, A. K.; Pal, S. K.; Pradeep, T. Quantum Clusters of Gold Exhibiting FRET J. Phys. Chem. C 2008, 112, 14324-14330
41. Link, S.; Beeby, A.; FitzGerald, S.; El-Sayed, M. A.; Schaaff, T. G.; Whetten, R. L. Visible to Infrared Luminescence from a 28-Atom Gold Cluster J. Phys. Chem. B 2002, 106, 3410-3415 (Pubitemid 35290238)
42. 38 Nanoparticles J. Am. Chem. Soc. 2004, 126, 6193-6199 (Pubitemid 38637987)
43. 25 Clusters J. Phys. Chem. C 2010, 114, 22417-22423
44. Wu, Z.; Jin, R. On the Ligand's Role in the Fluorescence of Gold Nanoclusters Nano Lett. 2010, 10, 2568-2573
45. Corma, A.; Serna, P. Chemoselective Hydrogenation of Nitro Compounds with Supported Gold Catalysts Science 2006, 313, 332-334 (Pubitemid 44480953)
46. 25 Nanoparticle Catalyst for Hydrogenation of Cyclic Ketone J. Catal. 2010, 271, 155-160
47. Au and the N -isobutyryl- l -cysteine-protected Au nanocluster with comparable size, which was reported in this ref 47. Because glutathione is a linear tripeptide composed of l -glutamine, l -cysteine, and glycine, their chiroptical responses may be overall governed by a chiral cysteine moiety in the ligands that can be directly attached to the Au atoms. Gautier, C.; Bürgi, T. Chiral N -Isobutyryl-cysteine Protected Gold Nanoparticles: Preparation, Size Selection, and Optical Activity in the UV-vis and Infrared J. Am. Chem. Soc. 2006, 128, 11079-11087 (Pubitemid 44300117)
48. 25 Nanospheres and Nanorods: Synthesis and Insight into the Origin of Chirality Nano Lett. 2011, 11, 3963-3969
49. 14 cluster Phys. Chem. Chem. Phys. 2012, 14, 3737-3740
50. Noguez, C.; Sanchez-Castillo, A.; Hidalgo, F. Role of Morphology in the Enhanced Optical Activity of Ligand-Protected Metal Nanoparticles J. Phys. Chem. Lett. 2011, 2, 1038-1044
51. m of Low Nuclearities J. Phys. Chem. A 2010, 114, 10345-10356
52. Matsuoka, N.; Hidaka, J.; Shimura, Y. Absorption and Circular Dichroism Spectra of Oxalatobis(aminoacidato)cobaltate(III) Complexes Inorg. Chem. 1970, 9, 719-723