Three-step method to determine the eutectic composition of binary and ternary mixtures: Tested on two novel eutectic phase change materials based on salt hydrates

Journal of Thermal Analysis and Calorimetry

Volumn 117, Issue 2, 2014, Pages 595-602

  Schmit, Henri ^a   Rathgeber, Christoph ^a   Hennemann, Peter ^a   Hiebler, Stefan ^a  

^a BAVARIAN CENTER FOR APPLIED ENERGY RESEARCH ZAE BAYERN   (Germany)

Author keywords

DSC; Eutectic; Phase change material; Salt hydrate; T History method; Temperature composition diagram

Indexed keywords

DIFFERENTIAL SCANNING CALORIMETRY; HYDRATES; HYDRATION; MANGANESE; MIXTURES; PHASE CHANGE MATERIALS; ZINC;

BINARY AND TERNARY MIXTURES; DSC; EUTECTIC COMPOSITION; LIQUIDUS TEMPERATURE; SALT HYDRATES; T-HISTORY METHOD; TEMPERATURE RANGE; TEMPERATURE-COMPOSITION;

EUTECTICS;

EID: 84904514492     PISSN: 13886150     EISSN: None     Source Type: Journal    
DOI: 10.1007/s10973-014-3783-6     Document Type: Article

References (22)

1. Mehling H, Cabeza LF. Heat and cold storage with PCM. Berlin: Springer; 2008.
2. Jeon J, Lee J-H, Seo J, Jeong S-G, Kim S. Application of pcm thermal energy storage system to reduce building energy consumption. J Therm Anal Calorim. 2013;111: 279-88.
3. Zhai XQ, Wang XL, Wang T, Wang RZ. A review on phase change cold storage in air conditioning system: Materials and applications. Renew Sust Energy Rev. 2013;22: 108-20.
4. Cabeza LF, Castell A, Barreneche C, de Gracia A, Fernández AI. Materials used as pcm in thermal energy storage in buildings: A review. Renew Sust Energy Rev. 2011;15: 1675-95.
5. Farid MM, Khudhair AM, Siddique AKR, Said A-H. A review on phase energy storage: Materials and applications. Eenergy Convers Manage. 2004;45(15): 97-1615.
6. Nagano K, Mochida T, Takeda S, Domnski R, Rebow M. Thermal characteristics of manganese (ii) nitrate hexahydrate as a phase change material for cooling systems. Appl Therm Eng. 2003;23: 229-41.
7. Lane GA. Solar heat storage: Latent heat material, vol. II. Boca Raton: CRC Press, Inc.; 1986.
8. Benrath A, Hartung P, Wilden M. Über die anwendung der auftau-schmelzmethode auf anorganische binäre systeme. J Prakt Chem. 1935;143: 298-304.
9. Marcus Y, Minevich A, Ben-Dor L. Solid-liquid phase diagram of binary salt hydrate mixtures involving magnesium nitrate and acetate, magnesium and aluminum nitrate, ammonium alum and sulfate, and ammonium alum and aluminum sulfate. Thermochim Acta. 2004;412: 163-70.
10. Marcus Y, Minevich A, Ben-Dor L. Solid-liquid phase equilibria of binary salt hydrate mixtures involving ammonium alum. J Therm Anal Calorim. 2005;81: 51-5.
11. Benessam S, Khimeche K, Djellouli F, Benziane M, Dahmani A. Phase diagram of ibuprofen with fatty acids. J Therm Anal Calorim. 2013;112: 317-20.
12. Rycerz L. Practical remarks concerning phase diagram determination on the basis of differential scanning calorimetry measurements. J Therm Anal Calorim. 2013;113: 231-8.
13. Günther E, Hiebler S, Mehling H, Redlich R. Enthalpy of phase change materials as a function of temperature: Required accuracy and suitable measurement methods. Int J Thermophys. 2009;30: 1257-69.
14. Kousksou T, Jamil A, Zeraouli Y, Dumas J-P. Equilibrium system liquidus temperatures of binary mixtures from differential scanning calorimetry. Chem Eng Sci. 2007;62: 6516-23.
15. Ewing WW, McGovern JJ, Mathews GE. The temperature-composition relations of the binary system zinc nitrate-water. J Am Chem Soc. 1933;55: 4827-30.
16. 3 i. les isothermes-25 et-20-C. J Therm Anal Calorim. 2003;74: 341-7.
17. Purdon FF, Slater VW. Aqueous solution and the phase diagram. London: Edward Arnold & CO; 1946.
18. Dellien I. A dsc study of the phase transformations of ammonium nitrate. Thermochim Acta. 1982;55: 181-91.
19. 24 LEA, SHC Task 42/ECES Annex. Compact thermal energy storage. http://task42.iea-shc.org
20. Lázaro A, Günther E, Mehling H, Hiebler S, Marín JM, Zalba B. Verification of a t-history installation to measure enthalpy versus temperature curves of phase change materials. Meas Sci Technol. 2006;17: 2168-74.
21. Rathgeber C, Schmit H, Hennemann P, Hiebler S. Calibration of a t-history calorimeter to measure enthalpy curves of phase change materials in the temperature range from 40 to 200 8C. Meas Sci Technol. 2014;25: 035011.
22. Abhat A. Low temperature latent heat storage: I: Heat storage materials; II: Heat transfer considerations. Ispra: Ispra Courses; 1981.