A new sealed lithium-peroxide battery with a co-doped Li2O cathode in a superconcentrated lithium bis(fluorosulfonyl)amide electrolyte

Scientific Reports

Volumn 4, Issue , 2014, Pages

  Okuoka, Shin Ichi ^a   Ogasawara, Yoshiyuki ^b   Suga, Yosuke ^b   Hibino, Mitsuhiro ^b   Kudo, Tetsuichi ^b   Ono, Hironobu ^a   Yonehara, Koji ^a   Sumida, Yasutaka ^a   Yamada, Yuki ^b   Yamada, Atsuo ^b   Oshima, Masaharu ^b   Tochigi, Eita ^b   Shibata, Naoya ^b   Ikuhara, Yuichi ^b   Mizuno, Noritaka ^b  

^a NIPPON SHOKUBAI CO LTD   (Japan)

^b UNIVERSITY OF TOKYO   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 84904490727     PISSN: None     EISSN: 20452322     Source Type: Journal    
DOI: 10.1038/srep05684     Document Type: Article

References (24)

1. Poizot, P., Laruelle, S., Grugeon, S., Dupont, L. & Tarascon, J-M. Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries. Nature 407, 496-499 (2000).
2. Bervas, M. et al. Investigation of the lithiation and delithiation conversion mechanisms of bismuth fluoride nanocomposites. J. Electrochem. Soc. 153, A799-A808 (2006).
3. Badway, F., Pereira, N., Cosandey, F. & Amatucci, G. G. Carbon-metal fluoride nanocomposites structure and electrochemistry of FeF3:C. J. Electrochem. Soc. 150, A1209-A1218 (2003).
4. Abraham, K. M. & Jiang, Z. A polymer electrolyte-based rechargeable lithium/ oxygen battery. J. Electrochem. Soc. 143, 1-5 (1996).
5. Ogasawara, T., Débart, A., Holzapfel, M., Novák, P. & Bruce, P. G. Rechargeable Li2O2 electrode for lithium batteries. J. Am. Chem. Soc. 128, 1390-1393 (2006).
6. Zhang, S. S., Foster, D. & Read, J. Discharge characteristic of a non-aqueous electrolyte Li/O2 battery. J. Power Sources 195, 1235-1240 (2010).
7. Lu, Y.-C., Gasteiger, H. A., Crumlin, E., McGuire, Jr, R. & Shao-Horn, Y. Electrocatalytic activity studies of select metal surfaces and implications in Li-air batteries. J. Electrochem. Soc. 157, A1016-A1025 (2010).
8. Thapa, A. K. & Ishihara, T. Mesoporous a-MnO2/Pd catalyst air electrode for rechargeable lithium-air battery. J. Power Sources 196, 7016-7020 (2011).
9. Trahan, M. J. et al. Cobalt phthalocyanine catalyzed lithium-air batteries. J. Electrochem. Soc. 160, A1577-A1586 (2013).
10. Sathiya, M. et al. Reversible anionic redox chemistry in high-capacity layeredoxide electrodes. Nat. Mater. 12, 827-835 (2013).
11. Sathiya, M. et al. High performance Li2Ru12yMnyO3 (0.2 # y # 0.8) cathode materials for rechargeable lithium-ion batteries: Their understanding. Chem. Mater. 25, 1121-1131 (2013).
12. Koga, H. et al. Different oxygen redox participation for bulk and surface: A possible global explanation for the cycling mechanism of Li1.20Mn0.54Co0.13Ni0.13O2. J. Power Sources 236, 250-258 (2013).
13. Yoon, W. et al. Oxygen contribution on Li-ion intercalation- deintercalation in LiCoO2 investigated by O K-edge and Co L-edge X-ray absorption spectroscopy. J. Phys. Chem. B 106, 2526-2532 (2002).
14. Yamada, Y. et al. Unusual stability of acetonitrile-based superconcentrated electrolytes for fast-charging lithium-ion batteries. J. Am. Chem. Soc. 136, 5039-5046 (2014).
15. Antaya, M., Cearns, K., Preston, J. S., Reimers, J. N. & Dahn, J. R. In situ growth of layered, spinel, and rock-salt LiCoO2 by laser ablation deposition. J. Appl. Phys. 76, 2799-2806 (1994).
16. Moen, A. et al. X-ray absorption spectroscopic studies at the cobalt K-edge on a reduced Al2O3-supported rhenium-promoted cobalt Fischer-Tropsch catalyst. Chem. Mater. 9, 1241-1247 (1997).
17. Wu, Z. et al. Symmetry dependence of x-ray absorption near-edge structure at the metal K edge of 3d transition metal compounds. Appl. Phys. Lett. 79, 1918-1920 (2001).
18. Garcia, B., Farcy, J., Pereira-Ramos, J. P. & Baffier, N. Electrochemical properties of low temperature crystallized LiCoO2. J. Electrochem. Soc. 144, 1179-1184 (1997).
19. Narukawa, S. et al. Anti-fluorite type Li6CoO4, Li5FeO4, and Li6MnO4 as the cathode for lithium secondary batteries. Solid State Ionics 122, 59-64 (1999).
20. Luge, R. & Hoppe, R. A new cobaltate with isolated anion structure: Li6[CoO4]. Z. Anorg. Allg. Chem. 534, 61-68 (1986).
21. Pistoia, G., Zane, D.& Zhang, Y. Some aspects of LiMn2O4 electrochemistry in the 4 volt range. J. Electrochem. Soc. 142, 2551-2557 (1995).
22. Freunberger, S. A. et al. Reactions in the rechargeable lithium-O2 battery with alkyl carbonate electrolytes. J. Am. Chem. Soc. 133, 8040-8047 (2011).
23. McCloskey, B. D., Bethune, D. S., Shelby, R. M., Girishkumar, G. & Luntz, A. C. Solvents' critical role in nonaqueous lithium-oxygen battery electrochemistry. J. Phys. Chem. Lett. 2, 1161-1166 (2011).
24. Ottakam Thotiyl, M. M., Freunberger, S. A., Peng, Z. & Bruce, P. G. The carbon electrode in nonaqueous Li-O2 cells. J. Am. Chem. Soc. 135, 494-500 (2013).