A novel chemoselective cleavage of (tert-butyl)(dimethyl)silyl (TBS) ethers catalyzed by Ce(SO4)2·4 H2O

Helvetica Chimica Acta

Volumn 97, Issue 7, 2014, Pages 965-972

  González Calderón, Davir ^a   González González, Carlos A ^a   Fuentes Benítez, Aydeé ^a   Cuevas Yáñez, Erick ^a   Corona Becerril, David ^a   González Romero, Carlos ^a  

^a UNIVERSIDAD AUTÓNOMA DEL ESTADO DE MÉXICO   (Mexico)

Author keywords

(tert Butyl)(dimethyl)silyl (TBS) ethers; Alcohols; Catalysis; Cesium(IV) sulfate catalyst

Indexed keywords

ALCOHOLS; CATALYSIS; SILICON;

CATALYTIC AMOUNTS; CHEMOSELECTIVE; CHEMOSELECTIVE DEPROTECTION; COMPETITIVE EXPERIMENTS; CONVENTIONAL HEATING; HYDROXY COMPOUNDS; MICROWAVE-ASSISTED;

ETHERS;

(TERT BUTYL)(DIMETHYL)SILYL; ALKYL ETHER; DIPHENYL ETHER DERIVATIVE; ETHER DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; DRUG SELECTIVITY; HEATING; MICROWAVE RADIATION; PRIORITY JOURNAL;

EID: 84904410528     PISSN: 0018019X     EISSN: 15222675     Source Type: Journal    
DOI: 10.1002/hlca.201300354     Document Type: Article

References (6)

1. T. W. Greene, P. G. M. Wuts, 'Protective Groups in Organic Synthesis', 3rd edn., John Wiley & Sons, Inc., New York, 1999, p. 113.
2. R. Dureau, L. Legentil, R. Daniellou, V. Ferrières, J. Org. Chem. 2012, 77, 1301; J. K. Rout, C. V. Ramana, J. Org. Chem. 2012, 77, 1566; T. S. Kumar, S. Y. Zhou, B. V. Joshi, R. Balasubramanian, T. Yang, B. T. Liang, K. A. Jacobson, J. Med. Chem. 2010, 53, 2562; M. Petrovaì, M. Budesiìnskyì, E. Zborniìkovaì, P. Fiedler, I. Rosenberg, Org. Lett. 2011, 13, 4200.
3. J. R. Hwu, M. L. Jain, F. Y. Tsai, S. C. Tsay, A. Balakumar, G. H. Hakimelahi, J. Org. Chem. 2000, 65, 5077.
4. A. DattaGupta, R. Singh, V. Singh, Synlett 1996, 69.
5. S. V. Ankala, G. Fenteany, Tetrahedron Lett. 2002, 43, 4729.
6. G. Bartoli, G. Cupone, R. Dalpozzo, A. De Nino, L. Maiuolo, A. Procopio, L. Sambri, A. Tagarelli, Tetrahedron Lett. 2002, 43, 5945.