K+-doped Li1.2Mn0.54Co 0.13Ni0.13O2: A novel cathode material with an enhanced cycling stability for lithium-ion batteries

ACS Applied Materials and Interfaces

Volumn 6, Issue 13, 2014, Pages 10330-10341

  Li, Qi ^a   Li, Guangshe ^a   Fu, Chaochao ^b   Luo, Dong ^b   Fan, Jianming ^b   Li, Liping ^b  

^a FUJIAN INSTITUTE OF RESEARCH ON THE STRUCTURE OF MATTER   (China)

^b FUJIAN INSTITUTE OF RESEARCH ON THE STRUCTURE OF MATTER   (China)

Author keywords

cycling stability; Li rich layered oxides; lithium ion batteries; phase transition

Indexed keywords

CATHODES; LITHIUM BATTERIES; LITHIUM COMPOUNDS; MANGANESE; MANGANESE OXIDE; NICKEL; PHASE TRANSITIONS; STABILITY;

CATH-ODE MATERIALS; CYCLING PERFORMANCE; CYCLING STABILITY; LAYERED OXIDES; LAYERED STRUCTURES; LITHIUM-ION BATTERY; SPINEL STRUCTURE; STERIC HINDRANCES;

LITHIUM;

EID: 84904106202     PISSN: 19448244     EISSN: 19448252     Source Type: Journal    
DOI: 10.1021/am5017649     Document Type: Article

References (55)

1. 3 Chem. Commun. 2002, 2790-2791
2. 2 (M = Mn, Ni, Co) Electrodes for Lithium-Ion Batteries J. Mater. Chem. 2007, 17, 3053-3272
3. 2 J. Am. Chem. Soc. 2011, 133, 4404-4419
4. 2) for Lithium-Ion Batteries J. Phys. Chem. Lett. 2013, 4, 1268-1280
5. Song, B.; Liu, H.; Liu, Z.; Xiao, P.; Lai, M. O.; Lu, L. High Rate Capability Caused by Surface Cubic Spinels in Li-Rich Layer-Structured Cathodes for Li-Ion Batteries Sci. Rep. 2013, 3, 3094
6. 2 Nanomaterials by a Molten-Salt Method: towards a High Capacity and High Power Cathode for Rechargeable Lithium Batteries J. Mater. Chem. 2012, 22, 25380-25387
7. 2 with an Excellent Eectrochemical Performance from -10.4 to 45.4 °C J. Mater. Chem. A 2013, 1, 1220-1227
8. 2 Composites with High Capacity and Superior Rate Capability for Lithium-Ion Batteries J. Mater. Chem. A 2014, 2, 1471-1483
9. 2 with Improved Rate Capability J. Power Sources 2013, 228, 14-23
10. 2 Cathode Material for Lithium-Ion Batteries via Aerogel Template J. Power Sources 2013, 240, 140-148
11. 2 (M = Ni, Mn, Co) Li-Ion Cathodes by a Ball Milling-Annealing Process J. Power Sources 2012, 204, 200-204
12. Lee, J.; Urban, A.; Li, X.; Su, D.; Hautier, G.; Ceder, G. Unlocking the Potential of Cation-Disordered Oxides for Rechargeable Lithium Batteries Science 2014, 343, 519-522
13. 2 for Li-Ion Batteries Chem. Mater. 2013, 25, 2319-2326
14. Gu, M.; Belharouak, I.; Zheng, J.; Wu, H.; Xiao, J.; Genc, A.; Amine, K.; Thevuthasan, S.; Baer, D. R.; Zhang, J.-G. Formation of the Spinel Phase in the Layered Composite Cathode Used in Li-Ion Batteries ACS Nano 2012, 7, 760-767
15. 2 Nanoparticles by a Layered-Template Route for High-Performance Li-Ion Batteries Eur. J. Inorg. Chem. 2013, 2013, 2887-2892
16. Xu, B.; Fell, C. R.; Chi, M.; Meng, Y. S. Identifying Surface Structural Changes in Layered Li-Excess Nickel Manganese Oxides in High Voltage Lithium Ion Batteries: A joint Experimental and Theoretical Study Energy Environ. Sci. 2011, 4, 2223-2233
17. Song, B.; Liu, Z.; Lai, M. O.; Lu, L. Structural Evolution and the Capacity Fade Mechanism upon Long-Term Cycling in Li-Rich Cathode Material Phys. Chem. Chem. Phys. 2012, 14, 12875-12883
18. 2 Lithium-Ion Battery Cathode during High-Voltage Hold (4.5 V) via Magnetic, X-ray Diffraction and Electron Microscopy Studies J. Mater. Chem. A 2013, 1, 6249-6261
19. Lee, E.-S.; Manthiram, A. Smart Design of Lithium-Rich Layered Oxide Cathode Compositions with Suppressed Voltage Decay J. Mater. Chem. A 2014, 2, 3932-3939
20. Zheng, J.; Gu, M.; Xiao, J.; Zuo, P.; Wang, C.; Zhang, J. G. Corrosion/Fragmentation of Layered Composite Cathode and Related Capacity/Voltage Fading during Cycling Process Nano Lett. 2013, 13, 3824-30
21. 2 J. Am. Chem. Soc. 2006, 128, 8694-8698
22. 2 J. Electrochem. Soc. 2002, 149, A778-A791
23. 3 and Related Li-Mn-O Materials J. Electrochem. Soc. 2011, 158, A1015-A1022
24. 2 Electrochem. Solid-State Lett. 2001, 4, A78-A81
25. 2 Cathode Material J. Mater. Chem. A 2013, 1, 11397-11403
26. Ates, M. N.; Jia, Q. Y.; Shah, A.; Busnaina, A.; Mukerjee, S.; Abraham, K. M. Mitigation of Layered to Spinel Conversion of a Li-Rich Layered Metal Oxide Cathode Material for Li-Ion Batteries J. Electrochem. Soc. 2014, 161, A290-A301
27. 2 Microspheres and Their Capacitance Colloids Surf., A 2010, 363, 64-70
28. 4 from Alpha Manganese Dioxide Nanorods J. Power Sources 2008, 184, 494-497
29. Toby, B. H. EXPGUI, A Graphical User Interface for GSAS J. Appl. Crystallogr. 2001, 34, 210-213
30. 2 Cathode for Li-Ion Batteries Electrochim. Acta 2012, 80, 187-195
31. 2 J. Electrochem. Soc. 2013, 160, A786-A792
32. 2O Incorporation Chem. Mater. 2013, 25, 2515-2526
33. 2: Cationic Effect on Hydrothermal Crystallization Nanotechnology 2008, 19, 225606
34. 2 as Cathode Material for Lithium Ion Battery Electrochem. Commun. 2007, 9, 1228-1232
35. Luo, D.; Li, G.; Fu, C.; Zheng, J.; Fan, J.; Li, Q.; Li, L. A New Spinel-Layered Li-Rich Microsphere as a High-Rate Cathode Material for Li-Ion Batteries Adv. Energy Mater. 2014, 10.1002/aenm.201400062
36. 2 in Lithium-Ion Batteries with an Anomalous Capacity and Cycling Stability at 45.4°C Scr. Mater. 2012, 66, 300-303
37. 3: Difference between La-Deficient and Sr-Substituting Effects Phys. Rev. B 1997, 56, 979-982
38. 4 Spinel: Cationic Order and Particle Size Distribution J. Phys. Chem. C 2011, 115, 25170-25182
39. 4 ACS Appl. Mater. Interfaces 2014, 6, 2439-2449
40. 2 for Lithium-Ion Batteries J. Mater. Chem. A 2013, 1, 9721
41. Kuch, W.; Schulze, M.; Schnurnberger, W.; Bolwin, K. XPS Lineshape Analysis of Potassium Coadsorbed with Water on Ni (111) Surf. Sci. 1993, 287, 600-604
42. 2C Catalysts Fuel 2007, 86, 1298-1303
43. 2C Catalysts for Mixed Alcohols Synthesis via Syngas Catal. Commun. 2007, 8, 513-518
44. Kang, K.; Meng, Y. S.; Breger, J.; Grey, C. P.; Ceder, G. Electrodes with High Power and High Capacity for Rechargeable Lithium Batteries Science 2006, 311, 977-80
45. Ceder, G. Opportunities and Challenges for First-Principles Materials Design and Applications to Li Battery Materials MRS Bull. 2011, 35, 693-701
46. 2 Electrode Materials: Structural, Magnetic, and Electrochemical Studies J. Electrochem. Soc. 1996, 143, 1168-1175
47. Ates, M. N.; Mukerjee, S.; Abraham, K. M. A Li-Rich Layered Cathode Material with Enhanced Structural Stability and Rate Capability for Li-Ion Batteries J. Electrochem. Soc. 2014, 161, A355-A363
48. 2: Optimized Synthesis and Applications as Advanced High-Voltage Cathode for Batteries Working at Elevated Temperatures Electrochim. Acta 2012, 81, 283-291
49. 2 as a High Performance Cathode Material for Li-Ion Batteries to Operate between -10.4 and 45.4 °C J. Mater. Chem. 2012, 22, 22233-22241
50. He, P.; Yu, H.; Zhou, H. Layered Lithium Transition Metal Oxide Cathodes towards High Energy Lithium-Ion Batteries J. Mater. Chem. 2012, 22, 3680-3695
51. Thackeray, M. M.; Johnson, C. S.; Vaughey, J. T.; Li, N.; Hackney, S. A. Advances in Manganese-Oxide "Composite" Electrodes for Lithium-Ion Batteries J. Mater. Chem. 2005, 15, 2257-2267
52. 2 (M = Ni, Mn, Co) J. Power Sources 2012, 218, 34-38
53. 3 after Partial Delithiation and Re-Lithiation Adv. Energy Mater. 2013, 3, 1358-1367
54. 2 Compounds upon Alkali De-intercalation Phys. Chem. Chem. Phys. 2012, 14 (44) 15571-8
55. Van Der Ven, A.; Ceder, G. In Lithium Batteries: Science and Technology; Nazri, G. A.; Pistoia, G., Eds.; Springer: New York, 2009; Chapter 2, pp 71-78.