Two lanthanide(III)-copper(II) chains based on [Cu2Ln 2] clusters exhibiting high stability, magnetocaloric effect and slow magnetic relaxation

Chinese Chemical Letters

Volumn 25, Issue 6, 2014, Pages 829-834

  Miao, Xiao Hong ^a   Han, Song De ^a   Liu, Sui Jun ^a   Bu, Xian He ^a  

^a NANKAI UNIVERSITY   (China)

Author keywords

3d 4f; High stability; Magnetocaloric effect; Slow magnetic relaxation

Indexed keywords

EID: 84904071233     PISSN: 10018417     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.cclet.2014.05.025     Document Type: Article

References (55)

1. A. Bencini, C. Benelli, and A. Caneschi et al. Crystal and molecular structure of and magnetic coupling in two complexes containing gadolinium(III) and copper(II) ions J. Am. Chem. Soc. 107 1985 8128 8136
2. R.E.P. Winpenny The structures and magnetic properties of complexes containing 3d- and 4f-metals Chem. Soc. Rev. 27 1998 447 452
3. M. Sakamoto, K. Manseki, and H. Okawa d-f Heteronuclear complexes: synthesis, structures and physicochemical aspects Coord. Chem. Rev. 219 2001 379 414 (Pubitemid 32936589)
4. C. Benelli, and D. Gatteschi Magnetism of lanthanides in molecular materials with transition-metal ions and organic radicals Chem. Rev. 102 2002 2369 2388
5. tbutyl-diethanolamine: synthesis, structures, and magnetic properties Inorg. Chem. 48 2009 6713 6723
6. O. Kahn Chemistry and physics of supramolecular magnetic materials Acc. Chem. Res. 33 2000 647 657
7. 2O (DMF = N,N-dimethylformamide) J. Am. Chem. Soc. 125 2003 12396 12397 (Pubitemid 37264929)
8. 12Gd} cluster Angew. Chem. Int. Ed. 48 2009 521 524
9. 4} ring Angew. Chem. Int. Ed. 49 2010 5185 5188
10. M. Evangelisti, F. Luis, L.J. de Jongh, and M. Affronte Magnetothermal properties of molecule-based materials J. Mater. Chem. 16 2006 2534 2549 (Pubitemid 43967678)
11. M. Evangelisti, and E.K. Brechin Recipes for enhanced molecular cooling Dalton Trans. 39 2010 4672 4676
12. 4+ clusters for magnetic refrigeration Angew. Chem. Int. Ed. 51 2012 4633 4636
13. J.B. Peng, Q.C. Zhang, and X.J. Kong et al. A 48-metal cluster exhibiting a large magnetocaloric effect Angew. Chem. Int. Ed. 50 2011 10649 10652
14. Y.Z. Zheng, M. Evangelisti, F. Tuna, and R.E.P. Winpenny Co-Ln mixed-metal phosphonate grids and cages as molecular magnetic refrigerants J. Am. Chem. Soc. 134 2012 1057 1065
15. Y.Z. Zheng, G.J. Zhou, Z.P. Zheng, and R.E.P. Winpenny Molecule-based magnetic coolers Chem. Soc. Rev. 43 2014 1462 1475
16. F.S. Guo, J.D. Leng, J.L. Liu, Z.S. Meng, and M.L. Tong Polynuclear and polymeric gadolinium acetate derivatives with large magnetocaloric effect Inorg. Chem. 51 2012 405 413
17. S.J. Liu, J.P. Zhao, and J. Tao et al. An unprecedented decanuclear GdIII cluster for magnetic refrigeration Inorg. Chem. 52 2013 9163 9165
18. 16 macrocycles exhibiting large magnetocaloric effect Cryst. Growth Des. 13 2013 4631 4634
19. Y.C. Chen, F.S. Guo, and Y.Z. Zheng et al. Gadolinium(III)-hydroxy ladders trapped in succinate frameworks with optimized magnetocaloric effect Chem. Eur. J. 19 2013 13504 13510
20. 48} barrel Chem. Eur. J. 19 2013 14876 14885
21. J.W. Sharples, and D. Collison Coordination compounds and the magnetocaloric effect Polyhedron 54 2013 91 103
22. L.Z. Chen, and D.D. Huang Synthesis, structure and dielectric properties of a novel Gd coordination polymer based on 2-(pyridin-4-yl)-1H-imidazole-4,5- dicarboxylate Chin. Chem. Lett. 25 2014 279 282
23. R. Sessoli, D. Gatteschi, A. Caneschi, and M.A. Novak Magnetic bistability in a metal-ion cluster Nature 365 1993 141 143
24. D.P. Mills, F. Moro, and J. McMaster et al. A delocalized arene-bridged diuranium single-molecule magnet Nat. Chem. 3 2011 454 460
25. J. Schwöbel, S.H. Fu, and J. Brede et al. Real-space observation of spin-split molecular orbitals of adsorbed single-molecule magnets Nat. Commun. 3 2012 953
26. D. Gatteschi, and R. Sessoli Quantum tunneling of magnetization and related phenomena in molecular materials Angew. Chem. Int. Ed. 42 2003 268 297 (Pubitemid 36181508)
27. 2} units Chem. Commun. 46 2010 2566 2568
28. 2 single-chain magnet J. Am. Chem. Soc. 134 2012 7521 7529
29. 7} cluster-containing sandwich-type phosphotungstate functionalized by organic bisphosphonate ligands and its two-dimensional supramolecular structure Chin. Chem. Lett. 24 2013 581 584
30. 2x] (1, Ln = Gd and x = 0.52. 2, Ln = Er and x = 0.90. phen = 1, 10-phenanthroline) Sci. China Chem. 55 2012 926 933
31. E. Ruiz, J. Cirera, and J. Cano et al. Can large magnetic anisotropy and high spin really coexist? Chem. Commun. 44 2008 52 54 (Pubitemid 350264889)
32. O. Waldmann A criterion for the anisotropy barrier in single-molecule magnets Inorg. Chem. 46 2007 10035 10037
33. R. Sessoli Molecular nanomagnetism in florence: advancements and perspectives Inorg. Chim. Acta 361 2008 3356 3364
34. 3] single-molecule magnets Chem. Eur. J. 14 2008 9117 9121
35. J. Yoo, W. Wernsdorfer, and E.C. Yang et al. One-dimensional chain of tetranuclear manganese single-molecule magnets Inorg. Chem. 44 2005 3377 3379 (Pubitemid 40758060)
36. 4] single-molecule magnets J. Am. Chem. Soc. 127 2005 17353 17363 (Pubitemid 41791054)
37. 4 complex linked by dicyanamide anion: from single-molecule magnet to classical magnet behavior J. Am. Chem. Soc. 128 2006 3770 3783
38. 6 single-molecule magnets Chem. Commun. 2009 2009 2023 2025
39. A.D. Katsenis, R. Inglis, A. Prescimone, E.K. Brechin, and G.S. Papaefstathiou Two-dimensional frameworks built from Single-Molecule Magnets CrystEngComm 14 2012 1216 1218
40. 2 single-molecule magnet Angew. Chem. Int. Ed. 48 2009 1319 1614
41. T.D. Pasatoiu, M. Etienne, A.M. Madalan, M. Andruh, and R. Sessoli Dimers and chains of {3d-4f} single molecule magnets constructed from heterobimetallic tectons Dalton Trans. 39 2010 4802 4808
42. R. Sessoli, and A.K. Powell Strategies towards single molecule magnets based on lanthanide ions Coord. Chem. Rev. 253 2009 2328 2341
43. Z. He, C. He, and E.Q. Gao et al. Lanthanide-transition heterometallic extended structures with novel orthogonal metalloligand as building block Inorg. Chem. 42 2003 2206 2208
44. Q. Yue, J. Yang, and G.H. Li et al. Three-dimensional 3d-4f heterometallic coordination polymers: synthesis, structures, and magnetic properties Inorg. Chem. 44 2005 5241 5246 (Pubitemid 41096399)
45. S.J. Liu, W.C. Song, and L. Xue et al. Three new Cu(II)-Ln(III) heterometallic coordination polymers constructed from quinolinic acid and nicotinic acid: synthesis, structures, and magnetic properties Sci. China Chem. 55 2012 1064 1072
46. 36} wheels Angew. Chem. Int. Ed. 45 2006 73 77 (Pubitemid 43003990)
47. H.Y. Xu, F.H. Zhao, Y.X. Che, and J.M. Zheng Three 3d-4f heterometallic complexes constructed from oxalic acid and benzimidazole-5, 6-dicarboxylic acid CrystEngComm 14 2012 6869 6874
48. Rigaku Process-Auto 1998 Rigaku Americas Corporation The Woodlands, Texas
49. G.M. Sheldrick SHELXL-97, Program for Refinement of Crystal Structures 1997 University of Göttingen Germany
50. A.K. Chaudhari, B. Joarder, E. Rivière, G. Rogez, and S.K. Ghosh Nitrate-bridged "pseudo-double-propeller"-type lanthanide(III)- copper(II) heterometallic clusters: syntheses, structures, and magnetic properties Inorg. Chem. 51 2012 9159 9161
51. G. Karotsis, M. Evangelisti, S.J. Dalgarno, and E. Brechin A calix[4]arene 3d/4f magnetic cooler Angew. Chem. Int. Ed. 48 2009 9928 9931
52. E. Cremades, S. GoÍmez-Coca, D. Aravena, S. Alvarez, and E. Ruiz Theoretical study of exchange coupling in 3d-Gd complexes: large magnetocaloric effect systems J. Am. Chem. Soc. 134 2012 10532 10542
53. 12] clusters toward single-molecule magnets and cryogenic magnetic refrigerants Inorg. Chem. 52 2013 457 463
54. 4 complexes Dalton Trans. 41 2012 8333 8339
55. 6Ln] clusters: trapping lanthanides into copper cages with artificial amino acids Inorg. Chem. 51 2012 5911 5918