Direct determination of the simplest Criegee intermediate (CH 2OO) self reaction rate

Journal of Physical Chemistry Letters

Volumn 5, Issue 13, 2014, Pages 2224-2228

  Buras, Zachary J ^a   Elsamra, Rehab M I ^b   Green, William H ^a  

^a Massachusetts Institute of Technology   (United States)

^b Alexandria University Faculty Of Science   (Egypt)

Author keywords

absolute rate coefficients; atmospheric chemistry; Criegee intermediate; infrared absorption; multiple pass absorption measurements; ozonolysis; radical self reaction

Indexed keywords

ATMOSPHERIC CHEMISTRY; ATOM LASERS; INFRARED ABSORPTION; LIGHT ABSORPTION; MOLECULES; OZONE;

ABSORPTION MEASUREMENTS; CRIEGEE INTERMEDIATES; OZONOLYSIS; RADICAL SELF-REACTION; RATE COEFFICIENTS;

REACTION INTERMEDIATES;

EID: 84903822815     PISSN: None     EISSN: 19487185     Source Type: Journal    
DOI: 10.1021/jz5008406     Document Type: Article

References (16)

1. 2 Science 2012, 335, 204-207
2. Taatjes, C. A.; Shallcross, D. E.; Percival, C. J. Research Frontiers in the Chemistry of Criegee Intermediates and Tropospheric Ozonolysis Phys. Chem. Chem. Phys. 2014, 16, 1704-1718
3. Vereecken, L.; Harder, H.; Novelli, A. The Reactions of Criegee Intermediates with Alkenes, Ozone, and Carbonyl Oxides Phys. Chem. Chem. Phys. 2014, 16, 4039-4049
4. 2OO and its Implications in Atmospheric Chemistry Nat. Chem. 2014, 6, 477-483
5. 2OO and Alkenes J. Phys. Chem. A 2014, 118, 1997-2006
6. 2OO Phys. Chem. Chem. Phys. 2014, 16, 10438-10443
7. 2OO J. Phys. Chem. Lett. 2013, 4, 4201-4205
8. 2I Radicals with Molecular Oxygen at Atmospheric Temperatures Phys. Chem. Chem. Phys. 2006, 8, 1416-1424
9. 2 J. Phys. Chem. Lett. 2013, 4, 3824-3824
10. 2 Phys. Chem. Chem. Phys. 2013, 15, 19119-19124
11. Physical Constants of Organic Compounds. In CRC Handbook of Chemistry and Physics [Online], 89th ed.; Lide, D. R., Ed.; CRC Press/Taylor and Francis: Boca Raton, FL, 2009.
12. Baulch, D. L.; Duxbury, J.; Grant, S. J.; Montague, D. C. Evaluated Kinetic Data for High Temperature Reactions. Volume 4 Homogeneous Gas Phase Reactions of Halogen- and Cyanide- Containing Species J. Phys. Chem. Ref. Data 1981, 10, 1-721
13. Fuller, E. N.; Schettler, P. D.; Giddings, J. C. New Method for Prediction of Binary Gas-Phase Diffusion Coefficients Ind. Eng. Chem. 1966, 58, 18-27
14. Percival, C. J.; Welz, O.; Eskola, A. J.; Savee, J. D.; Osborn, D. L.; Topping, D. O.; Lowe, D.; Utembe, S. R.; Bacak, A.; M c Figgans, G. Regional and Global Impacts of Criegee Intermediates on Atmospheric Sulphuric Acid Concentrations and First Steps of Aerosol Formation Faraday Discuss. 2013, 165, 45-73
15. Saiz-Lopez, A.; Plane, J. M. C.; Baker, A. R.; Carpenter, L. J.; von Glasow, R.; Gómez Martín, J. C.; McFiggans, G.; Saunders, R. W. Atmospheric Chemistry of Iodine Chem. Rev. 2011, 112, 1773-1804
16. Neeb, P.; Horie, O.; Moortgat, G. K. The Ethene-Ozone Reaction in the Gas Phase J. Phys. Chem. A 1998, 102, 6778-6785 (Pubitemid 128604937)