Liquid-liquid extraction of Cd(II) from pure and Ni/Cd acidic chloride media using Cyanex 921: A selective treatment of hazardous leachate of spent Ni-Cd batteries

Journal of Hazardous Materials

Volumn 278, Issue , 2014, Pages 258-266

  Choi, Seon Young ^a,b   Nguyen, Viet Tu ^b,c   Lee, Jae chun ^b,c   Kang, Ho ^a   Pandey, B D ^d  

^a Chungnam National University   (South Korea)

^b Korea Institute of Geosceince and Mineral Resources   (South Korea)

^c University of Science and Technology (UST)   (South Korea)

^d NATIONAL METALLURGICAL LABORATORY   (India)

Author keywords

Cyanex 921; Divalent cadmium; Ni Cd batteries; Recycling; Solvent extraction

Indexed keywords

CADMIUM; CHLORINE COMPOUNDS; HAZARDS; LEACHATE TREATMENT; NICKEL CADMIUM BATTERIES; RECYCLING; SOLVENT EXTRACTION;

CYANEX 921; LIQUID-LIQUID EXTRACTION; NI-CD BATTERIES; NUMERICAL TREATMENTS; QUANTITATIVE EXTRACTION; SELECTIVE TREATMENT; STRIPPING EFFICIENCY; THERMODYNAMIC PARAMETER;

NICKEL;

CADMIUM; CHLORIDE; CYANEX 921; NICKEL; REAGENT; UNCLASSIFIED DRUG; ORGANOPHOSPHORUS COMPOUND; TRIOCTYL PHOSPHINE OXIDE; WASTE;

ACIDITY; CADMIUM; LEACHATE; METALLURGY; SEPARATION; SIMULATION; SOLVENT; THERMODYNAMICS;

AQUEOUS SOLUTION; ARTICLE; ELECTRICAL EQUIPMENT; EQUILIBRIUM CONSTANT; HAZARDOUS WASTE; IONIC STRENGTH; LEACHING; LIQUID LIQUID EXTRACTION; NICKEL CADMIUM BATTERY; SOLVENT EXTRACTION; STOICHIOMETRY; CHEMISTRY; PH; POWER SUPPLY; PROCEDURES; SEWAGE; WASTE;

CADMIUM; CHLORIDES; ELECTRIC POWER SUPPLIES; HYDROGEN-ION CONCENTRATION; LIQUID-LIQUID EXTRACTION; NICKEL; ORGANOPHOSPHORUS COMPOUNDS; WASTE DISPOSAL, FLUID; WASTE PRODUCTS;

EID: 84903381630     PISSN: 03043894     EISSN: 18733336     Source Type: Journal    
DOI: 10.1016/j.jhazmat.2014.06.013     Document Type: Article

References (35)

1. Pérez-Marín A.B., Meseguer Zapata V., Ortuño J.F., Aguilar M., Sáez J., Lloréns M. Removal of cadmium from aqueous solutions by adsorption onto orange waste. J. Hazard. Mater. 2007, 139(1):122-131.
2. Salim R., Al-Subu M.M., Sahrhage E. Uptake of cadmium from water by beech leaves. J. Environ. Sci. Health 1992, A27(3):603-627.
3. Sadegh Safarzadeh M., Bafghi M.S., Moradkhani D., Ojaghi Ilkhchi M. A review on hydrometallurgical extraction and recovery of cadmium from various resources. Miner. Eng. 2007, 20(3):211-220.
4. Jha M.K., Kumar V., Jeong J., Lee J.-C. Review on solvent extraction of cadmium from various solutions. Hydrometallurgy 2012, 111-112:1-9.
5. Islamoglu S., Yilmaz L., Ozbelge H.O. Development of a precipitation based separation scheme for selective removal and recovery of heavy metals from cadmium rich electroplating industry effluents. Sep. Sci. Technol. 2006, 41:3367-3385.
6. Alguacil F.J. A kinetic study of cadmium(II) adsorption on Lewatit TP260 resin. J. Chem. Res. 2003, 3:144-146.
7. Dabrowski A., Hubicki Z., Podkoscielny P., Robens E. Selective removal of the heavy metal ions from waters and industrial wastewaters by ion exchange methods. Chemosphere 2004, 56:91-106.
8. Kocaoba S. Comparison of Amberlite IR 120 and dolamite's performance for the removal of heavy metals. J. Hazard. Mater. 2007, 147(1-2):488-496.
9. Lackovic K., Angove M.J., Wells J.D., Johnson B.B. Modeling the adsorption of Cd(II) onto Muloorina illite and related clay minerals. J. Colloid Interface Sci. 2003, 257:31-40.
10. Oshima S., Perera J.M., Northcott K.A., Kokusen H., Stevens G.W., Komatsu Y. Adsorption behavior of cadmium(II) and lead(II) on mesoporous silicate MCM-41. Sep. Sci. Technol. 2006, 41(8):1635-1643.
11. Leyva-Ramos R., Rangel-Mendez J.R., Mendoza-Barron J., Fuentes-Rubio L., Guerrero-Coronado R.M. Adsorption of cadmium(II) from aqueous solution onto activated carbon. Water Sci. Technol. 1997, 35(7):205-211.
12. Alguacil F.J., Tayibi H. Carrier-facilitated transport of Cd(II) from a high-salinity chloride medium across a supported liquid membrane containing Cyanex 923 in Solvesso 100. Desalination 2005, 180:181-187.
13. Rathore N.S., Leopold A., Pabby A.K., Fortuny A., Coll M.T., Sastre A.M. Extraction and permeation studies of Cd(II) in acidic and neutral chloride media using Cyanex 923 on supported liquid membrane. Hydrometallurgy 2009, 96:81-87.
14. Alguacil F.J., Navarro P. Permeation of cadmium through a supported liquid membrane impregnated with Cyanex 923. Hydrometallurgy 2001, 61:137-142.
15. 4 using phosphine oxides (Cyanex 921 and Cyanex 923) as carriers: the influence of the membrane diluent (Exxsol D100 and Solvesso 100). Hydrometallurgy 2004, 74(3-4):195-202.
16. Kumar V., Kumar M., Jha M.K., Jeong J., Lee J.-C. Solvent extraction of cadmium from sulfate solution with di-(2-ethylhexyl) phosphoric acid diluted in kerosene. Hydrometallurgy 2009, 96(3):230-234.
17. Reddy B.R., Priya D.N., Kumar J.R. Solvent extraction of cadmium from sulphate solutions using TOPS99, PC88A, Cyanex 272 and their mixtures. Hydrometallurgy 2004, 74:277-283.
18. Owusu G. Selective extractions of Zn and Cd from Zn-Cd-Co-Ni sulfate solution using D2EHPA extractant. Hydrometallurgy 1998, 47:205-215.
19. Nogueira C.A., Delmas F. New flowsheet for the recovery of cadmium, cobalt and nickel from spent Ni-Cd batteries by solvent extraction. Hydrometallurgy 1999, 52:267-287.
20. Tait B.K. Two-phase potentiometric metal extraction titrations of silver(I), copper(II) and cadmium(II) using some cation-exchangers as extractants. Talanta 1995, 42(1):137-142.
21. Katsuta S., Tsuchiya F., Takeda Y. Equilibrium studies on complexation in water and solvent extraction of zinc(II) and cadmium(II) with benzo-18-crown-6. Talanta 2000, 51:631-644.
22. Preston J.S. The selective solvent extraction of cadmium by mixtures of carboxylic acids and trialkylphosphine sulphides, Part 1. The origin and scope of the synergistic effect. Hydrometallurgy 1994, 36:61-78.
23. Casas I., Miralles N., Sastre A.M., Aguilar M. Extraction of cadmium(II) by organophosphorus compounds. Polyhedron 1986, 5:2039-2045.
24. Almela A., Elizalde M.P. Solvent extraction of cadmium (II) from acidic media by Cyanex 302. Hydrometallurgy 1995, 37:47-57.
25. Sato T., Adachi K., Kato T., Nakamura T. The extraction of divalent manganese, cobalt, copper, zinc and cadmium from hydrochloric acid solutions by tri-n-octylamine. Sep. Sci. Technol. 1982, 17(13-14):1565-1576.
26. Sato T., Shimomura T., Murakami S., Maeda T., Nakamura T. Liquid-liquid extraction of divalent manganese, cobalt, copper, zinc and cadmium from aqueous chloride solutions by tricaprylmethylammonium chloride. Hydrometallurgy 1984, 12:245-254.
27. Sato T., Nakamura T. The stability constants of the aqueous chloro complexes of divalent zinc, cadmium and mercury determined by solvent extraction with tri-n-octylphosphine oxide. Hydrometallurgy 1980, 6:3-12.
28. Reddy B.R., Neela Priya D. Chloride leaching and solvent extraction of cadmium, cobalt and nickel from spent nickel-cadmium batteries using Cyanex 923 and 272. J. Power Sources 2006, 161(2):1428-1434.
29. Leopold A.A., Coll M.T., Fortuny A., Rathore N.S., Sastre A.M. Mathematical modeling of cadmium(II) solvent extraction from neutral and acidic chloride media using Cyanex 923 extractant as a metal carrier. J. Hazard. Mater. 2010, 182(1-3):903-911.
30. Dziwinski E., Szymanowski J. Composition of Cyanex 923, Cyanex 925, Cyanex 921 and TOPO. Solv. Extr. Ion Exch. 1998, 16(6):1515-1525.
31. Kolthoff I.M., Sandell E.B., Meehan E.J., Bruckenstein S. Quantitative Chemical Analysis 1971, 722-723. McMillan, London. 4th ed.
32. Pourbaix M. Atlas of Electrochemical Equilibria in Aqueous Solutions 1974, 414-420. National Association of Corrosion Engineers, Houston, TX, USA. 2nd English ed.
33. Smith R.M., Martell A.E. Critical Stability Constant, vol. 4: Inorganic Complexes 1976, 108-109. Plenum Press, New York.
34. Alguacil F.J., Lopez F.A. The extraction of mineral acids by the phosphine oxide Cyanex 923. Hydrometallurgy 1996, 42:245-255.
35. Navarro R., Saucedo I., Núňez A., Ávila M., Guibal E. Cadmium extraction from hydrochloric acid solutions using Amberlite XAD-7 impregnated with Cyanex 921 (tri-octyl phosphine oxide). React. Funct. Polym. 2008, 68:557-571.