In situ synthesized nano-copper over ZSM-5 for the catalytic dehydration of glycerol under mild conditions

Journal of the Taiwan Institute of Chemical Engineers

Volumn 45, Issue 4, 2014, Pages 1443-1448

  Yue, Chuan Jun ^a   Gan, Miao Miao ^a   Gu, Li Ping ^a   Zhuang, Ya Feng ^a  

^a CHANGZHOU INSTITUTE OF TECHNOLOGY   (China)

Author keywords

Cu ZSM 5; Glycerol; In situ impregnated reduction; Solvent free catalytic dehydration

Indexed keywords

COPPER; DEHYDRATION; DIFFERENTIAL SCANNING CALORIMETRY; TEMPERATURE PROGRAMMED DESORPTION; THERMOGRAVIMETRIC ANALYSIS; TRANSMISSION ELECTRON MICROSCOPY; X RAY DIFFRACTION;

BRUNAUER EMMETT TELLERS; CATALYTIC DEHYDRATION; IN-SITU SYNTHESIZED; LOW TEMPERATURES; OPTIMUM CONDITIONS; SCANNING CALORIMETRY; SITU IMPREGNATED REDUCTION; SOLVENT FREE CONDITIONS;

GLYCEROL;

EID: 84903380776     PISSN: 18761070     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jtice.2014.01.005     Document Type: Article

References (33)

1. Katryniok B., Paul S., Dumeignil F. Recent developments in the field of catalytic dehydration of glycerol to acrolein. ACS Catal 2013, 3:1819-1834.
2. Pagliaro M., Ciriminna R., Kimura H., Rossi M., Della-Pina C. From glycerol to value-added products. Angew Chem Int Ed 2007, 46:4434-4440.
3. Jia C.J., Liu Y., Schmidt W., Lu A.H., Schüth F. Small-sized HZSM-5 zeolite as highly active catalyst for gas phase dehydration of glycerol to acrolein. J Catal 2010, 269:71-79.
4. Atia H., Armbruster U., Martin A. Dehydration of glycerol in gas phase using heteropolyacid catalysts as active compounds. J Catal 2008, 258:71-82.
5. Chai S., Wang H., Liang Y., Xu B. Sustainable production of acrolein: preparation and characterization of zirconia-supported 12-tungstophosphoric acid catalyst for gas-phase dehydration of glycerol. Appl Catal A: Gen 2009, 353:213-222.
6. Lauriol-Garbey P., Postole G., Loridant S., Auroux A., Belliere-Baca V., Rey P., et al. Acid-base properties of niobium-zirconium mixed oxide catalysts for glycerol dehydration by calorimetric and catalytic investigation. Appl Catal B: Environ 2011, 106:94-102.
7. Suprun W., Lutecki M., Haber T., Papp H. Acidic catalysts for the dehydration of glycerol: activity and deactivation. J Mol Catal A 2009, 309:71-78.
8. Wang F., Dubois J-L., Ueda W. Catalytic dehydration of glycerol over vanadium phosphate oxides in the presence of molecular oxygen. J Catal 2009, 268:260-267.
9. Tsukuda E., Sato S., Takahashi R., Sodesawa T. Production of acrolein from glycerol over silica-supported heteropoly acids. Catal Commun 2007, 8:1349-1353.
10. Chieregato A., Basile F., Concepción P., Guidetti S., Liosi G., Soriano M.D., et al. Glycerol oxidehydration into acrolein and acrylic acid over W-V-Nb-O bronzes with hexagonal structure. Catal Today 2012, 197:58-65.
11. García-Sancho C., Moreno-Tost R., Mérida-Robles J., Santamaría-González J., Jiménez-López A., Maireles-Torres P. Zirconium doped mesoporous silica catalysts for dehydration of glycerol to high added-value products. Appl Catal A: Gen 2012, 433-434:179-187.
12. 2-supported Nb- and W-oxide in the gas-phase dehydration of glycerol to acrolein. J Catal 2013, 297:93-109.
13. Omata K., Izumi S., Murayama T., Ueda W. Hydrothermal synthesis of W-Nb complex metal oxides and their application to catalytic dehydration of glycerol to acrolein. Catal Today 2013, 201:7-11.
14. 2 and ammoxidation over Sb-(Fe, V)-O. Appl Catal B: Environ 2013, 132-133:170-182.
15. 2 catalysts for the hydrogenolysis of glycerol. Appl Catal B: Environ 2014, 145:108-119.
16. Gu Y.L., Cui N.Y., Yu Q.J., Li C.Y., Cui Q.K. Study on the influence of channel structure properties in the dehydration of glycerol to acrolein over H-zeolite catalysts. Appl Catal A: Gen 2012, 429:9-16.
17. Akiyama M., Sato S., Takahashi R., Inui K., Yokota M. Dehydration-hydrogenation of glycerol into 1,2-propanediol at ambient hydrogen pressure. Appl Catal A: Gen 2009, 371:60-66.
18. Haider M.H., Dummer N.F., Zhang D.H., Miedziak P., Davies T.E., Taylor S.H., et al. Rubidium- and caesium-doped silicotungstic acid catalysts supported on alumina for the catalytic dehydration of glycerol to acrolein. J Catal 2012, 286:206-213.
19. Shen L.Q., Yin H.B., Wang A.L., Feng Y.H., Shen Y.T., Wu Z.N., et al. Liquid phase dehydration of glycerol to acrolein catalyzed by silicotungstic, phosphotungstic, and phosphomolybdic acids. Chem Eng J 2012, 180:277-283.
20. Shen L.Q., Yin H.B., Wang A.L., Lu X.F., Zhang C.H., Chen F., et al. Liquid phase catalytic dehydration of glycerol to acrolein over Brønsted acidic ionic liquid catalysts. J Ind Eng Chem 2013, 10.1016/j.jiec.2013.06.004.
21. 5 catalyst on the dehydration of glycerol. Catal Today 2013, 10.1016/j.cattod.2013.11.051.
22. Huang J.B., Liu C., Wei S.A., Huang X.L. Density functional theory study on the dehydration mechanism of glycerine. Acta Chim Sin 2010, 68:1043-1049.
23. Sato S., Akiyama M., Takahashi R., Hara T., Inui K., Yokota M. Vapor-phase reaction of polyols over copper catalysts. Appl Catal A: Gen 2008, 347:186-191.
24. Mane R.B., Kondawar S.E., Niphadkar P.S., Joshi P.N., Patil K.R., Rode C.V. Effect of preparation parameters of Cu catalysts on their physico-chemical properties and activities for glycerol hydrogenolysis. Catal Today 2012, 198:321-329.
25. Zakaria Z.Y., Linnekoski J., Amin N.A.S. Catalyst screening for conversion of glycerol to light olefins. Chem Eng J 2012, 207-208:803-813.
26. Du H.B., Zhou Q., Zhou F.Q., Pang W.Q. Study on the synthesis and structure of Cu-ZSM-5 type molecular sieve. Acta Physico-chim Sin 1994, 10:635-638.
27. Zhu H-T., Zhang C-Y., Yin Y-S. Rapid synthesis of copper nanoparticles by sodium hypophosphite reduction in ethylene glycol under microwave irradiation. J Cryst Growth 2004, 270:722-728.
28. Dam J., Hanefeld U. Renewable chemicals: dehydroxylation of glycerol and polyols. ChemSusChem 2011, 4:1017-1034.
29. Kim Y.T., Jung K-D., Park E.D. A comparative study for gas-phase dehydration of glycerol over H-zeolites. Appl Catal A: Gen 2011, 393:275-287.
30. Miyazawa T., Kusunoki Y., Kunimori K., Tomishige K. Glycerol conversion in the aqueous solution under hydrogen over Ru/C+an ion-exchange resin and its reaction mechanism. J Catal 2006, 240:213-221.
31. Alhanash A., Kozhevnikova E.F., Kozhevnikov I.V. Hydrogenolysis of glycerol to propanediol over Ru: polyoxometalate bifunctional catalyst. Catal Lett 2008, 120:307-311.
32. 2 catalysts prepared by precipitation-gel method in the hydrogenolysis of glycerol to 1,2-propanediol: effect of residual sodium. Appl Catal A: Gen 2009, 366:288-298.
33. Mane R.B., Rode C.V. Continuous dehydration and hydrogenolysis of glycerol over non-chromium copper catalyst: laboratory-scale process studies. Org Process Res Dev 2012, 16:1043-1052.