A novel and precise measuring method for the entropy of lithium-ion cells: Δs via electrothermal impedance spectroscopy

Electrochimica Acta

Volumn 137, Issue , 2014, Pages 311-319

  Schmidt, Jan Philipp ^a   Weber, André ^a   Ivers Tiffée, Ellen ^a  

^a KARLSRUHE INSTITUTE OF TECHNOLOGY   (Germany)

Author keywords

electrothermal impedance spectroscopy; entropy; Lithium ion; measurement; thermal behavior

Indexed keywords

ELECTRIC HEATING; LITHIUM BATTERIES; MEASUREMENTS; OPEN CIRCUIT VOLTAGE; SPECTROSCOPY;

ELECTRODE MATERIAL; HYSTERESIS BEHAVIOR; IMPEDANCE SPECTROSCOPY; LITHIUM IONS; LITHIUM-ION CELLS; POTENTIOMETRIC MEASUREMENTS; PRECISE MEASURING; THERMAL BEHAVIORS;

ENTROPY;

EID: 84903132725     PISSN: 00134686     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.electacta.2014.05.153     Document Type: Article

References (26)

1. K. Onda, T. Ohshima, M. Nakayama, K. Fukuda, and T. Araki Thermal behavior of small lithium-ion battery during rapid charge and discharge cycles J. Power Sources 158 2006 535 542 (Pubitemid 43867974)
2. K.E. Thomas, and J. Newman Thermal Modeling of Porous Insertion Electrodes J. Electrochem. Soc. 150 2003 A176 A192
3. L.J. Krause, L.D. Jensen, and J.R. Dahn Measurement of Parasitic Reactions in Li Ion Cells by Electrochemical Calorimetry J. Electrochem. Soc. 159 2012 A937 A943
4. L.E. Downie, K.J. Nelson, R. Petibon, V.L. Chevrier, and J.R. Dahn The Impact of Electrolyte Additives Determined Using Isothermal Microcalorimetry ECS Electrochem. Lett. 2 2013 A106 A109
5. J.-S. Hong, H. Maleki, S. Al Hallaj, L. Redey, and J.R. Selman Electrochemical-Calorimetric Studies of Lithium-Ion Cells J. Electrochem. Soc. 145 1998 1489 1501 (Pubitemid 128612683)
6. V.V. Viswanathan, D. Choi, D. Wang, W. Xu, S. Towne, R.E. Williford, J.G. Zhang, J. Liu, and Z. Yang Effect of entropy change of lithium intercalation in cathodes and anodes on Li-ion battery thermal management J. Power Sources 195 2010 3720 3729
7. K. Jalkanen, T. Aho, and K. Vuorilehto Entropy change effects on the thermal behavior of a LiFePO4/graphite lithium-ion cell at different states of charge J. Power Sources 243 2013 354 360
8. W. Lu, and J. Prakash In Situ Measurements of Heat Generation in a Li/Mesocarbon Microbead Half-Cell J. Electrochem. Soc. 150 2003 A262 A266
9. T.H. Tran, S. Harmand, B. Desmet, and F. Pailhoux Thermal Characterization of LiNi0.8Co0.15Al0.05O2/Graphite Battery J. Electrochem. Soc. 160 2013 A775 A780
10. K. Onda, H. Kameyama, T. Hanamoto, and K. Ito Experimental Study on Heat Generation Behavior of Small Lithium-Ion Secondary Batteries J. Electrochem. Soc. 150 2003 A285 A291
11. S. Al Hallaj, R. Venkatachalapathy, J. Prakash, and J.R. Selman Entropy Changes Due to Structural Transformation in the Graphite Anode and Phase Change of the LiCoO2 Cathode J. Electrochem. Soc. 147 2000 2432 2436
12. S. Al Hallaj, J. Prakash, and J.R. Selman Characterization of commercial Li-ion batteries using electrochemical calorimetric measurements J. Power Sources 87 2000 186 194 (Pubitemid 30585586)
13. H. Yang, and J. Prakash Determination of the Reversible and Irreversible Heats of a LiNi0.8Co0.15Al0.05O2/Natural Graphite Cell Using Electrochemical-Calorimetric Technique J. Electrochem. Soc. 151 2004 A1222 A1229
14. Y. Reynier, R. Yazami, and B. Fultz The entropy and enthalpy of lithium intercalation into graphite J. Power Sources 119 2003 850 855
15. K. Ozawa, Lithium Ion Rechargeable Batteries: Materials, Technology, and New Applications, Wiley, Weinheim, 2012.
16. 4/graphite lithium-ion battery J. Power Sources 195 2010 2961 2968
17. Y. Kobayashi, H. Miyashiro, K. Kumai, K. Takei, T. Iwahori, and I. Uchida Precise Electrochemical Calorimetry of LiCoO2/Graphite Lithium-Ion Cell: Understanding Thermal Behavior and Estimation of Degradation Mechanism J. Electrochem. Soc. 149 2002 A978 A982
18. J.P. Schmidt, D. Manka, D. Klotz, and E. Ivers-Tiffée Investigation of the Thermal Properties of a Li-Ion Pouch-Cell by Electrothermal Impedance Spectroscopy J. Power Sources 196 2011 8140 8146
19. K.E. Thomas, and J. Newman Heats of mixing and of entropy in porous insertion electrodes J. Power Sources 119-121 2003 844 849
20. Boashash, B., ed. (2003), Time-Frequency Signal Analysis and Processing: A Comprehensive Reference.
21. M. Fleckenstein, S. Fischer, O. Bohlen, and B. Bäker Thermal Impedance Spectroscopy - A method for the thermal characterization of high power battery cells J. Power Sources 223 2013 259 267
22. D. Linzen Impedance-Based Loss Calculation and Thermal Modeling of Electrochemical Energy Storage Devices for Design Considerations of Automotive Power Systems 2006 Shaker Verlag GmbH Germany
23. J.P. Schmidt, H.Y. Tran, J. Richter, E. Ivers-Tiffée, and M. Wohlfahrt-Mehrens Analysis and Prediction of the Open Circuit Potential of Lithium-Ion Cells J. Power Sources 239 2013 696 704
24. T. Ohzuku, Y. Iwakoshi, and K. Sawai Formation of Lithium-Graphite Intercalation Compounds in Nonaqueous Electrolytes and Their Application as a Negative Electrode for a Lithium Ion (Shuttlecock) Cell J. Electrochem. Soc. 140 1993 2490 2498
25. M. Winter, J.O. Besenhard, M.E. Spahr, and P. Novak Insertion electrode materials for rechargeable lithium batteries Advanced Materials 10 1998 725 763 (Pubitemid 128577688)
26. M.A. Roscher, D.U. Sauer, Dynamic electric behavior and open-circuit-voltagemodeling of LiFePO4-based lithium ion secondary batteries, J. Power Sources196 (2011) 331336.