Transition-metal-free synthesis of ynol ethers and thioynol ethers via displacement at sp Centers: A revised mechanistic pathway

Journal of Organic Chemistry

Volumn 79, Issue 12, 2014, Pages 5869-5874

  Gray, Vincent James ^a   Cuthbertson, James ^a   Wilden, Jonathan D ^a  

^a UNIVERSITY COLLEGE LONDON   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMISTRY; ORGANIC COMPOUNDS;

FUNCTIONALIZED; MECHANISTIC PATHWAYS; PROTOCOL CANS;

ETHERS;

1 (NEOPENTYLOXY) 2 PHENYLETHYNE; 1 METHOXY 2 PHENYLETHYNE; 1 PROPOXY 2 PHENYLETHYNE; ALKYNE; BENZYL(PHENYLETHYNYL)SULFANE; ETHER DERIVATIVE; ETHYL(PHENYLETHYNYL)SULFANE; HEXYL(PHENYLETHYNYL)SULFANE; METHOXY 2 PHENYLETHYNE; OXYGEN; TERT BUTYL(PHENYLETHYNYL)SULFATE; TERT BUTYL[[4 (TRIFLUOROMETHYL)PHENYL]ETHYNYL]SULFANE; TETR BUTYL[(4 METHOXYPHENYL)ETHYNYL]SULFANE; THIOYNOL ETHER DERIVATIVE; TRANSITION ELEMENT; TRIMETHYL(2 [(PHENYLETHYNYL)OXY]ETHYL]SILANE; UNCLASSIFIED DRUG; YNOL ETHER DERIVATIVE; [(4 BROMOPHENYL)ETHYNYL](TERT BUTYL) SULFANE; [2,2 BIS (2,2,2 TRIFLUOROETHOXY)VINYL]BENZENE;

ARTICLE; ATOM; CARBON NUCLEAR MAGNETIC RESONANCE; ELECTRON; PROTON NUCLEAR MAGNETIC RESONANCE; SUBSTITUTION REACTION; SYNTHESIS;

EID: 84903119209     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo500814y     Document Type: Article

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