Kinetics of wet peroxide oxidation of phenol with a gold/activated carbon catalyst

Chemical Engineering Journal

Volumn 253, Issue , 2014, Pages 486-492

  Dominguez C M ^a   Quintanilla, A ^a   Casas, J A ^a   Rodriguez, J J ^a  

^a UNIVERSIDAD AUTÓNOMA DE MADRID   (Spain)

Author keywords

Catalytic wet peroxide oxidation; Deactivation; Gold nanoparticles; Kinetic model; Phenol

Indexed keywords

ACTIVATED CARBON; GOLD; HYDROGEN PEROXIDE; KINETIC PARAMETERS; KINETIC THEORY; METAL NANOPARTICLES; OIL SHALE; PEROXIDES; PHENOLS; POLLUTION;

CATALYTIC WET PEROXIDE OXIDATION; DEACTIVATION; GOLD NANOPARTICLES; KINETIC MODELING; OXIDATIVE THERMAL TREATMENT; PHENOL CONCENTRATION; TEMPERATURE DEPENDENCE; WET PEROXIDE OXIDATION;

CATALYST DEACTIVATION;

EID: 84902530883     PISSN: 13858947     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.cej.2014.05.063     Document Type: Article

References (21)

1. Rokhina E.V., Virkutyte J. Environmental application of catalytic processes: heterogeneous liquid phase oxidation of phenol with hydrogen peroxide. Crit. Rev. Environ. Sci. Technol. 2010, 41:125-167.
2. Perathoner S., Centi G. Wet hydrogen peroxide catalytic oxidation (WHPCO) of organic waste in agro-food and industrial streams. Top. Catal. 2005, 33:207-224.
3. Navalon S., Alvaro M., Garcia H. Heterogeneous Fenton catalysts based on clays, silicas and zeolites. Appl. Catal. B 2010, 99:1-26.
4. Navalon S., Dhakshinamoorthy A., Alvaro M., Garcia H. Heterogeneous Fenton catalysts based on activated carbon and related materials. ChemSusChem 2011, 16(12):1712-1730.
5. Dhakshinamoorthy A., Navalon S., Alvaro M., Garcia H. Metal nanoparticles as heterogeneous Fenton catalysts. ChemSusChem 2012, 5:46-64.
6. Han Y., Phonthammachai N., Ramesh K., Zhong Z., White T. Removing organic compounds from aqueous medium via wet peroxidation by gold catalysts. Environ. Sci. Technol. 2008, 42(3):908-912.
7. Navalon S., Martin R., Alvaro M., Garcia H. Gold on diamond nanoparticles as a highly efficient Fenton catalyst. Angew. Chem. 2010, 122(45):8581-8585.
8. Martin R., Navalon S., Alvaro M., Garcia H. Optimized water treatment by combining catalytic Fenton reaction using diamond supported gold and biological degradation. Appl. Catal. B Environ. 2011, 103(1-2):246-252.
9. Quintanilla A., Garcia-Rodriguez S., Dominguez C.M., Blasco S., Casas J.A., Rodriguez J.J. Supported gold nanoparticle catalysts for wet peroxide oxidation. Appl. Catal. B Environ. 2012, 111:81-89.
10. A. Quintanilla, C.M. Dominguez, S. Blasco, J.A. Casas, J.J. Rodriguez, Catalytic Wet Peroxide Oxidation of Organic Pollutants by Gold, in: 2nd European Conference on Environmental Applications of Advanced Oxidation Processes, 2009, Nicosia (Cyprus).
11. Eisenberg G.M. Industrial and engineering chemistry. Anal. Ed. 1943, 15:327-328.
12. Bhatia S., Kalam A., Joglekar H., Joshi J. Effective diffusivity of phenol in activated carbon. Chem. Eng. Commun. 1990, 98(1):139-154.
13. 2 catalyst for the continuous treatment of phenol aqueous solutions in a fixed bed reactor. Catal. Today 2010, 149:334-340.
14. Zazo J.A., Pliego G., Blasco S., Casas J.A., Rodriguez J.J. Intensification of the Fenton process by increasing the temperature. Ind. Eng. Chem. Res. 2011, 50(2):866-870.
15. Inchaurrondo N., Cechini J., Font J., Haure P. Strategies for enhanced CWPO of phenol solutions. Appl. Catal. B Environ. 2012, 111:641-648.
16. Domínguez C.M., Ocón P., Quintanilla A., Casas J.A., Rodriguez J.J. Highly efficient application of activated carbon as catalyst for wet peroxide oxidation. Appl. Catal. B Environ. 2013, 140-141:663-670.
17. Sievers M. Advanced oxidation processes. Treatise water. Science 2011, 4:377-408.
18. Centi G., Perathoner S., Torre T., Verduna M.G. Catalytic wet oxidation of carboxylic acids on homogeneous and heterogeneous Fenton-type catalysts. Catal. Today 2000, 55(1):61-69.
19. Nijhuis T.A., Gardner T.Q., Weckhuysen B.M. Modeling of kinetics and deactivation in the direct epoxidation of propene over gold-titania catalysts. J. Catal. 2005, 236:153-163.
20. Abad A., Corma A., Garcia H. Catalyst parameters determining activity and selectivity of supported gold nanoparticles for the aerobic oxidation of alcohols: the molecular reaction mechanism. Chem. Eur. J. 2008, 14(1):212-222.
21. Martin R., Navalon S., Delgado J.J., Calvino J.J., Alvaro M., Garcia H. Influence of the preparation procedure on the catalytic activity of gold supported on diamond nanoparticles for phenol peroxidation. Chem. Eur. J. 2012, 17(34):9494-9502.