Transformation of SiO2 in Titanium Silicalite-1/SiO2 extrudates during tetrapropylammonium hydroxide treatment and improvement of catalytic properties for propylene epoxidation

Chemical Engineering Journal

Volumn 253, Issue , 2014, Pages 464-471

  Song, Wancang ^a   Zuo, Yi ^a   Xiong, Guang ^a   Zhang, Xiongfu ^a   Jin, Fengying ^a   Liu, Liping ^a   Wang, Xiangsheng ^a  

^a DALIAN UNIVERSITY OF TECHNOLOGY   (China)

Author keywords

Propylene epoxidation; TPAOH treatment; Transformation; TS 1

Indexed keywords

CATALYST ACTIVITY; MAGIC ANGLE SPINNING; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; SILICATE MINERALS; SILICON; TITANIUM; TITANIUM DIOXIDE; TRANSMISSION ELECTRON MICROSCOPY; X RAY DIFFRACTION; X RAY PHOTOELECTRON SPECTROSCOPY;

EXTRUDATES; PROPYLENE EPOXIDATION; TPAOH TREATMENT; TRANSFORMATION; TS-1;

PROPYLENE;

EID: 84902529256     PISSN: 13858947     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.cej.2014.05.075     Document Type: Article

References (49)

1. Nijhuis T.A., Makkee M., Moulijn J.A., Weckhuysen B.M. The production of propene oxide: catalytic processes and recent developments. Ind. Eng. Chem. Res. 2006, 45:3447-3459.
2. Sasidharan M., Patra A.K., Kiyozumi Y., Bhaumik A. Fabrication, characterization and catalytic oxidation of propylene over TS-1/Au membranes. Chem. Eng. Sci. 2012, 75:250-255.
3. Bassler P., Weidenbach M., Goebbel H. The new HPPO process for propylene oxide: from joint development to worldscale production. Chem. Eng. Trans. 2010, 21:571-576.
4. 2 catalyzed by supported TS-1 catalyst in a fixed-bed reactor: experiments and kinetics. Chem. Eng. J. 2013, 215-216:306-314.
5. Russo V., Tesser R., Santacesaria E., Di Serio M. Chemical and technical aspects of propene oxide production via hydrogen peroxide (HPPO process). Ind. Eng. Chem. Res. 2013, 52:1168-1178.
6. M. Taramasso, G. Pergo, B. Notari, Preparation of porous crystalline synthetic material comprised of silicon and titanium oxides, US Patent 4410501 (1983).
7. Clerici M.G., Bellussi G., Romano U. Synthesis of propylene oxide from propylene and hydrogen peroxide catalyzed by titanium silicalite. J. Catal. 1991, 129:159-167.
8. 2 solids prepared by the sol-gel method. Micropor. Mater. 1995, 4:273-282.
9. Borin M.F., da Silva T., Felisbino R.F., Cardoso D. Synthesis of TS-1 molecular sieves using a new Ti source. J. Phys. Chem. B 2006, 110:15080-15084.
10. Zuo Y., Wang X.S., Guo X.W. Synthesis of Titanium Silicalite-1 with small crystal size by using mother liquid of Titanium Silicalite-1 as seed. Ind. Eng. Chem. Res. 2011, 50:8485-8491.
11. Deng X.J., Wang Y.N., Shen L., Wu H.H., Liu Y.M., He M.Y. Low-cost synthesis of Titanium Silicalite-1 (TS-1) with highly catalytic oxidation performance through a controlled hydrolysis process. Ind. Eng. Chem. Res. 2013, 52:1190-1196.
12. Fan W.B., Duan R.G., Yokoi T., Wu P., Kubota Y., Tatsumi T. Synthesis, crystallization mechanism and catalytic properties of titanium-rich TS-1 free of extraframework titanium species. J. Am. Chem. Soc. 2008, 130:10150-10164.
13. Chandra D., Mal N.K., Mukherjee M., Bhaumik A. Titanium-rich highly ordered mesoporous silica synthesized by using a mixed surfactant system. J. Solid State Chem. 2006, 179:1802-1807.
14. Fang Y.M., Hu H.Q. Mesoporous TS-1: nanocasting synthesis with CMK-3 as template and its performance in catalytic oxidation of aromatic thiophene. Catal. Commun. 2007, 8:817-820.
15. Lakiss L., Rivallan M., Goupil J.M., Fallah J.E., Mintova S. Self-assembled titanosilicate TS-1 nanocrystals in hierarchical structures. Catal. Today 2011, 168:112-117.
16. Chen L.H., Li X.Y., Tian G., Li Y., Rooke J.C., Zhu G.S., Qiu S.L., Yang X.Y., Su B.L. Highly stable and reusable multimodal zeolite TS-1 based catalysts with hierarchically interconnected three-level micro-meso-macroporous structure. Angew. Chem. Int. Ed. 2011, 50:11156-11161.
17. Zhou J., Hua Z.L., Cui X.Z., Ye Z.Q., Cui F.M., Shi J.L. Hierarchical mesoporous TS-1 zeolite: a highly active and extraordinarily stable catalyst for the selective oxidation of 2,3,6-trimethylphenol. Chem. Commun. 2010, 46:4994-4996.
18. 2 xerogels imprinted with silanized protozeolitic units. Chem. Eng. J. 2011, 171:1428-1438.
19. 2. Chem. Catal. Chem. 2010, 2:407-412.
20. Hutchings G.J., Lee D.F. Control of product selectivity for the epoxidation of allyl alcohol by variation of the acidity of the catalyst TS-1. J. Chem. Soc., Chem. Commun. 1994, 9:1095-1096.
21. Ogura M., Shinomiya S.Y., Tateno J., Nara Y., Nomura M., Kikuchi E., Matsukata M. Alkali-treatment technique-new method for modification of structural and acid-catalytic properties of ZSM-5 zeolites. Appl. Catal. A: Gen. 2001, 219:33-43.
22. Tsai S.T., Chao P.Y., Tsai T.C., Wang I., Liu X.X., Guo X.W. Effects of pore structure of post-treated TS-1 on phenol hydroxylation. Catal. Today 2009, 148:174-178.
23. Silvestre-Albero A., Grau-Atienza A., Serrano E., García-Martínez J., Silvestre-Albero J. Desilication of TS-1 zeolite for the oxidation of bulky molecules. Catal. Commun. 2014, 44:35-39.
24. Wang Y.R., Lin M., Tuel A. Hollow TS-1 crystals formed via a dissolution-recrystallization process. Micropor. Mesopor. Mater. 2007, 102:80-85.
25. Zuo Y., Song W.C., Dai C.Y., He Y.P., Wang M.L., Wang X.S., Guo X.W. Modification of small-crystal titanium silicalite-1 with organic bases: recrystallization and catalytic properties in the hydroxylation of phenol. Appl. Catal. A: Gen. 2013, 453:272-279.
26. Serrano D.P., Sanz R., Pizarro P., Moreno I., de Frutos P., Blazquez S. Preparation of extruded catalysts based on TS-1 zeolite for their application in propylene epoxidation. Catal. Today 2009, 143:151-157.
27. Au L.T.Y., Chau J.L.H., Ariso C.T., Yeung K.L. Preparation of supported Sil-1, TS-1 and VS-1 membranes-effects of Ti and V metal ions on the membrane synthesis and permeation properties. J. Membr. Sci. 2001, 183:269-291.
28. 2 egg-shell catalysts. Chem. Eng. J. 2011, 175:408-416.
29. Li G., Wang X.S., Yan H.S., Liu Y.H., Liu X.W. Epoxidation of propylene using supported titanium silicalite catalysts. Appl. Catal. A: Gen. 2002, 236:1-7.
30. 2 in fixed-bed reactor. Chem. Eng. J. 2014, 243:192-196.
31. Wang L.Q., Wang X.S., Guo X.W. Quick synthesis of titanium silicalite-1. Chin. J. Catal. 2001, 22:513-514.
32. A.C.k. Yip, F.L.Y. Lam, X.J. Hu, L. Ping, Study on the synthesis of clay-based titanium silicalite-1 catalytic composite, Ind. Eng. Chem. Res. 48 (2009) 5226-5275.
33. Qiu F.R., Wang X.B., Zhang X.F., Liu H.O., Liu S.Q., Yeung K.L. Preparation and properties of TS-1 zeolite and film using Sil-1 nanoparticles as seeds. Chem. Eng. J. 2009, 147:316-322.
34. Balducci L., Bianchi D., Bortolo R., D'Aloisio R., Ricci M., Tassinari R., Ungarelli R. Direct oxidation of benzene to phenol with hydrogen peroxide over a modified Titanium Silicalite. Angew. Chem. Int. Ed. 2003, 42:4937-4940.
35. Wells D.H., Delgass W.N., Thomson K.T. Evidence of defect-promoted reactivity for epoxidation of propylene in titanosilicate (TS-1) catalysts: a DFT study. J. Am. Chem. Soc. 2004, 126:2956-2962.
36. Zhang F.Z., Guo X.W., Wang X.S., Li G., Zhou J.C., Yu J.Q., Li C. The active sites in different TS-1 zeolites for propylene epoxidation studied by ultraviolet resonance Raman and ultraviolet visible absorption spectroscopies. Catal. Lett. 2001, 72:3-4.
37. Wang X.B., Zhang X.F., Liu H.O., Yeung K.L., Wang J.Q. Preparation of titanium silicalite-1 catalytic films and application as catalytic membrane reactors. Chem. Eng. J. 2010, 156:562-570.
38. Vayssilov G.N. Structural and physicochemical features of titanium silicalites. Catal. Rev. 1997, 39:209-251.
39. Li C., Xiong G., Xin Q., Liu J.K., Ying P.L., Feng F.C., Li J., Yang W.B., Wang Y.Z., Wang G.R., Liu X.Y., Lin M., Wang X.Q., Min E.Z. UV resonance Raman spectroscopic identification of titanium atoms in the framework of TS-1 zeolite. Angew. Chem. Int. Ed. 1999, 38:2220-2222.
40. Su J., Xiong G., Zhou J.C., Liu W.H., Zhou D.H., Wang G.R., Wang X.S., Guo H.C. Amorphous Ti species in titanium silicalite-1: structural features, chemical properties, and inactivation with sulfosalt. J. Catal. 2012, 288:1-7.
41. Guo Q., Feng Z.D., Li G.N., Fan F.T., Li C. A thorough investigation of the active titanium species in TS-1 zeolite by in situ UV resonance Raman spectroscopy. J. Phys. Chem. C 2013, 117:2844-2848.
42. 2 pellet support. J. Chem. Technol. Biotechnol. 2007, 82:414-420.
43. 29Si MAS NMR studies of titanosilicalite (TS)-1. J. Chem. Soc., Chem. Commun. 1992, 21:1578-1580.
44. Wan J.G., Xu L., Zhang K., Peng H.G., Wu H.H., Jiang J.G., Liu Y.M., Wu P. Multilayer structured MFI-type titanosilicate: synthesis and catalytic properties in the selective epoxidation of bulky molecules. J. Catal. 2012, 288:16-23.
45. Xu C.H., Jin T.H., Jhung S.H., Chang J.S., Hwang J.S., Park S.E. Hydrophobicity and catalytic properties of Ti-MFI zeolites synthesized by microwave and conventional heating. Catal. Today 2006, 111:366-372.
46. Park S., Cho K.M., Youn M.H., Seo J.G., Jung J.C., Baeck S.H., Kim T.J., Chung Y.M., Oh S.h., Song I.K. Direct epoxidation of propylene with hydrogen peroxide over TS-1 catalysts: effect of hydrophobicity of the catalysts. Catal. Commun. 2008, 9:2485-2488.
47. van der Pol A.J.H.P., Verduyn A.J., van Hooff J.H.C. Why are some titanium silicalite-1 samples active and others not?. Appl. Catal. A: Gen. 1992, 92:113-130.
48. Ratnasamy P., Srinivas D., Knözinger H. Active sites and reactive intermediates in titanium silicate molecular sieves. Adv. Catal. 2004, 48:1-169.
49. Davies L., McMorn P., Bethell D., Page P.C.B., King F., Hancock F.E., Hutchings G.J. Effect of preparation method on leaching of Ti from the redox molecular sieve TS-1. Phys. Chem. Chem. Phys. 2001, 3:632-639.