Electrical properties of proton conducting solid biopolymer electrolytes based on starch-chitosan blend

Ionics

Volumn 20, Issue 7, 2014, Pages 977-999

  Shukur, M F ^a   Ithnin, R ^a   Kadir, M F Z ^a  

^a UNIVERSITY OF MALAYA   (Malaysia)

Author keywords

Ammonium chloride; Conductivity; Relaxation time; Rice and Roth model; Solid polymer electrolyte; Starch chitosan blend

Indexed keywords

ACTIVATION ENERGY; CHITOSAN; CHLORINE COMPOUNDS; ELECTRIC CONDUCTIVITY; ELECTRIC PROPERTIES; RELAXATION TIME; STARCH;

AMMONIUM CHLORIDE; BIOPOLYMER ELECTROLYTE; CONDUCTING ELECTROLYTE; FOURIER TRANSFORM INFRA REDS; PROTON CONDUCTING SOLIDS; ROOM-TEMPERATURE CONDUCTIVITY; SOLID POLYMER ELECTROLYTES; TEMPERATURE DEPENDENCE;

SOLID ELECTROLYTES;

EID: 84902377783     PISSN: 09477047     EISSN: 18620760     Source Type: Journal    
DOI: 10.1007/s11581-013-1033-8     Document Type: Article

References (98)

1. Sudhakar YN, Selvakumar M, Bhat DK (2013) LiClO4-doped plasticized chitosan and poly(ethylene glycol) blend as biodegradable polymer electrolyte for supercapacitors. Ionics 19: 277-285. doi: 10. 1007/s11581-012-0745-5.
2. Shuhaimi NEA, Alias NA, Kufian MZ, Majid SR, Arof AK (2010) Characteristics of methyl cellulose-NH4NO3-PEG electrolyte and application in fuel cells. J Solid State Electrochem 14: 2153-2159. doi: 10. 1007/s10008-010-1099-4.
3. Mohan KR, Achari VBS, Rao VVRN, Sharma AK (2011) Electrical and optical properties of (PEMA/PVC) polymer blend electrolyte doped with NaClO4. Polym Test 30: 881-886. doi: 10. 1016/j. polymertesting. 2011. 08. 010.
4. Agrawal RC, Hashmi SA, Pandey GP (2007) Electrochemical cell performance studies on all-solid-state battery using nano-composite polymer electrolyte membrane. Ionics 13: 295-298. doi: 10. 1007/s11581-007-0112-0.
5. Siebert E, Rosini S, Bouchet R, Vitter G (2003) Mixed potential type hydrogen sensor. Ionics 9: 168-175. doi: 10. 1007/BF02375962.
6. Singh KP, Singh RP, Gupta PN (1995) Polymer based solid state electrochromic display device using PVA complex electrolytes. Solid State Ionics 78: 223-229. doi: 10. 1016/0167-2738(95)00100-K.
7. Arico AS, Blasi AD, Brunaccini G et al (2010) High temperature operation of a solid polymer electrolyte fuel cell stack based on a new ionomer membrane. Fuel Cells 10: 1013-1023. doi: 10. 1002/fuce. 201000031.
8. Wu F, Feng T, Wu C, Bai Y, Ye L, Chen J (2010) Thermally stable hyperbranched polyether-based polymer electrolyte for lithium-ion batteries. J Phys D Apply Phys. doi: 10. 1088/0022-3727/43/3/035501.
9. Ha HJ, Kil EH, Kwon YH, Kim JY, Lee CK, Lee SY (2012) UV-curable semi-interpenetrating polymer network-integrated, highly bendable plastic crystal composite electrolytes for shape-conformable all-solid-state lithium ion batteries. Energy Environ Sci 5: 6491-6499. doi: 10. 1039/c2ee03025j.
10. Ismail L, Majid SR, Arof AK (2009) Conductivity study in PEO-LiOAc based polymer electrolyte. Mater Res Innov 13: 282-284. doi: 10. 1179/143307509X440532.
11. Noor IS, Majid SR, Arof AK (2013) Poly(vinyl alcohol)-LiBOB complexes for lithium-air cells. Electrochim Acta 102: 149-160. doi: 10. 1016/j. electacta. 2013. 04. 010.
12. Shuhaimi NEA, Majid SR, Arof AK (2009) On complexation between methyl cellulose and ammonium nitrate. Mater Res Innov 13: 239-242. doi: 10. 1179/143307509X440406.
13. Majid SR, Arof AK (2007) Electrical behavior of proton-conducting chitosan-phosphoric acid-based electrolytes. Physica B 390: 209-215. doi: 10. 1016/j. physb. 2006. 08. 038.
14. Karuppasamy K, Thanikaikarasan S, Antony R, Balakumar S, Shajan XS (2012) Effect of nanochitosan on electrochemical, interfacial and thermal properties of composite solid polymer electrolytes. Ionics 18: 737-745. doi: 10. 1007/s11581-012-0678-z.
15. Kadir MFZ, Majid SR, Arof AK (2010) Plasticized chitosan-PVA blend polymer electrolyte based proton battery. Electrochim Acta 55: 1475-1482. doi: 10. 1016/j. electacta. 2009. 05. 011.
16. 3 polymer electrolyte. Mater Res Innov 15: S82-S85. doi: 10. 1179/143307511X1303189074.
17. Fan L, Dang Z, Nan CW, Li M (2002) Thermal, electrical and mechanical properties of plasticized polymer electrolytes based on PEO/P(VDF-HFP) blends. Electrochim Acta 48: 205-209. doi: 10. 1016/S0013-4686(02)00603-5.
18. Sandoval C, Castro C, Gargallo L, Radic D, Freire J (2005) Specific interactions in blends containing chitosan and functionalized polymers. Molecular dynamics simulations. Polymer 46: 10437-10442. doi: 10. 1016/j. polymer. 2005. 08. 059.
19. El-Kader MFHA, Ragab HS (2013) DC conductivity and dielectric properties of maize starch/methylcellulose blend films. Ionics 19: 361-369. doi: 10. 1007/s11581-012-0742-8.
20. 4I. J Non-Cryst Solids 357: 3261-3266. doi: 10. 1016/j. jnoncrysol. 2011. 05. 021.
21. Rajendran S, Mahendran O (2001) Experimental investigations on plasticized PMMA/PVA polymer blend electrolytes. Ionics 7: 463-468. doi: 10. 1007/BF02373585.
22. Bourtoom T, Chinnan MS (2008) Preparation and properties of rice starch-chitosan blend biodegradable film. LWT-Food Sci Technol 41: 1633-1641. doi: 10. 1016/j. lwt. 2007. 10. 014.
23. Zhai M, Zhao L, Yoshii F, Kume T (2004) Study on antibacterial starch/chitosan blend film formed under the action of irradiation. Carbohydr Polym 57: 83-88. doi: 10. 1016/j. carbpol. 2004. 04. 003.
24. Xu YX, Kim KM, Hanna MA, Nag D (2005) Chitosan-starch composite film: preparation and characterization. Ind Crop Prod 21: 185-192. doi: 10. 1016/j. indcrop. 2004. 03. 002.
25. Nakajima H, Honma I (2002) Proton-conducting hybrid solid electrolytes for intermediate temperature fuel cells. Solid State Ionics 148: 607-610. doi: 10. 1016/S0167-2738(02)00127-3.
26. Pratap R, Singh B, Chandra S (2006) Polymeric rechargeable solid-state proton battery. J Power Sources 161: 702-706. doi: 10. 1016/j. jpowsour. 2006. 04. 020.
27. Wang P (2008) Granular starch hydrolysis for fuel ethanol production. Dissertation, University of Illinois.
28. Pomeranz Y (1991) Functional properties of food components, 2nd edn. San Diego, California.
29. Knorr D, Heinz V, Buckow R (2006) High pressure application for food biopolymers. Biochim Biophys Acta 1764: 619-631. doi: 10. 1016/j. bbapap. 2006. 01. 017.
30. Zarillo S, Pearsall DM, Raymond JS, Tisdale MA, Quon DJ (2008) Directly dated starch residues document early formative maize (Zea mays L.) in tropical Ecuador. Proc Natl Acad Sci U S A 105: 5006-5011. doi: 10. 1073/pnas. 0800894105.
31. Ramesh S, Shanti R, Morris E (2012) Studies on the thermal behavior of CS: LiTFSI:[Amim] Cl polymer electrolytes exerted by different [Amim] Cl content. Solid State Sci 14: 182-186. doi: 10. 1016/j. solidstatesciences. 2011. 11. 022.
32. Lu DR, Xiao CM, Xu SJ (2009) Starch-based completely biodegradable polymer materials. Express Polym Lett 3: 366-375. doi: 10. 3144/expresspolymlett. 2009. 46.
33. 3 polymer electrolytes. Solid State Ionics 225: 649-653. doi: 10. 1016/j. ssi. 2012. 03. 019.
34. Halim NFA, MAjid SR, Arof AK, Kajzar F, Pawlicka A (2012) Gellan gum-LiI gel polymer electrolytes. Mol Cryst Liq Cryst 554: 232-238. doi: 10. 1080/15421406. 2012. 634344.
35. Ayala G, Agudelo A, Vargas R (2012) Effect of glycerol on the electrical properties and phase behavior of cassava starch biopolymers. DYNA 79: 138-147.
36. Samsudin AS, Khairul WM, Isa MIN (2012) Characterization on the potential of carboxy methylcellulose for application as proton conducting biopolymer electrolytes. J Non-Cryst Solids 358: 1104-1112. doi: 10. 1016/j. jnoncrysol. 2012. 02. 004.
37. 3 polymer electrolyte. J Non-Cryst Solids 356: 2277-2281. doi: 10. 1016/j. jnoncrysol. 2010. 08. 011.
38. 2O-MO (M = Pb, Zn) glass thin films and study of thin properties. Dissertation, Mahatma Gandhi University.
39. Stephan AM, Thirunakaran R, Renganathan NG, Sundaram V, Pitchumani S, Muniyandi N, Gangadharan R, Ramamoorthy P (1999) A study on polymer blend electrolyte based on PVC/PMMA with lithium salt. J Power Sources 81-82: 752-758. doi: 10. 1016/S0378-7753(99)00148-2.
40. 4Br polymer electrolyte system. Physica B 403: 2740-2747. doi: 10. 1016/j. physb. 2008. 02. 001.
41. 4SCN polymer electrolytes. Physica B 357: 412-419. doi: 10. 1016/j. physb. 2004. 12. 007.
42. Khiar AS, Arof AK (2010) Conductivity studies of starch-based polymer electrolytes. Ionics 16: 123-129. doi: 10. 1007/s11581-009-0356-y.
43. Han DG, Choi GM (1998) Computer simulation of the electrical conductivity of composites: the effect of geometrical arrangement. Solid State Ionics 106: 71-87. doi: 10. 1016/S0167-2738(97)00484-0.
44. 3. Ionics 18: 655-665. doi: 10. 1007/s11581-012-0667-2.
45. 3 composite polymer electrolyte with blocking electrodes. Electrochim Acta 46: 1829-1836. doi: 10. 1016/S0013-4686(00)00723-4.
46. Shuhaimi NEA, Teo LP, Woo HJ, Majid SR, Arof AK (2012) Electrical double-layer capacitors with plasticized polymer electrolyte based on methyl cellulose. Polym Bull 69: 807-826. doi: 10. 1007/s00289-012-0763-5.
47. Shukur MF, Ithnin R, Illias H, Kadir MFZ (2013) Proton conducting polymer electrolyte based on plasticized chitosan-PEO blend and application in electrochemical devices. Opt Mater 35: 1834-1841. doi: 10. 1016/j. optmat. 2013. 03. 004.
48. Kumar DA, Selvasekarapandian S, Baskaran R, Savitha T, Nithya D (2012) Thermal, vibrational and ac impedance studies on proton conducting polymer electrolytes based on poly(vinyl acetate). J Non-Cryst Solids 358: 531-536. doi: 10. 1016/j. jnoncrysol. 2011. 11. 031.
49. Gondaliya N, Kanchan DK, Sharma P (2013) Effect of a plasticizer on a solid polymer electrolyte. Soc Plast Eng. doi: 10. 2417/spepro. 004646.
50. 4) polymer electrolyte system. IOSR J Appl Phys 2: 1-6.
51. Ibrahim S, Johan MR (2012) Thermolysis and conductivity studies of poly(ethylene oxide) (PEO) based polymer electrolytes doped with carbon nanotube. Int J Electrochem Sci 7: 2596-2615.
52. Johan MR, Ting LM (2011) Structural, thermal and electrical properties of nano manganese-composite polymer electrolytes. Int J Electrochem Sci 6: 4737-4748.
53. Sudhakar YN, Selvakumar M (2012) Lithium perchlorate doped plasticized chitosan and starch blend as biodegradable polymer electrolyte for supercapacitors. Electrochim Acta 78: 398-405. doi: 10. 1016/j. electacta. 2012. 06. 032.
54. 4X (X = Cl, Br, I). J Non-Cryst Solids 355: 84-90. doi: 10. 1016/j. jnoncrysol. 2008. 10. 009.
55. 4I doped chitosan solid electrolyte. Physica B 404: 1373-1379. doi: 10. 1016/j. physb. 2008. 12. 027.
56. Rice MJ, Roth WL (1972) Ionic transport in super ionic conductors: a theoretical model. J Solid State Chem 4: 294-310. doi: 10. 1016/0022-4596(72)90121-1.
57. Ramasamy P (2012) A dielectric relaxation study of starch-water and starch-glycerol films. Ionics 18: 413-423. doi: 10. 1007/s11581-011-0636-1.
58. Hegenbart S (1996) Understanding starch functionality. Food product design. http://www. foodproductdesign. com/articles/1996/01/understanding-starch-functionality. aspx. Accessed 1 January 1996.
59. Ning W, Xingxiang Z, Haihui L, Jianping W (2009) N, N-dimethylacetamide/lithium chloride plasticized starch as solid biopolymer electrolytes. Carbohydr Polym 77: 607-611. doi: 10. 1016/j. carbpol. 2009. 02. 002.
60. Corn Refiners Association (2006) Corn Refiners Technical Booklet. Corn starch. Eleventh Edition. Washington D. C., USA. http://www. corn. org/wp-content/uploads/2009/12/Starch2006. pdf.
61. Winie T, Arof AK (2006) Transport properties of hexanoyl chitosan-based gel electrolyte. Ionics 12: 149-152. doi: 10. 1007/s11581-006-0026-2.
62. Majid SR, Arof AK (2005) Proton-conducting polymer electrolyte films based on chitosan acetate complexed with NH4NO3 salt. Physica B 355: 78-82. doi: 10. 1016/j. physb. 2004. 10. 025.
63. Winie T, Ramesh S, Arof AK (2009) Studies on the structure and transport properties of hexanoyl chitosan-based polymer electrolytes. Physica B 404: 4308-4311. doi: 10. 1016/j. physb. 2009. 08. 004.
64. Lesmes DP, Friedman SP (2005) Relationships between the electrical and hydrogeological properties of rocks and soils. In: Rubin Y, Hubbard SS (eds) Hydrogeophysics. Springer, Dordrecht, pp 87-128.
65. Saikia D, Pan YC, Kao HM (2012) Synthesis, multinuclear NMR characterization and dynamic property of organic-inorganic hybrid electrolyte membrane based on alkoxysilane and poly(oxyalkylene) diamine. Membranes 2: 253-274. doi: 10. 3390/membranes2020253.
66. Liu P, Yu L, Liu H, Chen L, Li L (2009) Glass transition temperature of starch studied by a high-speed DSC. Carbohydr Polym 77: 250-253. doi: 10. 1016/j. carbpol. 2008. 12. 027.
67. 1ρ CRAMPS. J Appl Polym Sci 86: 1253-1258. doi: 10. 1002/app. 11091.
68. Kumar M, Sekhon SS (2002) Role of plasticizer's dielectric constant on conductivity modification of PEO-NH4F polymer electrolytes. Eur Polym J 38: 1297-1304. doi: 10. 1016/S0014-3057(01)00310-X.
69. 3 polymer electrolyte membrane. Spectrochim Acta A 78: 1068-1074. doi: 10. 1016/j. saa. 2010. 12. 051.
70. Mason RN, Hu L, Glatzhofer DT, Frech R (2010) Infrared spectroscopic and conductivity studies of poly(N-methylpropylenimine)/lithium triflate electrolytes. Solid State Ionics 180: 1626-1632. doi: 10. 1016/j. ssi. 2009. 10. 021.
71. 3-DMF electrolytes. Eur Polym J 40: 1841-1847. doi: 10. 1016/j. eurpolymj. 2004. 03. 026.
72. Ning W, Xingxiang Z, Haihui L, Benqiao H (2009) 1-Allyl-3-methylimidazolium chloride plasticized-corn starch as solid biopolymer electrolytes. Carbohydr Polym 76: 482-484. doi: 10. 1016/j. carbpol. 2008. 11. 005.
73. Liang S, Huang Q, Liu L, Yam KL (2009) Microstructure and molecular interaction in glycerol plasticized chitosan/poly(vinyl alcohol) blending films. Macromol Chem Phys 210: 832-839. doi: 10. 1002/macp. 200900053.
74. Woo HJ, Majid SR, Arof AK (2012) Dielectric properties and morphology of polymer electrolyte based on poly(e{open}-caprolactone) and ammonium thiocyanate. Mater Chem Phys 134: 755-761. doi: 10. 1016/j. matchemphys. 2012. 03. 064.
75. Woo HJ, Majid SR, Arof AK (2011) Conduction and thermal properties of a proton conducting polymer electrolyte based on poly (ε-caprolactone). Solid State Ionics 199-2000: 14-20. doi: 10. 1016/j. ssi. 2011. 07. 007.
76. Aziz NA, Majid SR, Arof AK (2012) Synthesis and characterizations of phthaloyl chitosan-based polymer electrolytes. J Non-Cryst Solids 358: 1581-1590. doi: 10. 1016/j. jnoncrysol. 2012. 04. 019.
77. Ramesh S, Yahaya AH, Arof AK (2002) Dielectric behaviour of PVC-based polymer electrolytes. Solid State Ionics 152-153: 291-294. doi: 10. 1016/S0167-2738(02)00311-9.
78. Mishra R, Rao KJ (1998) Electrical conductivity studies of poly(ethyleneoxide)-poly(vinylalcohol) blends. Solid State Ionics 106: 113-127. doi: 10. 1016/S0167-2738(97)00493-1.
79. Ali RM, Harun NI, Ali AMM, Yahya MZA (2011) Conductivity studies on plasticised cellulose acetate-ammonium iodide based polymer electrolytes. Mater Res Innov 15: S39-S42. doi: 10. 1179/143307511X13031890747570.
80. 2 nanocomposite polymer electrolytes. Mater Res Innov 13: 255-258. doi: 10. 1179/143307509X440451.
81. Kato Y, Hasumi K, Yokoyama S, Yabe T, Ikuta H, Uchimoto Y, Wakihara M (2002) Influence of peg-borate ester on thermal property and ionic conductivity of the polymer electrolyte. J Therm Anal Calorim 69: 889-896. doi: 10. 1023/A: 1020664107896.
82. Hashim MA, Khiar ASA (2011) Supercapacitor based on activated carbon and hybrid solid polymer electrolyte. Mater Res Innov 15: S63-66. doi: 10. 1179/143307511X13031890747813.
83. Subban RHY, Arof AK (2003) Impedance spectroscopic studies on a binary salt poly(vinyl chloride) based electrolyte. Ionics 9: 375-381. doi: 10. 1007/BF02376589.
84. 4SCN polymer electrolyte. J Non-Cryst Solids 354: 1494-1502. doi: 10. 1016/j. jnoncrysol. 2007. 08. 038.
85. Idris NH, Senin HB, Arof AK (2007) Dielectric spectra of LiTFSI-doped chitosan/PEO blends. Ionics 13: 213-217. doi: 10. 1007/s11581-007-0093-z.
86. 3 polymer electrolytes. Mater Res Innov 13: 285-287. doi: 10. 1179/143307509X440541.
87. Williams G, Watts DC (1970) Non-symmetrical dielectric relaxation behaviour arising from a simple empirical decay function. Trans Faraday Soc 66: 80-85. doi: 10. 1039/TF9706600080.
88. Dutta P, Biswas S, De SK (2002) Dielectric relaxation in polyaniline-polyvinyl alcohol composites. Mater Res Bull 37: 193-200. doi: 10. 1016/S0025-5408(01)00813-3.
89. 3)], where 1 ≤ x/y ≤ 3. Solid State Ionics 177: 475-482. doi: 10. 1016/j. ssi. 2005. 12. 019.
90. Ramesh S, Arof AK (2001) Ionic conductivity studies of plasticized poly(vinyl chloride) polymer electrolytes. Mater Sci Eng B 85: 11-15. doi: 10. 1016/S0921-5107(01)00555-4.
91. 2. Mater Chem Phys 116: 81-87. doi: 10. 1016/j. matchemphys. 2009. 02. 056.
92. Aziz SB, Abidin ZHZ, Arof AK (2010) Influence of silver ion reduction on electrical modulus parameters of solid polymer electrolyte based on chitosan-silver triflate electrolyte membrane. Express Polym Lett 5: 300-310. doi: 10. 3144/expresspolymlett. 2010. 38.
93. Ramesh S, Liew CW, Arof AK (2011) Ion conducting corn starch biopolymer electrolytes doped with ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate. J Non-Cryst Solids 357: 3654-3660. doi: 10. 1016/j. jnoncrysol. 2011. 06. 030.
94. Hema M, Selvasekarapandian S, Nithya H, Sakunthala A, Arunkumar D (2009) Structural and ionic conductivity studies on proton conducting polymer electrolyte based on polyvinyl alcohol. Ionics 15: 487-491. doi: 10. 1007/s11581-008-0254-8.
95. Jonscher AK (1996) Universal relaxation law. Chelsea Dielectrics Press, London.
96. 3 glassy system. Mater Chem Phys 65: 275-281. doi: 10. 1016/S0254-0584(00)00244-3.
97. Kadir MFZA, Teo LP, Majid SR, Arof AK (2009) Conductivity studies on plasticised PEO/chitosan proton conducting polymer electrolyte. Mater Res Innov 13: 259-262. doi: 10. 1179/143307509X440460.
98. Kufian MZ, Majid SR, Arof AK (2007) Dielectric and conduction mechanism studies of PVA-orthophosphoric acid polymer electrolyte. Ionics 13: 231-234. doi: 10. 1007/s11581-007-0098-7.