Experimental and numerical validation of the effective medium theory for the B-term band broadening in 1st and 2nd generation monolithic silica columns

Journal of Chromatography A

Volumn 1351, Issue , 2014, Pages 46-55

  Deridder, Sander ^a   Vanmessen, Alison ^b   Nakanishi, Kazuki ^c   Desmet, Gert ^a   Cabooter, Deirdre ^b  

^a VRIJE UNIVERSITEIT BRUSSEL   (Belgium)

^b UNIVERSITY OF LEUVEN   (Belgium)

^c KYOTO UNIVERSITY   (Japan)

Author keywords

Effective diffusion; Effective medium theory; Modeling; Monolithic porous medium; Peak parking

Indexed keywords

MESOPOROUS MATERIALS; MODELS; MUSCULOSKELETAL SYSTEM; POROSITY; SILICA;

EFFECTIVE DIFFUSION; EFFECTIVE MEDIUM THEORIES; EXPERIMENTAL AND NUMERICAL VALIDATIONS; MESOPOROUS SKELETONS; MONOLITHIC SILICA COLUMNS; PEAK PARKING; POROUS MEDIUM; TETRAHEDRAL SKELETON MODEL;

DIFFUSION;

SILICON DIOXIDE;

ARTICLE; CHEMICAL ANALYSIS; CHEMICAL STRUCTURE; CONCENTRATION (PARAMETERS); CONTROLLED STUDY; DATA ANALYSIS; DIFFUSION; EFFECTIVE MEDIUM THEORY; INTERMETHOD COMPARISON; LONGITUDINAL STUDY; MATHEMATICAL COMPUTING; MATHEMATICAL MODEL; POROSITY; PREDICTION; PRIORITY JOURNAL; PROCESS DEVELOPMENT; PROCESS MODEL;

EFFECTIVE DIFFUSION; EFFECTIVE MEDIUM THEORY; MODELING; MONOLITHIC POROUS MEDIUM; PEAK PARKING;

CHROMATOGRAPHY; COMPUTER SIMULATION; DIFFUSION; MODELS, CHEMICAL; POROSITY; REPRODUCIBILITY OF RESULTS; SILICON DIOXIDE;

EID: 84902242850     PISSN: 00219673     EISSN: 18733778     Source Type: Journal    
DOI: 10.1016/j.chroma.2014.04.099     Document Type: Article

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