Physicochemical and catalytic properties of montmorillonites modified with 12-tungstophosphoric acid

Applied Clay Science

Volumn 95, Issue , 2014, Pages 220-231

  Pacuła, Aleksandra ^a   Pamin, Katarzyna ^a   Zieba, Adam ^a   Kryściak Czerwenka, Joanna ^a   Olejniczak, Zbigniew ^b   Serwicka, Ewa M ^a   Drelinkiewicz, Alicja ^a  

^a INSTITUTE OF CATALYSIS AND SURFACE CHEMISTRY   (Poland)

^b INSTITUTE OF NUCLEAR PHYSICS   (Poland)

Author keywords

Dehydration of ethanol; Keggin like structure; Montmorillonite; Transesterification of castor oil

Indexed keywords

BENTONITE; CATALYST ACTIVITY; DEPOSITION; DISPERSIONS; ETHANOL; IMPREGNATION; ION EXCHANGE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; SODIUM; TRANSESTERIFICATION; VEGETABLE OILS;

12-TUNGSTOPHOSPHORIC ACID; CASTOR OIL; DEHYDRATION OF ETHANOL; HIGH CATALYTIC PERFORMANCE; INCIPIENT WETNESS IMPREGNATION METHOD; MONTMORILLONITE SUPPORTS; SUPPORTED HETEROPOLY ACID;

CLAY MINERALS;

ACIDITY; CATALYSIS; CATALYST; DEHYDRATION; ETHANOL; MONTMORILLONITE; PHYSICOCHEMICAL PROPERTY; VEGETABLE OIL;

EID: 84902116636     PISSN: 01691317     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.clay.2014.04.016     Document Type: Article

References (51)

1. Ahmed O.S., Dutta D.K. Friedel-Crafts benzylation of benzene using Zn and Cd ions exchanged clay composites. J. Mol. Catal. A 2005, 229:227-231.
2. Atkins, M.P., 1997. US Patent 5 629 459 to BP CHEM INT LTD.
3. Barshad I. The nature of lattice expansion and its relation to hydration in montmorillonite and vermiculite. Am. Mineral. 1949, 34:675-684.
4. Barshad I. The effect of the interlayer cations on the expansion of the mica type of crystal lattice. Am. Mineral. 1950, 35:225-238.
5. Bhorodwaj S.K., Dutta D.K. Heteropoly acid supported modified montmorillonite clay: an effective catalyst for the esterification on acetic acid with sec-butanol. Appl. Catal. A 2010, 378:221-226.
6. Bhorodwaj S.K., Dutta D.K. Activated clay supported heteropoly acid catalysts for esterification of acetic acid with butanol. Appl. Clay Sci. 2011, 53:347-352.
7. Bhorodwaj S.K., Pathak M.G., Dutta D.K. Esterification of acetic acid with n-butanol using heteropoly acid supported modified clay catalyst. Catal. Lett. 2009, 133:185-191.
8. Bielański A., Lubańska A. FTIR investigation on Wells-Dawson and Keggin type heteropolyacids: dehydration and ethanol sorption. J. Mol. Catal. A Chem. 2004, 224:179-187.
9. Bielański A., Lubańska A., Poźniczek J., Micek-Ilnicka A. Oxide supports for 12-tungstosilicic acid catalysts in gas phase synthesis of MTBE. Appl. Catal. A 2003, 238:239-250.
10. Bokade V.V., Yadav G.D. Transesterification of edible and nonedible oils with alcohols over heteropolyacids supported on acid-treated clay. Ind. Eng. Chem. Res. 2009, 48:9408-9415.
11. Bokade V.V., Yadav G.D. Heteropolyacid supported on montmorillonite catalyst for dehydration of dilute bio-ethanol. Appl. Clay Sci. 2011, 53:263-271.
12. 40 supported on silica. Catal. Lett. 1994, 25:225-240.
13. Cseri T., Békássy S., Figueras F., Cseke E., Menorval L.C., Dutartre R. Characterization of clay-based catalysts and their application in Friedel-Craft alkylation of aromatics. Appl. Catal. A 1995, 132:141-155.
14. 2. Catal. Lett. 1998, 51:77-83.
15. Haber J., Pamin K., Matachowski L., Napruszewska B., Połtowicz J. Potassium and silver salt of tungstophosphoric acid as catalysts in dehydration of ethanol and hydration of ethylene. J. Catal. 2002, 207:296-306.
16. Haber J., Pamin K., Matachowski L., Mucha D. Catalytic performance of the dodecatungstophosphoric acid on different supports. Appl. Catal. A 2003, 256:141-152.
17. Hart M.P., Brown D.R. Surface acidities and catalytic activities of acid-activated clays. J. Mol. Catal. A 2004, 212:315-321.
18. Hayashi H., Moffat J.B. The properties of heteropoly acids and the conversion of methanol to hydrocarbons. J. Catal. 1982, 77:473-484.
19. Knifton, J.F., 1990. US Patent 4 898 987 to Texaco Chemical Company.
20. Knifton, J.F., Grice, N.J., 1992. US Patent 5 107 027 to Texaco Chemical Company.
21. 40 supported on MCM-41 molecular sieve and amorphous silica. J. Mol. Catal. 1996, A114:287-298.
22. -. J. Chem. Soc. Chem. Commun. 1992, 756-757.
23. 40 supported on various porous silica-based materials. Microporous Mesoporous Mater. 1998, 22:151-163.
24. 2. J. Mol. Catal. 1990, 60:65-70.
25. McGarvey G.B., Moffat J.B. A study of solution species generated during the formation of 12-heteropoly oxometalate catalysts. J. Mol. Catal. 1991, 69:137-155.
26. Misono M. Unique acid catalysis of heteropoly compounds (heteropolyoxometalates) in the solid state. Chem. Commun. 2001, 1141-1152.
27. Nowińska K., Fórmaniak R., Kaleta W., Wacław A. Heteropoly compounds incorporated into mesoporous material structure. Appl. Catal. A 2003, 256:115-123.
28. Okuhara T., Mizuno N., Misono M. Catalytic chemistry of heteropoly compounds. Adv. Catal. 1996, 41:113-252.
29. Pacuła A., Bielańska E., Gaweł A., Bahranowski K., Serwicka E.M. Textural effects in powdered montmorillonite induced by freeze-drying and ultrasound pretreatment. Appl. Clay Sci. 2006, 32:64-72.
30. Pamin K., Kubacka A., Olejniczak Z., Haber J., Sulikowski B. Immobilization of dodecatungstophosphoric acid on dealuminated zeolite Y: a physicochemical study. Appl. Catal. A 2000, 194(195):137-146.
31. Pizzio L.R., Cáceres C.V., Blanco M.N. Acid catalysts prepared by impregnation of tungstophosphoric acid solutions on different supports. Appl. Catal. A 1998, 167:283-294.
32. Pope M.T. Heteropoly and Isopoly Oxometalates 1983, Springer-Verlag Berlin, Heidelberg.
33. Rožić L., Grbić B., Radić N., Petrović S., Novaković T., Vuković Z., Nedić Z. Mesoporous 12-tungstophosporic acid/activated bentonite catalysts for oxidation of 2-propanol. Appl. Clay Sci. 2011, 53:151-156.
34. Soetaredjo F.E., Ayucitra A., Ismadji S., Maukar A.L. KOH/bentonite catalysts for transesterification of palm oil to biodiesel. Appl. Clay Sci. 2011, 53:341-346.
35. Sulikowski B., Rachwalik R. Catalytic properties of heteropoly acid/zeolite hybrid materials: toluene disproportionation and transalkylation with 1,2,4-trimethylbenzene. Appl. Catal. A 2003, 256:173-182.
36. Teoh L.G., Shieh J., Lai W.H., Hung I.M., Hon M.H. Structure and optical properties of mesoporous tungsten oxide. J. Alloys Compd. 2005, 396:251-254.
37. 40. Top. Catal. 2001, 15:73-81.
38. Trpkovska M., Šoptrajanov B. Tetraamminecopper (II) molybdate and tetraamminecopper (II) tungstate: a Fourier-transform infrared study. J. Mol. Struct. 1997, 408(409):345-348.
39. Varisli D., Dogu T., Dogu G. Ethylene and diethyl-ether production by dehydration reaction of ethanol over different heteropolyacid catalysts. Chem. Eng. Sci. 2007, 62:5349-5352.
40. Villegas R.A.S., Espírito Santo J.L., Mattos M.C.S., Aguiar M.R.M.P., Guarino A.W.S. Characterization of natural Brazilian clays and their utilization as catalysts in the coiodination of alkenes with water and alcohols. J. Braz. Chem. Soc. 2005, 16:565-570.
41. Yadav G.D. Synergism of clay and heteropoly acids as nano-catalysts for the development of green processes with potential industrial applications. Catal. Surv. Jpn. 2005, 9:117-137.
42. Yadav G.D., Asthana N.S. Kinetics and mechanism of selective monoacylation of mesitylene. Ind. Eng. Chem. Res. 2002, 41:5565-5575.
43. Yadav G.D., Bokade V.V. Novelties of heteropoly acid supported on clay: etherification of phenethyl alcohol with alkanols. Appl. Catal. A 1996, 147:299-323.
44. Yadav G.D., Doshi N.S. Alkylation of hydroquinone with methyl-tert-butyl-ether and tert-butanol. Catal. Today 2000, 60:263-273.
45. Yadav G.D., Doshi N.S. Alkylation of aniline with methyl-tert-butyl-ether (MTBE) and tert-butanol over solid acids: product distribution and kinetics. J. Mol. Catal. A 2003, 194:195-209.
46. Yadav G.D., Kirthivasan N. Single-pot synthesis of methyl tert-butyl ether from tert-butyl alcohol and methanol: dodecatungstophosphoric acid supported on clay as an efficient catalyst. J. Chem. Soc. Chem. Commun. 1995, 203-204.
47. Yadav G.D., Krishnan M.S. Etherification of β-naphtol with alkanols using modified clays and sulfated zirconia. Ind. Eng. Chem. Res. 1998, 37:3358-3365.
48. Zhao H., Zhou C.H., Wu L.M., Lou J.Y., Li N., Yang H.M., Tong D.S., Yu W.H. Catalytic dehydration of glycerol to acrolein over sulfuric acid-activated montmorillonite catalysts. Appl. Clay Sci. 2013, 74:154-162.
49. Zieba A., Matachowski L., Lalik E., Drelinkiewicz A. Methanolysis of castor oil catalysed by solid potassium and cesium salts of 12-tungstophosphoric acid. Catal. Lett. 2009, 127:183-194.
50. Zieba A., Pacuła A., Dreliniewicz A. Transesterification of triglycerides with methanol catalyzed by heterogeneous zinc hydroxy nitrate catalyst. Evaluation of variables affecting the activity and stability of catalyst. Energy Fuel 2010, 24:634-645.
51. 40. J. Mol. Catal. A Chem. 2010, 316:30-44.