Thermodynamic Modelling of Hydrogel Systems

Progress in Colloid and Polymer Science

Volumn 140, Issue , 2013, Pages 175-187

  Arndt, Markus C ^a   Sadowski, Gabriele ^a  

^a TU DORTMUND UNIVERSITY   (Germany)

Author keywords

Hydrogel; Organic solvents; PNIPAAm; Salts; Swelling

Indexed keywords

EID: 84901988595     PISSN: 0340255X     EISSN: None     Source Type: Book Series    
DOI: 10.1007/978-3-319-01683-2_14     Document Type: Chapter

References (41)

1. Patenaude M, Hoare T (2012) Injectable, degradable thermoresponsive poly(N-isopropylacrylamide) hydrogels. ACS Macro Lett 1:409-413
2. Wohlfarth C (2000) Thermodynamic data of copolymer solutions. CRC Press, Boca Raton
3. Tao C-T, Young T-H (2005) Phase behavior of poly(N-iso-propylacrylamide) in water-methanol cononsolvent mixtures and its relevance to membrane formation. Polymer 46:10077-10084
4. Winnik FM et al (1993) Cononsolvency of poly(N-isopr-opylacrylamide): a look at spin-labeled polymers in mixtures of water and tetrahydrofuran. Macromolecules 26:4577-4585
5. Winnik FM, Ringsdorf H, Venzmer J (1990) Methanol-water as a co-nonsolvent system for poly(N-isopropylacrylamide). Macromolecules 23:2415-2416
6. Tanaka F, Koga T, Winnik FM (2008) Temperature-responsive polymers in mixed solvents: competitive hydrogen bonds cause cononsolvency. Phys Rev Lett 101(2):028302-1-028302-4
7. Tanaka F et al (2011) Preferential adsorption and co-nonsolvency of thermoresponsive polymers in mixed solvents of water/methanol. Macromolecules 44:2978-2989
8. Costa ROR, Freitas RFS (2002) Phase behavior of poly(N-isopr-opylacrylamide) in binary aqueous solutions. Polymer 43:5879-5885
9. Schild HG, Muthukumar M, Tirrell DA (1991) Cononsolvency in mixed aqueous solutions of poly(N-isopropylacrylamide). Macromolecules 24:948-982
10. Mukae K et al (1993) Swelling of poly(N-isopropylacrylamide) gels in water-alcohol (C1-C4) mixed solvents. J Phys Chem B 97:737-741
11. Arndt MC, Sadowski G (2012) Modeling poly(N-isop-ropylacrylamide) hydrogels in water/alcohol mixtures with PC-SAFT. Macromolecules 45:6686-6696
12. Flory PJ (1953) Principles of polymer chemistry. Cornell University Press, London
13. Flory PJ (1950) Statistical mechanics of swelling of network structures. J Chem Phys 18(1):108-111
14. Flory PJ (1951) Statistical thermodynamics of rubber elasticity. J Chem Phys 19(12):1435-1439
15. Flory PJ, Rehner J (1943) Statistical mechanics of cross-linked polymer networks. J Chem Phys 11(11):512-520
16. Guth E, James HM (1941) Elastic and thermoelastic properties of rubberlike materials. Ind Eng Chem 33(5):624-629
17. James HM, Guth E (1953) Statistical thermodynamics of rubber elasticity. J Chem Phys 21(6):1039-1049
18. Peterson LE, Anthony RL, Guth E (1942) Equation of state of some synthetic rubbers. Ind Eng Chem 34(11):1349-1352
19. Miao B et al (2010) Effect on finite extensibility on the equilibrium chain size. Macromol Theory Simul 19:414-420
20. Zhi D et al (2010) A molecular thermodynamic model for temperature-and solvent-sensitive hydrogels, application to the swelling behavior of PNIPAm hydrogels in ethanol/water mixtures. Chem Eng Sci 65:3223-3230
21. Koga T et al (2008) Theoretical modeling of associated structures in aqueous solutions of hydrophobically modified telechelic PNIPAM Based on a neutron scattering study. Macromolecules 41:9413-9422
22. Maurer G, Prausnitz JM (1996) Thermodynamics of phase equilibrium for systems containing gels. Fluid Phase Equilibr 115:113-133
23. Poschlad K, Enders S (2011) Thermodynamics of aqueous solutions containing poly(N-isopropylacrylamide). Fluid Phase Equilibr 302:153-160
24. Althans D, Langenbach K, Enders S (2012) Influence of different alcohols on the swelling behaviour of hydrogels. Mol Phys 110(11-12):1391-1402
25. Gross J, Sadowski G (2001) Perturbed-chain SAFT: an equation of state based on a perturbation theory for chain molecules. Ind Eng Chem Res 40(4):1244-1260
26. Gross J, Sadowski G (2002) Modeling polymer systems using the perturbed-chain statistical associating fluid theory equation of state. Ind Eng Chem Res 41(5):1084-1093
27. Gross J, Sadowski G (2002) Application of the perturbed-chain SAFT equation of state to associating systems. Ind Eng Chem Res 41(22):5510-5515
28. Cameretti LF, Sadowski G (2005) Modeling of aqueous electrolyte solutions with perturbed-chain statistical associated fluid theory. Ind Eng Chem Res 44:3355-3362
29. Held C, Cameretti LF, Sadowski G (2008) Modeling aqueous electrolyte solutions-Part 1. Fully dissociated electrolytes. Fluid Phase Equilibr 270(1-2):87-96
30. Chapman WG et al (1990) New reference equation of state for associating liquids. Ind Eng Chem Res 29:1709-1721
31. Huang SH, Radosz M (1990) Equation of state for small, large, polydisperse, and associating molecules. Ind Eng Chem Res 29:2284-2294
32. Hüther A (2000) Experimentelle und theoretische Untersuchungen zum Quellungsgleichgewicht von Hydrogelen in wässrigen Lösungen. In: Lehrstuhl für Thermodynamik. Technische Universität Kaiserslautern, Kaiserslautern
33. Orlov Y, Xu X, Maurer G (2005) Swelling of a N-isopropyl acrylamide hydrogel in two aqueous/organic two-phase systems. Fluid Phase Equilibr 235:18-25
34. Held C et al. (2013) ePC-SAFT revised (in preparation)
35. Stoychev I et al (2009) Modeling the phase behavior of PEO-PPO-PEO surfactants in carbon dioxide using the PC-SAFT equation of state-application to dry decontamination of solid substances. J Chem Eng Data 54:1551-1559
36. Kleiner M (2008) Thermodynamic modeling of complex systems: polar and associating fluids and mixtures. In: Laboratory of Thermodynamics. Technische Universität Dortmund, Dortmund
37. Poschlad K (2011) Experimentelle und theoretische Untersuchungen der Wirkstoffaufnahme und-abgabe von Poly-(N-isopropylacrylamid)-Hydrogelen. In: Thermodynamik und Thermische Verfahrenstechnik. Technische Universität Berlin, Berlin
38. Ishidao T et al (1993) Swelling behaviors of poly(N-isopr-opylacrylamide) gel in poly(ethylene glycol)-water mixtures. Macromolecules 26:7361-7362
39. Othmer DF, Chudgar MM, Levy SL (1952) Binary and ternary systems of acetone, methyl ethyl ketone, and water. Ind Eng Chem 44(8):1872-1881
40. Annaka M et al (2000) Salt-induced volume phase transition of poly(N-isopropylacrylamide) gel. J Chem Phys 113(14):5980-5985
41. Inomata H et al (1992) Effect of additives on phase transition of N-isopropylacrylamide gels. Langmuir 8:687-690