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wherein the C-Li bond is remarkably longer than the Li-O bond (224.5 pm versus 197.9 pm). A similar situation is observed in the ethyl ether solvate
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Langer, J.; Köhler, M.; Fischer, R.; Dündar, F.; Görls, H.; Westerhausen, M. Organometallics 2012, 31, 6172-6182 wherein the C-Li bond is remarkably longer than the Li-O bond (224.5 pm versus 197.9 pm). A similar situation is observed in the ethyl ether solvate
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(2012)
Organometallics
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Langer, J.1
Köhler, M.2
Fischer, R.3
Dündar, F.4
Görls, H.5
Westerhausen, M.6
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0020798850
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several other analogous systems, e.g. ENAWOF
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Hope, H.; Power, P. P. J. Am. Chem. Soc. 1982, 105, 5320-5324 and several other analogous systems, e.g., ENAWOF
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(1982)
J. Am. Chem. Soc.
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Hope, H.1
Power, P.P.2
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0141605074
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Even more remarkable, two or three lithium atoms are bound to a single benzene carbon in these solvates. The robustness of the proposed generalization is confirmed by the fact that whatever "bond" is considered the "interaction", lithium is the electrophilic ending, and the interaction is realistically designated a lithium bond
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Vestergren, M.; Eriksson, J.; Hilmersson, G.; Hakansson, M. J. Organomet. Chem. 2003, 682, 172-179 Even more remarkable, two or three lithium atoms are bound to a single benzene carbon in these solvates. The robustness of the proposed generalization is confirmed by the fact that whatever "bond" is considered the "interaction", lithium is the electrophilic ending, and the interaction is realistically designated a lithium bond
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(2003)
J. Organomet. Chem.
, vol.682
, pp. 172-179
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Vestergren, M.1
Eriksson, J.2
Hilmersson, G.3
Hakansson, M.4
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