Insight in the phase separation peculiarities of poly(dialkylaminoethyl methacrylate)s

Langmuir

Volumn 30, Issue 19, 2014, Pages 5609-5619

  Thavanesan, Thaanuskah ^a   Herbert, Christian ^b   Plamper, Felix A ^a  

^a RWTH AACHEN UNIVERSITY   (Germany)

^b DWI LEIBNIZ INSTITUTE FOR INTERACTIVE MATERIALS   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

FLUORESCENCE SPECTROSCOPY; HYDROGELS; HYDROPHOBICITY; POLYMERS;

CONSTANT TEMPERATURE; DIMETHYLAMINOETHYL METHACRYLATES; ELEVATED TEMPERATURE; LOWER CRITICAL SOLUTION TEMPERATURE BEHAVIOR; LOWER TEMPERATURES; N ,N-DIETHYLAMINOETHYL METHACRYLATE; PHASE SEPARATION MECHANISM; THERMO-RESPONSIVE;

PHASE SEPARATION;

EID: 84901036336     PISSN: 07437463     EISSN: 15205827     Source Type: Journal    
DOI: 10.1021/la5007583     Document Type: Article

References (66)

1. Plamper, F. A.; Synatschke, C. V.; Majewski, A. P.; Schmalz, A.; Schmalz, H.; Müller, A. H. E. Star-shaped poly(2-(dimethylamino)ethyl methacrylate) and its derivatives: Toward new properties and applications Polimery 2014, 59, 66-73
2. Plamper, F. A.; Ruppel, M.; Schmalz, A.; Borisov, O.; Ballauff, M.; Müller, A. H. E. Tuning the thermoresponsive properties of weak polyelectrolytes: Aqueous solutions of star-shaped and linear poly(N,N-dimethylaminoethyl methacrylate) Macromolecules 2007, 40, 8361-8366
3. Plamper, F. A.; Schmalz, A.; Ballauff, M.; Müller, A. H. E. Tuning the thermoresponsiveness of weak polyelectrolytes by pH and light: Lower and upper critical-solution temperature of poly(N,N-dimethylaminoethyl methacrylate) J. Am. Chem. Soc. 2007, 129, 14538-14539
4. Karjalainen, E.; Aseyev, V.; Tenhu, H. Influence of hydrophobic anion on solution properties of PDMAEMA Macromolecules 2014, 47, 2103-2111
5. Heyda, J.; Soll, S.; Yuan, J.; Dzubiella, J. Thermodynamic description of the LCST of charged thermoresponsive copolymers Macromolecules 2014, 47, 2096-2102
6. Savoji, M. T.; Strandman, S.; Zhu, J. X. X. Switchable vesicles formed by diblock random copolymers with tunable pH- and thermo-responsiveness Langmuir 2013, 29, 6823-6832
7. Huang, J.; Cusick, B.; Pietrasik, J.; Wang, L.; Kowalewski, T.; Lin, Q.; Matyjaszewski, K. Synthesis and in situ atomic force microscopy characterization of temperature-responsive hydrogels based on poly(2-(dimethylamino)ethyl methacrylate) prepared by atom transfer radical polymerization Langmuir 2007, 23, 241-249
8. Georgiou, T. K.; Vamvakaki, M.; Patrickios, C. S.; Yamasaki, E. N.; Phylactou, L. A. Nanoscopic cationic methacrylate star homopolymers: Synthesis by group transfer polymerization, characterization and evaluation as transfection reagents Biomacromolecules 2004, 5, 2221-2229
9. Xu, F. J.; Zhang, Z. X.; Ping, Y.; Li, J.; Kang, E. T.; Neoh, K. G. Star-shaped cationic polymers by atom transfer radical polymerization from beta-cyclodextrin cores for nonviral gene delivery Biomacromolecules 2009, 10, 285-93
10. Synatschke, C. V.; Schallon, A.; Jérôme, V.; Freitag, R.; Müller, A. H. E. Influence of polymer architecture and molecular weight of poly(2-(dimethylamino)ethyl methacrylate) polycations on transfection efficiency and cell viability in gene delivery Biomacromolecules 2011, 12, 4247-4255
11. Zhang, M.; Liu, L.; Wu, C.; Fu, G.; Zhao, H.; He, B. Synthesis, characterization and application of well-defined environmentally responsive polymer brushes on the surface of colloid particles Polymer 2007, 48, 1989-1997
12. Kind, L.; Plamper, F.; Göbel, R.; Müller, A.; Pieles, U.; Taubert, A.; Meier, W. Silsesquioxane/polyamine nanoparticle-templated formation of star- or raspberry-like silica nanoparticles Langmuir 2009, 25, 7109-7115
13. He, E.; Ravi, P.; Tam, K. C. Synthesis and self-assembly behavior of four-arm poly(ethylene oxide)-b-poly(2-(diethylamino)ethyl methacrylate) star block copolymer in salt solutions Langmuir 2007, 23, 2382-2388
14. Munoz-Bonilla, A.; Fernandez-Garcia, M.; Haddleton, D. M. Synthesis and aqueous solution properties of stimuli-responsive triblock copolymers Soft Matter 2007, 3, 725-731
15. Vamvakaki, M.; Palioura, D.; Spyros, A.; Armes, S. P.; Anastasiadis, S. H. Dynamic light scattering vs 1H NMR investigation of pH-responsive diblock copolymers in water Macromolecules 2006, 39, 5106-5112
16. Sun, J.-T.; Hong, C.-Y.; Pan, C.-Y. Fabrication of PDEAEMA-coated mesoporous silica nanoparticles and pH-responsive controlled release J. Phys. Chem. C 2010, 114, 12481-12486
17. Smith, A. E.; Xu, X.; Kirkland-York, S. E.; Savin, D. A.; McCormick, C. L. Schizophrenic self-assembly of block copolymers synthesized via aqueous RAFT polymerization: From micelles to vesicles Macromolecules 2010, 43, 1210-1217
18. Amalvy, J. I.; Wanless, E. J.; Li, Y.; Michailidou, V.; Armes, S. P.; Duccini, Y. Synthesis and characterization of novel pH-responsive microgels based on tertiary amine methacrylates Langmuir 2004, 20, 8992-8999
19. Dupin, D.; Armes, S. P.; Fujii, S. Stimulus-responsive liquid marbles J. Am. Chem. Soc. 2009, 131, 5386-5387
20. Howard, S. C.; Craig, V. S. J.; FitzGerald, P. A.; Wanless, E. J. Swelling and collapse of an adsorbed pH-responsive film-forming microgel measured by optical reflectometry and QCM Langmuir 2010, 26, 14615-14623
21. Li, Y.; Tang, Y.; Narain, R.; Lewis, A. L.; Armes, S. P. Biomimetic stimulus-responsive star diblock gelators Langmuir 2005, 21, 9946-54
22. Yan, B.; Han, D.; Boissiere, O.; Ayotte, P.; Zhao, Y. Manipulation of block copolymer vesicles using CO2: Dissociation or breathing Soft Matter 2013, 9, 2011-2016
23. Hu, Y. Q.; Kim, M. S.; Kim, B. S.; Lee, D. S. Synthesis and pH-dependent micellization of 2-(diisopropylamino)ethyl methacrylate based amphiphilic diblock copolymers via RAFT polymerization Polymer 2007, 48, 3437-3443
24. Du, J.; Tang, Y.; Lewis, A. L.; Armes, S. P. pH-Sensitive vesicles based on a biocompatible zwitterionic diblock copolymer J. Am. Chem. Soc. 2005, 127, 17982-17983
25. Bütün, V.; Armes, S. P.; Billingham, N. C. Synthesis and aqueous solution properties of near-monodisperse tertiary amine methacrylate homopolymers and diblock copolymers Polymer 2001, 42, 5993-6008
26. Stratakis, E.; Mateescu, A.; Barberoglou, M.; Vamvakaki, M.; Fotakis, C.; Anastasiadis, S. H. From superhydrophobicity and water repellency to superhydrophilicity: smart polymer-functionalized surfaces Chem. Commun. 2010, 46, 4136-4138
27. Schmalz, A.; Hanisch, M.; Schmalz, H.; Müller, A. H. E. Double stimuli-responsive behavior of linear and star-shaped poly(N,N-diethylaminoethyl methacrylate) in aqueous solution Polymer 2010, 51, 1213-1217
28. Aseyev, V.; Tenhu, H.; Winnik, F. M. Non-ionic thermoresponsive polymers in water Adv. Polym. Sci. 2011, 242, 29-89
29. Schild, H. G.; Tirrell, D. A. Microcalorimetric detection of lower critical solution temperatures in aqueous polymer solutions J. Phys. Chem. 1990, 94, 4352-6
30. Hofmann, C.; Schönhoff, M. Do additives shift the LCST of poly (N-isopropylacrylamide) by solvent quality changes or by direct interactions? Colloid Polym. Sci. 2009, 287, 1369-1376
31. Hofmann, C. H.; Schönhoff, M. Dynamics and distribution of aromatic model drugs in the phase transition of thermoreversible poly(N- isopropylacrylamide) in solution Colloid Polym. Sci. 2012, 290, 689-698
32. Flint, N. J.; Gardebrecht, S.; Swanson, L. Fluorescence investigations of smart microgel systems J. Fluoresc. 1998, 8, 343-353
33. Virtanen, J.; Lemmetyinen, H.; Tenhu, H. Fluorescence and EPR studies on the collapse of poly(N-isopropyl acrylamide)-g-poly(ethylene oxide) in water Polymer 2001, 42, 9487-9493
34. Niskanen, J.; Wu, C.; Ostrowski, M.; Fuller, G. G.; Tenhu, H.; Hietala, S. Interfacial and fluorescence studies on stereoblock poly(N-isopropylacryl amide)s Langmuir 2012, 28, 14792-14798
35. Kujawa, P.; Aseyev, V.; Tenhu, H.; Winnik, F. M. Temperature-sensitive properties of poly(N-isopropylacrylamide) mesoglobules formed in dilute aqueous solutions heated above their demixing point Macromolecules 2006, 39, 7686-7693
36. Pelton, R. Poly(N-isopropylacrylamide) (PNIPAM) is never hydrophobic J. Colloid Interface Sci. 2010, 348, 673-674
37. Virtanen, J.; Holappa, S.; Lemmetyinen, H.; Tenhu, H. Aggregation in aqueous poly(N-isopropylacrylamide)-block-poly(ethylene oxide) solutions studied by fluorescence spectroscopy and light scattering Macromolecules 2002, 35, 4763-4769
38. Bondarev, S. L.; Knyukshto, V. N.; Stepuro, V. I.; Stupak, A. P.; Turban, A. A. Fluorescence and electronic structure of the laser dye DCM in solutions and in polymethylmethacrylate J. Appl. Spectrosc. 2004, 71, 194-201
39. Plamper, F. A.; McKee, J. R.; Laukkanen, A.; Nykänen, A.; Walther, A.; Ruokolainen, J.; Aseyev, V.; Tenhu, H. Miktoarm stars of poly(ethylene oxide) and poly(dimethylaminoethyl methacrylate): manipulation of micellization by temperature and light Soft Matter 2009, 5, 1812-1821
40. Steinschulte, A. A.; Schulte, B.; Erberich, M.; Borisov, O. V.; Plamper, F. A. Unimolecular Janus micelles by microenvironment-induced, internal complexation ACS Macro Lett. 2012, 1, 504-507
41. Diaz-Fernandez, Y.; Foti, F.; Mangano, C.; Pallavicini, P.; Patroni, S.; Perez-Gramatges, A.; Rodriguez-Calvo, S. Micelles for the self-assembly of off-on-off fluorescent sensors for pH windows Chem. - Eur. J. 2006, 12, 921-930
42. Jin, N.; Morin, E. A.; Henn, D. M.; Cao, Y.; Woodcock, J. W.; Tang, S.; He, W.; Zhao, B. Agarose hydrogels embedded with pH-responsive diblock copolymer micelles for triggered release of substances Biomacromolecules 2013, 14, 2713-2723
43. Niskanen, J.; Karesoja, M.; Rossi, T.; Tenhu, H. Temperature and pH responsive hybrid nanoclay grafted with PDMAEMA Polym. Chem. 2011, 2, 2027-2036
44. Takagishi, T.; Hosokawa, T.; Hatanaka, Y. Binding methyl orange and hydrophobic fluorescent probes by poly(2-dimethylaminoethyl methacrylate) and copolymers of 2-dimethylaminoethyl methacrylate and N-vinyl-2-pyrrolidone: pH dependence of the binding and fluorescence intensity J. Polym. Sci., Part A: Polym. Chem. 1989, 27, 1-13
45. Housni, A.; Zhao, Y. Gold nanoparticles functionalized with block copolymers displaying either LCST or UCST thermosensitivity in aqueous solution Langmuir 2010, 26, 12933-12939
46. Steinschulte, A. A.; Schulte, B.; Rütten, S.; Eckert, T.; Okuda, J.; Möller, M.; Schneider, S.; Borisov, O. V.; Plamper, F. A. Effects of architecture on the stability of thermosensitive unimolecular micelles Phys. Chem. Chem. Phys. 2014, 16, 4917-4932
47. Braunecker, W. A.; Matyjaszewski, K. Controlled/living radical polymerization: Features, developments, and perspectives Prog. Polym. Sci. 2007, 32, 93-146
48. 3 miktoarm stars using a combined arm-first and core-first approach Polym. Chem. 2013, 4, 3885-3895
49. Küster, F. W.; Thiel, A.; Ruland, A.; Ruland, U. Rechentafeln für die Chemische Analytik, Basiswissen für die Analytische Chemie, 107 th ed.; De Gruyter: Berlin, Boston, 2011.
50. 2+-induced intermediate necklace structures of polyacrylate chains Macromolecules 2009, 42, 4288-4299
51. Ma, Y.; Tang, Y.; Billingham, N. C.; Armes, S. P.; Lewis, A. L.; Lloyd, A. W.; Salvage, J. P. Well-defined biocompatible block copolymers via atom transfer radical polymerization of 2-methacryloyloxyethyl phosphorylcholine in protic media Macromolecules 2003, 36, 3475-3484
52. Tanaka, T.; Fillmore, D.; Sun, S.-T.; Nishio, I.; Swislow, G.; Shah, A. Phase transitions in ionic gels Phys. Rev. Lett. 1980, 45, 1636-9
53. Shibayama, M.; Tanaka, T. Responsive Gels: Vol. Transitions I; Springer: Berlin, Heidelberg, 1993; Vol. 109, pp 1-62.
54. Polotsky, A. A.; Plamper, F. A.; Borisov, O. V. Collapse-to-swelling transitions in pH- and thermoresponsive microgels in aqueous dispersions: The thermodynamic theory Macromolecules 2013, 46, 8702-8709
55. Hofmann, C. H.; Plamper, F. A.; Scherzinger, C.; Hietala, S.; Richtering, W. Cononsolvency revisited: Solvent entrapment by N-isopropylacrylamide and N,N-diethylacrylamide microgels in different water/methanol mixtures Macromolecules 2013, 46, 523-532
56. Grobelny, S.; Hofmann, C. H.; Erlkamp, M.; Plamper, F. A.; Richtering, W.; Winter, R. Conformational changes upon high pressure induced hydration of poly(N-isopropylacrylamide) microgels Soft Matter 2013, 9, 5862-5866
57. Plamper, F. A.; Steinschulte, A. A.; Hofmann, C. H.; Drude, N.; Mergel, O.; Herbert, C.; Erberich, M.; Schulte, B.; Winter, R.; Richtering, W. Toward copolymers with ideal thermosensitivity: Solution properties of linear, well-defined polymers of N-isopropyl acrylamide and N,N-diethyl acrylamide Macromolecules 2012, 45, 8021-8026
58. Chodanowski, P.; Stoll, S. Monte Carlo simulations of hydrophobic polyelectrolytes: Evidence of complex configurational transitions J. Chem. Phys. 1999, 111, 6069-6081
59. Limbach, H. J.; Holm, C. Single-chain properties of polyelectrolytes in poor solvent J. Phys. Chem. B 2003, 107, 8041-8055
60. Aseyev, V. O.; Klenin, S. I.; Tenhu, H. Conformational changes of a polyelectrolyte in mixtures of water and acetone J. Polym. Sci., Part B: Polym. Phys. 1998, 36, 1107-1114
61. Aseyev, V. O.; Klenin, S. I.; Tenhu, H.; Grillo, I.; Geissler, E. Neutron scattering studies of the structure of a polyelectrolyte globule in a water-acetone mixture Macromolecules 2001, 34, 3706-3709
62. Kosovan, P.; Kuldova, J.; Limpouchova, Z.; Prochazka, K.; Zhulina, E. B.; Borisov, O. V. Molecular dynamics simulations of a polyelectrolyte star in poor solvent Soft Matter 2010, 6, 1872-1874
63. Plamper, F. A.; Reinicke, S.; Elomaa, M.; Schmalz, H.; Tenhu, H. Pearl necklace architecture: New threaded star-shaped copolymers Macromolecules 2010, 43, 2190-2203
64. Bokias, G.; Vasilevskaya, V. V.; Iliopoulos, I.; Hourdet, D.; Khokhlov, A. R. Influence of migrating ionic groups on the solubility of polyelectrolytes: Phase behavior of ionic poly(N-isopropylacrylamide) copolymers in water Macromolecules 2000, 33, 9757-9763
65. Pearson, R. T.; Warren, N. J.; Lewis, A. L.; Armes, S. P.; Battaglia, G. Effect of pH and temperature on PMPC-PDPA copolymer self-assembly Macromolecules 2013, 46, 1400-1407
66. Wieland, G.; Simchen, G. Synthese und Eigenschaften sterisch gehinderter tertiärer Amine und Guanidine Liebigs Ann. Chem. 1985, 1985, 2178-2193