Evaluate impact of catalyst type on oil yield and hydrogen consumption from mild hydrotreating

Energy and Fuels

Volumn 28, Issue 5, 2014, Pages 3086-3095

  French, Richard J ^a   Stunkel, James ^a   Black, Stuart ^a   Myers, Michele ^a   Yung, Matthew M ^a   Iisa, Kristiina ^a  

^a NATIONAL RENEWABLE ENERGY LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BATCH REACTORS; BIOFUELS; BIOMASS; CARBON; CATALYSTS; FUNCTIONAL GROUPS; NICKEL;

BIOMASS PYROLYSIS OIL; CARBON CONVERSIONS; EFFECT OF CATALYST; HYDROCARBON TRANSPORTATION; HYDRODEOXYGENATION; HYDROGEN CONSUMPTION; OXYGEN FUNCTIONAL GROUPS; PRECIOUS-METAL CATALYSTS;

OXYGEN;

EID: 84900549124     PISSN: 08870624     EISSN: 15205029     Source Type: Journal    
DOI: 10.1021/ef4019349     Document Type: Article

References (29)

1. U.S. Department of Energy, Biomass Multi-Year Program Plan 2011, Office of the Biomass Program, Energy Efficiency and Renewable Energy. Available at http://www1.eere.energy.gov/biomass/pdfs/mypp-april-2011.pdf (accessed April 6, 2014).
2. Beaudry-Losique, J. Growing a Robust Biofuels Economy, Venture Capital Forum. August 21-22, 2007. Available at http://www1.eere.energy.gov/ commercialization/pdfs/biomass.pdf (accessed April 6, 2014).
3. U.S. Department of Energy. U.S. Billion-Ton Update: Biomass Supply for a Bioenergy and Bioproducts Industry. Perlack, R. D.; Stokes, B. J. (Leads), ORNL/TM-2011/224; Oak Ridge National Laboratory: Oak Ridge, TN, 2011; 227p. Available at http://bioenergykdf.net (accessed April 6, 2014).
4. U.S. Environmental Protection Agency, EPA Proposes New Regulations for the National Renewable Fuel Standard Program for 2010 and Beyond 2009. Available at http://www.epa.gov/otaq/renewablefuels/rfs2-1-5.pdf (accessed April 6, 2014).
5. Czernik, S.; Bridgwater, A. V. Overview of Applications of Biomass Fast Pyrolysis Oil Energy Fuels 2004, 18, 590-598
6. Elliott, D. C.; Baker, E. G. Catalytic Hydrotreating of Biomass Liquefaction Products to Produce Hydrocarbon Fuels: Interim Report; Pacific Northwest National Laboratory: Richland, WA, 1986.
7. Elliott, D. C. Historical Developments in Hydroprocessing Bio-Oils Energy Fuels 2007, 21, 1792-1815
8. Conti, L.; Scano, G.; Boufala, J.; Mascia, S. Experiments of Bio-Oil Hydrotreating in a Continuous Bench-Scale Plant. Bio-Oil Prod. Util., Proc. EU-Can. Workshop Therm. Biomass Process 1996; pp 198-205.
9. Baker, E. G.; Elliott, D. C. Catalytic Upgrading of Biomass Pyrolysis Oils. In Research in Thermochemical Biomass Conversion; Bridgwater, A. V.; Kuester, J. L., Eds.; Elsevier Science Publishers, Ltd.: Barking, England, 1988; pp 883-895.
10. Baker, E. G.; Elliott, D. C. Method of Upgrading Oils Containing Hydroxyaromatic Hydrocarbon Compounds to Highly Aromatic Gasoline. US Patent 5,180,868, 1993.
11. Jones, S.; Valkenburg, C.; Walton, C.; Elliott, D.; Holladay, J.; Stevens, D.; Kinchin, C.; Czernik, S. Production of Gasoline and Diesel from Biomass via Fast Pyrolysis, Hydrotreating and Hydrocracking: A Design Case; Report PNNL-18284 Rev. 1; Pacific Northwest National Lab: Richland, WA, 2009.
12. Baldauf, W.; Balfanz, U. Upgrading of Fast Pyrolysis Liquids at Veba Oel AG Biomass Gasif. Pyrolysis 1997, 392-398
13. Marker, T. L. Opportunities for Biorenewables in Oil Refineries; Final Technical Report 2005; DOE Contract number DE-FG36-05GO15085.
14. Fu, X.; Dai, Z.; Tian, S.; Long, J.; Hou, S.; Wang, X. Catalytic Decarboxylation of Petroleum Acids from High Acid Crude Oils over Solid Acid Catalysts Energy Fuels 2008, 22, 1923-1929
15. Wang, H.; Male, J.; Wang, Y. Recent Advances in Hydrotreating of Pyrolysis Bio-Oil and Its Oxygen-Containing Model Compounds ACS Catal. 2013, 3, 1047-1070
16. Elliott, D. C.; Hart, T. R. Catalytic Hydroprocessing of Chemical Models for Bio-Oil Energy Fuels 2009, 23, 631-637
17. Elliott, D. C.; Hart, T. R.; Neuenschwander, G. G.; Rotness, L. J.; Zacher, A. H. Catalytic Hydroprocessing of Biomass Fast Pyrolysis Bio-Oil To Produce Hydrocarbon Products Environ. Prog. Sustainable Energy 2009, 28, 441-449
18. Wildschut, J.; Mahfud, F. H.; Venderbosch, R. H.; Heeres, H. J. Hydrotreatment of Fast Pyrolysis Oil Using Heterogeneous Noble-Metal Catalysts Ind. Eng. Chem. Res. 2009, 48, 10324-10334
19. Wildschut, J.; Iqbal, M.; Mahfud, F. H.; Cabrera, I. M.; Venderbosch, R. H.; Heeres, H. J. Insights in the Hydrotreatment of Fast Pyrolysis Oil Using a Ruthenium on Carbon Catalyst Energy Environ. Sci. 2010, 3, 962-970
20. de Miguel Mercader, F. Pyrolysis Oil Upgrading for Co-Processing in Standard Refinery Units, Ph.D. Thesis, University of Twente, 2010.
21. Ardiyanti, A. R.; Gutierrez, A.; Honkela, M. L.; Krause, A. O. I.; Heeres, H. J. Hydrotreatment of Wood-Based Pyrolysis Oil Using Zirconia-Supported Mono- and Bimetallic (Pt, Pd, Rh) Catalysts Appl. Catal., A 2011, 407, 56-66
22. Lin, Y.-C.; Li, C.-L.; Wan, H.-P.; Lee, H.-T.; Liu, C.-F. Catalytic Hydrodeoxygenation of Guaiacol on Rh-Based and Sulfided CoMo and NiMo Catalysts Energy Fuels 2011, 25, 890-896
23. Nicolaides, G. M. The Chemical Characterization of Pyrolytic Oils; University of Waterloo, Department of Chemical Engineering: Waterloo, Ontario, 1984; pp 17-26, 30-42.
24. French, R. J.; Stunkel, J.; Baldwin, R. M. Mild Hydrotreating of Bio-Oil: Effect of Reaction Severity and Fate of Oxygenated Species Energy Fuels 2011, 25, 3266-3274
25. Ben, H.; Ragauskas, A. J. NMR Characterization of Pyrolysis Oils from Kraft Lignin Energy Fuels 2011, 25, 2322-2332
26. Wildschut, J.; Arentz, J.; Rasrendra, C. B.; Venderbosch, R. H.; Heeres, H. J. Catalytic Hydrotreatment of Fast Pyrolysis Oil: Model Studies on Reaction Pathways for the Carbohydrate Fraction Environ. Prog. Sustainable Energy 2009, 28 (3) 450-460
27. Olcay, H.; Xu, L. J.; Xu, Y.; Huber, G. W. Aqueous-Phase Hydrogenation of Acetic Acid over Transition Metal Catalysts. ChemCatChem 2010, 2 (11) 1420-1424
28. 2 Catalysts Appl. Catal., A 2012, 411, 95-104
29. Ruddy, D. A.; Schaidle, J. A.; Ferrell, J. R., III; Wang, J.; Moens, L.; Hensley, J. E. Recent Advances in Heterogeneous Catalysts for Bio-Oil Upgrading via " ex Situ Catalytic Pyrolysis": Catalyst Development through the Study of Model Compounds Green Chem. 2014, 10.1039/c3gc41354c