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Volumn 5, Issue 6, 2014, Pages 2170-2176

The ON/OFF switching by metal ions of the "sergeants and Soldiers" chiral amplification effect on helical poly(phenylacetylene)s

Author keywords

[No Author keywords available]

Indexed keywords

AMPLIFICATION; METAL COMPLEXES; METAL IONS;

EID: 84900340047     PISSN: 20416520     EISSN: 20416539     Source Type: Journal    
DOI: 10.1039/c3sc53330a     Document Type: Article
Times cited : (70)

References (39)
  • 35
    • 84948391271 scopus 로고
    • No time-dependent changes in the CD signals of the copolymers were observed at the concentrations used in the studies. Only when much larger concentrations of metal were used, the CD response diminished due to aggregation phenomena. Also, no noticeable changes were observed at different temperatures ranging from 10 to 40 °C. In relation to the influence of the solvent media, the sense of chiral amplification induced by barium and lithium is independent of the solvent used (see ref. 4a)
    • T. Kelen F. Tüdös J. Macromol. Sci., Chem. 1975 9 1
    • (1975) J. Macromol. Sci., Chem. , vol.9 , pp. 1
    • Kelen, T.1    Tüdös, F.2
  • 37
    • 35048837491 scopus 로고    scopus 로고
    • DSC traces indicate that backbones of the copolymers and their complexes with barium adopt in all cases a cis-cisoidal configuration. Full description of thermal studies (DSC and TGA) at ESI. For related studies, see
    • S. -I. Sakurai S. Ohsawa K. Nagai K. Okoshi J. Kumaki E. Yashima Angew. Chem., Int. Ed. 2007 46 7605
    • (2007) Angew. Chem., Int. Ed. , vol.46 , pp. 7605
    • Sakurai, S.-I.1    Ohsawa, S.2    Nagai, K.3    Okoshi, K.4    Kumaki, J.5    Yashima, E.6


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.