Characterization of the dehydrogenation process of LiBH4 confined in nanoporous carbon

Journal of Physical Chemistry C

Volumn 118, Issue 17, 2014, Pages 8843-8851

  House, Stephen D ^a   Liu, Xiangfeng ^b   Rockett, Angus A ^a   Majzoub, Eric H ^c   Robertson, Ian M ^d  

^a United States of America   (United States)

^b UNIVERSITY OF CHINESE ACADEMY OF SCIENCES   (China)

^c UNIVERSITY OF MISSOURI ST LOUIS   (United States)

^d Wisconsin Electric Machines and Power Electronics Consortium   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

DIFFERENTIAL SCANNING CALORIMETRY; HYDROGEN STORAGE; SCAFFOLDS; TRANSMISSION ELECTRON MICROSCOPY;

CARBON SUPPORT FILMS; DIFFERENTIAL SCANNING CALORIMETERS; HYDROGEN STORAGE CAPACITIES; NANOPOROUS CARBONS; NUMBER OF CYCLES; OUTER SURFACE; PREFERENTIAL SEGREGATION;

DEHYDROGENATION;

EID: 84899814780     PISSN: 19327447     EISSN: 19327455     Source Type: Journal    
DOI: 10.1021/jp4098205     Document Type: Article

References (36)

1. Züttel, A.; Remhof, A.; Borgschulte, A.; Friedrichs, O. Hydrogen: The Future Energy Carrier Philos. Trans. R. Soc. A: Math., Phys. Eng. Sci. 2010, 368 (1923) 3329-3342
2. Grochala, W.; Edwards, P. P. Thermal Decomposition of the Non-Interstitial Hydrides for the Storage and Production of Hydrogen Chem. Rev. 2004, 104 (3) 1283-1316
3. Yang, J.; Sudik, A.; Wolverton, C.; Siegel, D. J. High Capacity Hydrogen Storage Materials: Attributes for Automotive Applications and Techniques for Materials Discovery Chem. Soc. Rev. 2010, 39 (2) 656-675
4. Sakintuna, B.; Lamari-Darkrim, F.; Hirscher, M. Metal Hydride Materials for Solid Hydrogen Storage: A Review Int. J. Hydrogen Energy 2007, 32 (9) 1121-1140
5. Orimo, S.-i.; Nakamori, Y.; Eliseo, J. R.; Züttel, A.; Jensen, C. M. Complex Hydrides for Hydrogen Storage Chem. Rev. 2007, 107 (10) 4111-4132
6. Graetz, J. New Approaches to Hydrogen Storage Chem. Soc. Rev. 2009, 38 (1) 73-82
7. Mandal, T. K.; Gregory, D. H. Hydrogen Storage Materials: Present Scenarios and Future Directions Annu. Rep. Sect. A (Inorg. Chem.) 2009, 105 (0) 21-54
8. Vajo, J. J.; Olson, G. L. Hydrogen Storage in Destabilized Chemical Systems Scripta Mater. 2007, 56 (10) 829-834
9. Alapati, S. V.; Johnson, J. K.; Sholl, D. S. Large-Scale Screening of Metal Hydride Mixtures for High-Capacity Hydrogen Storage from First-Principles Calculations J. Phys. Chem. C 2008, 112 (14) 5258-5262
10. Ozolins, V.; Majzoub, E. H.; Wolverton, C. First-Principles Prediction of Thermodynamically Reversible Hydrogen Storage Reactions in the Li-Mg-Ca-B-H System J. Am. Chem. Soc. 2008, 131 (1) 230-237
11. Fichtner, M. Properties of Nanoscale Metal Hydrides Nanotechnology 2009, 20 (20) 204009
12. Wagemans, R. W. P.; van Lenthe, J. H.; de Jongh, P. E.; van Dillen, A. J.; de Jong, K. P. Hydrogen Storage in Magnesium Clusters: Quantum Chemical Study J. Am. Chem. Soc. 2005, 127 (47) 16675-16680
13. 4 Supported on Carbon Nanofibers Angew. Chem., Int. Ed. 2006, 45 (21) 3501-3503
14. 4 ChemPhysChem 2010, 11 (4) 789-792
15. 2 Release, Reversibility, and Thermodynamics J. Phys. Chem. C 2010, 114 (10) 4675-4682
16. Vajo, J. J. Influence of Nano-Confinement on the Thermodynamics and Dehydrogenation Kinetics of Metal Hydrides Curr. Opin. Solid State Mater. Sci. 2011, 15 (2) 52-61
17. 4 J. Alloys Compd. 2005, 404, 427-430
18. - Complexes During Hydrogen Desorption from Metal Borohydrides J. Phys. Chem. C 2008, 112 (9) 3164-3169
19. 4/Silica-Gel Mixtures and the Effect of Additives J. Phys. Chem. C 2007, 111 (37) 14026-14029
20. Au, M.; Jurgensen, A. R.; Spencer, W. A.; Anton, D. L.; Pinkerton, F. E.; Hwang, S.-J.; Kim, C.; Bowman, R. C. Stability and Reversibility of Lithium Borohydrides Doped by Metal Halides and Hydrides J. Phys. Chem. C 2008, 112 (47) 18661-18671
21. 4 J. Phys. Chem. B 2005, 109 (9) 3719-3722
22. 2) J. Phys. Chem. C 2007, 111 (51) 19134-19140
23. 4: A Synergetic Effect of Nanoconfinement and Ni Addition Chem. Commun. 2010, 46 (43) 8201-8203
24. Zhang, Y.; Zhang, W.-S.; Wang, A.-Q.; Li-Xian, S.; Fan, M.-Q.; Chu, H.-L.; Sun, J.-C.; Zhang, T. Nanoparticles Supported by Disordered Mesoporous Carbon: Hydrogen Storage Performances and Destabilization Mechanisms Int. J. Hydrogen Energy 2007, 32 (16) 3976-3980
25. Vajo, J.; Salguero, T.; Gross, A.; Skeith, S.; Olson, G. Thermodynamic Destabilization and Reaction Kinetics in Light Metal Hydride Systems J. Alloys Compd. 2007, 446-447, 409-414
26. 4 in Nanoporous Carbon Scaffolds J. Phys. Chem. C 2008, 112 (14) 5651-5657
27. 4 Hydrogen Desorption by Inclusion into Mesoporous Carbons J. Power Sources 2009, 189 (2) 902-908
28. Nielsen, T. K.; Bösenberg, U.; Gosalawit, R.; Dornheim, M.; Cerenius, Y.; Besenbacher, F.; Jensen, T. R. A Reversible Nanoconfined Chemical Reaction ACS Nano 2010, 4 (7) 3903-3908
29. 4 Via Confinement in Highly Ordered Nanoporous Carbon J. Phys. Chem. C 2010, 114 (33) 14036-14041
30. 4: Elimination of Diborane Release and Tunable Behavior for Hydrogen Storage Applications Chem. Mater. 2011, 23 (Compendex) 1331-1336
31. Meng, Y.; Gu, D.; Zhang, F.; Shi, Y.; Cheng, L.; Feng, D.; Wu, Z.; Chen, Z.; Wan, Y.; Stein, A.; Zhao, D. A Family of Highly Ordered Mesoporous Polymer Resin and Carbon Structures from Organic-Organic Self-Assembly Chem. Mater. 2006, 18 (18) 4447-4464
32. Mitchell, D. R. G. Circular Hough Transform Diffraction Analysis: A Software Tool for Automated Measurement of Selected Area Electron Diffraction Patterns within Digital Micrograph Ultramicroscopy 2008, 108 (4) 367-374
33. Rasband, W. S. Imagej; U. S. National Institutes of Health: Bethesda, MD, 1997-2012.
34. 2 Sorption in Nanoconfined Complex Metal Hydrides by Alkali Metal Addition J. Mater. Chem. 2012, 22 (26) 13209-13215
35. 4: Determination of Distinct Prolific Effects from Pore Size, Crystallite Size, and Surface Interactions J. Phys. Chem. C 2012, 116 (39) 21046-21051
36. Mason, T.; Majzoub, E. H. Effects of a Carbon Surface Environment on the Hydrogen Storage Properties of Nanoclusters. Manuscript in preparation.