Predicting the integral heat of adsorption for gas physisorption on microporous and mesoporous adsorbents

Journal of Physical Chemistry C

Volumn 118, Issue 16, 2014, Pages 8350-8358

  Whittaker, Peter B ^a   Wang, Xiaolin ^b   Zimmermann, Wolfgang ^c   Regenauer Lieb, Klaus ^a   Chua, Hui Tong ^a  

^a UNIVERSITY OF WESTERN AUSTRALIA   (Australia)

^b UNIVERSITY OF TASMANIA   (Australia)

^c SPG Steiner GmbH   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATED CARBON; ISOTHERMS; SILICA GEL;

CLAPEYRON EQUATIONS; CLAUSIUS-CLAPEYRON EQUATIONS; HEAT OF ADSORPTION; HEATS OF ADSORPTION; ISOTHERM MODELS; MESOPOROUS ADSORBENTS; POTENTIAL FUNCTION; PREDICTIVE METHODS;

PHYSISORPTION;

EID: 84899582245     PISSN: 19327447     EISSN: 19327455     Source Type: Journal    
DOI: 10.1021/jp410873v     Document Type: Article

References (30)

1. Siperstein, F.; Gorte, R. J.; Myers, A. L. A New Calorimeter for Simultaneous Measurements of Loading and Heats of Adsorption from Gaseous Mixtures Langmuir 1999, 15, 1570-1576
2. Zimmermann, W.; Keller, J. U. A New Calorimeter for Simultaneous Measurement of Isotherms and Heats of Adsorption Thermochim. Acta 2003, 405, 31-41
3. 6 on Silicalite Langmuir 1996, 12, 5888-5895
4. Chua, H. T.; Ng, K. C.; Malek, A.; Kashiwagi, T.; Akisawa, A.; Saha, B. B. Modeling the Performance of Two-Bed, Silica Gel-Water Adsorption Chillers Int. J. Refrig. 1999, 22, 194-204
5. Wang, X.; Chua, H. T. Two Bed Silica Gel-Water Adsorption Chillers: An Effectual Lumped Parameter Model Int. J. Refrig. 2007, 30, 1417-1426
6. Sáez, A.; Toledo, M. Thermal Effect of the Adsorption Heat on an Adsorbed Natural Gas Storage and Transprotation Systems Appl. Therm. Eng. 2009, 29, 2617-2623
7. Rezaei, F.; Webley, P. Structured Adsorbents in Gas Separation Processes Sep. Purif. Technol. 2010, 70, 243-256
8. Dutta, B. K. Principals of Mass Transfer and Separation Processes; Prentice-Hall of India Private Limited: New Delhi, India, 2007.
9. Shen, D.; Bülow, M.; Siperstein, F.; Engelhard, M.; Myers, A. L. Comparison of Experimental Techniques for Measuring Isosteric Heat of Adsorption Adsorption 2000, 6, 275-286
10. Akkimaradi, B. S.; Prasar, M.; Dutta, P.; Saha, B. B.; Srinivasan, K. Adsorption of Nitrogen on Activated Carbon-Refit of Experimental Data and Derivation of Properties Required for Design of Equipment J. Chem. Eng. Data 2009, 54, 2291-2295
11. El-Sharkawy, I. I.; Saha, B. B.; Koyama, S.; Srinivasan, K. Isosteric Heats of Adsorption Extracted from Experiments of Ethanol and HFC 134a on Carbon Based Adsorbents Int. J. Heat Mass Transfer 2007, 50, 902-907
12. Pinto, M. L.; Pires, J.; Carvalho, A. P.; Carvalho, M. B. On the Difficulties of Predicting the Adsorption of Volatile Organic Compounds at Low Pressures in Microporous Solid: The Example of Ethyl Benzene J. Phys. Chem. B. 2006, 110, 250-257
13. Pan, H.; Ritter, J. A.; Balbuena, P. B. Examination of the Approximatations Used in Determining the Isosteric Heats of Adsorption from the Clausius-Clapeyron Equation Langmuir 1998, 14, 6323-6327
14. Ritter, J. A.; Kapoor, A.; Yang, R. T. Localized Adsorption with Lateral Interaction on Random and Patchwise Heterogeneous Surfaces J. Phys. Chem. 1990, 94, 6785-6791
15. Boddenberg, B.; Rakhmatkariev, G. U.; Greth, R. Statistical Thermodynamics of Methanol and Ethanol Adsorption in Zeolite NaZSM5 J. Phys. Chem. B 1997, 101, 1634-1640
16. Ramirez-Pastor, A. J.; Pereyra, V. D.; Riccardo, J. L. Statistical Thermodynamics of Linear Adsorbates in Low Dimensions: Application to Adsorption on Heterogeneous Surfaces Langmuir 1999, 15, 5707-5712
17. Dhar, H. P.; Conway, B. E.; Joshi, K. M. On the Form of Adsorption Isotherms for Substitutional Adsorption of Molecules of Different Sizes Electrochim. Acta 1973, 18, 789-798
18. Savara, A.; Schmidt, C. M.; Geiger, F. M.; Weitz, E. Adsorption Entropies and Enthalpies and Their Implications for Adsorbate Dynamics J. Phys. Chem. C 2009, 113, 2806-2815
19. Whittaker, P. B.; Wang, X.; Regenauer-Lieb, K.; Chua, H. T. Predicting Isosteric Heats for Gas Adsorption Phys. Chem. Chem. Phys. 2013, 15, 473-482
20. Dubinin, M. M.; Astakhov, V. A. Development of the Concepts of Volume Filling of Micropores in the Adsorption of Gases and Vapors by Microporous Adsorbents Bull Acad. Sci. U.S.S.R. 1971, 20, 3-7
21. Dubinin, M. M. Physical Adsorption of Gases and Vapors in Micropores. Chapter in Progress in Surface and Membrane Science Vol. 9; Academic Press: New York, NY, USA, 1975.
22. Ozawa, S.; Kusumi, S.; Ogino, Y. Physical Adsorption of Gases at High Pressure IV. An Improvement of the Dubinin-Astakhov Adsorption Equation J. Colloid Interface Sci. 1976, 56, 83-91
23. Saha, B. B.; Koyama, S.; El-Sharkawy, I. I.; Habib, K.; Srinivasan, K.; Dutta, P. Evaluation of Adsorption Parameters and Heats of Adsorption Through Desorption Measurements J. Chem. Eng. Data 2007, 52, 2419-2424
24. Wang, X.; French, J.; Srinivasan, K.; Chua, H. T. Adsorption Measurements of Methane on Activated Carbon in the Temperature Range (281 to 343) K and Pressures to 1.2 MPa J. Chem. Eng. Data 2010, 55, 2700-2706
25. Saha, B. B.; Chakraborty, A.; Koyama, S.; Yoon, S.; Mochida, I.; Kumja, M.; Yap, C.; Ng, K. C. Isotherms and Thermodynamics for the Adsorption of n -Butane on Pitch Based Activated Carbon Int. J. Heat Mass Transfer 2008, 51, 1582-1589
26. Hill, T. L. Statistical Mechanics of Adsorption. V. Thermodynamics and Heat of Adsorption J. Chem. Phys. 1949, 17, 520-535
27. Wilhelm, M.; Soltman, C.; Koch, D.; Grathwohl, G. Ceramers-Functional Materials for Adsorption Techniques J. Eur. Ceram. Soc. 2005, 25, 271-276
28. Chua, H. T.; Ng, K. C.; Chakraborty, A.; Oo, N. M.; Othman, M. A. Adsorption Characteristics of Silica Gel + Water Systems J. Chem. Eng. Data 2002, 47, 1177-1181
29. Robens, E.; Keller, J. U.; Massen, C. H.; Staudt, R. Sources of Error in Sorption and Density Measurements J. Therm. Anal. Calorim. 1999, 55, 383-387
30. Tóth, J. Gas-(Dampf-) Adsorption An Festen Oberflächen Inhomogener Aktivität, I Acta Chim. Acad. Sci. Hung. 1962, 30, 415-430