Carbon storage by mineralisation (CSM): Serpentinite rock carbonation via Mg(OH)2 reaction intermediate without CO2 pre-separation

Energy Procedia

Volumn 37, Issue , 2013, Pages 5945-5954

  Zevenhoven, Ron ^a   Fagerlund, Johan ^a   Nduagu, Experience ^c   Romão, Inês ^a   Jie, Bu ^b   Highfield, James ^b  

^a ÅBO AKADEMI UNIVERSITY   (Finland)

^b INSTITUTE OF CHEMICAL AND ENGINEERING SCIENCES   (Singapore)

^c CITEC Oy Ab   (Finland)

Author keywords

Operation on flue gas; Serpentinite

Indexed keywords

EID: 84898743753     PISSN: 18766102     EISSN: None     Source Type: Conference Proceeding    
DOI: 10.1016/j.egypro.2013.06.521     Document Type: Conference Paper

References (26)

1. Zevenhoven, R, Fagerlund, J, Songok, JK, CO2 mineral sequestration - developments towards large-scale application. Greenhouse Gases: Science and Technology 2011;1:48-57. doi: 10.1002/ghg3.
2. Khoo, HH, Sharatt, PN, Bu, J, Borgna, A, Yeo, TY, Highfield, J, Björklöf, TG, Zevenhoven, R Carbon capture and mineralization in Singapore: preliminary environmental iMPacts and costs via LCA. Ind. & Eng. Chem. Res. 2011;50:11350-11357 doi:10.1021/ie200592h.
3. Fagerlund, J, Teir, S, Nduagu, E, Zevenhoven, R. Carbonation of magnesium silicate mineral using a pressurized gas/solid process. (GHGT-9) Energia Procedia 2009;1: 4907-4914. doi: 10.1016/j.egypro.2009.02.321.
4. 2 using a pressurized fluidized bed. (GHGT-10) Energia Procedia 2011;4:4993-4999. doi: 10.1016/j.egypro.2011.02.470.
5. Stasiulaitiene, I., Fagerlund, J, Nduagu, E, Denafas, G, Zevenhoven, R. Carbonation of serpentinite rock from Lithuania and Finland. (GHGT-10) Energia Procedia 2011;4: 2963-2970 doi: 10.1016/j.egypro.2011.02.205.
6. Nduagu E, Björklöf, T, Fagerlund, J, Wärnå, J, Geerlings, H, Zevenhoven, R Production of reactive magnesium from magnesium silicate for the purpose of CO2 mineralization. Part 1. Application to Finnish serpentinite. Miner. Engng. 2012;30:75-86. doi:10.1016/j.mineng.2011.12.004.
7. Nduagu, E, Björklöf, T, Fagerlund, J, Mäkelä, E, Salonen, J, Geerlings, H, Zevenhoven, R. Production of reactive magnesium from magnesium silicate for the purpose of CO2 mineralization. Part 2. Mg extraction modeling and application to different Mg silicate rocks Miner. Engng. 2012;30:87-94. doi:10.1016/j.mineng.2011.12.002.
8. Highfield, JG, Lim, HQ, Fagerlund, J, Zevenhoven, R. Activation of serpentine for CO2 mineralization by flux extraction of soluble magnesium salts using ammonium sulphate. RSC Advances 2012;2: 6535-6541. doi: 10.1039/c2ra01347a.
9. Nduagu E. The production of Mg(OH)2 from Mg-silicate rock for CO2 mineral sequestration. PhD thesis Åbo Akademi University, Turku Finland. (2012) under review for forthcoming public defence.
10. Nduagu E, Fagerlund, J, Zevenhoven, R. Contribution of iron to the energetics of CO2 sequestration in Mg-silicates-based rock. Energy Conv. & Manage. 2012; 55: 178-186. doi:10.1016/j.enconman.2011.10.023.
11. Nduagu, E, Romão, I, Fagerlund, J, Zevenhoven, R. Performance assessment of producing Mg(OH)2 for CO2 mineral sequestration. Applied Energy (2012) submitted.
12. Zevenhoven, R, Fagerlund, J, Björklöf, T, Mäkelä, M, Eklund, O. Carbon dioxide mineralisation and integration with flue gas desulphurisation applied to a modern coal-fired power plant. Proceedings of ECOS2012, Perugia, Italy, June 2012 - paper 179.
13. Björklöf, TG, An energy efficiency study of carbon dioxide mineralization. MSc thesis Åbo Akademi University, Turku Finland. (2010).
14. Fagerlund, J, Nduagu, E, Romão, I, Zevenhoven, R., A stepwise process for carbon dioxide sequestration using magnesium silicates. Front. Chem. Eng. China 2010;4: 133-141 doi: 10.1007/s11705-009-0259-5.
15. Fagerlund, J, and Zevenhoven R. An experimental study of Mg(OH)2 carbonation. Int. J. Greenh. Gas Contr. 2011;4:1406- 1412 doi: 10.1016/j.ijggc.2011.05.039.
16. Fagerlund, J. Carbonation of Mg(OH)2 in a pressurised fluidised bed for CO2 sequestration. PhD thesis Åbo Akademi University, Turku Finland. ISBN 987-952-12-2707-3 (2012).
17. Fagerlund J, Highfield J, Zevenhoven R. Kinetics studies on wet and dry gas-solid carbonation. RSC Advances 2012;2:10380-10393. doi: 10.1039/c2ra21428h.
18. Highfield, J, Bu, J, Fagerlund, J, Zevenhoven, R. The promoter effect of steam in gas-solid CO2 mineralisation. ICCDU-XI, France, June 2011.
19. Highfield, JG, Chen, J, Bu, J, Haghighatlari, M, Fagerlund, J, Zevenhoven, R, in preparation.
20. Fagerlund, J, Nduagu, E, Romão I, Zevenhoven, R CO2 fixation using magnesium silicate minerals. Part 1: Process description and performance Energy 2012;41:184-191. doi: 10.1016/j.energy.2011.08.032.
21. Romão, I, Nduagu, E, Fagerlund, J, M Gando-Ferreira, L, Zevenhoven, R CO2 Fixation Using Magnesium Silicate Minerals. Part 2: Energy Efficiency and Integration with Iron-and Steelmaking Energy 2012;41:203-211. doi: 10.1016/j.energy.2011.08.026.
22. Romão, I, Eriksson, M, Nduagu, E, Fagerlund, J., Gando-Ferreira, L, Zevenhoven, R. Carbon dioxide storage by mineralisation applied to an industrial-scale lime kiln. Proceedings of ECOS2012, Perugia, Italy, June 2012 - paper 226.
23. Bai P, Bu J, Yeo TY, Sharratt P, Borgna, A, Khoo HH. Two birds with one stone: why CO2 mineralization is attracting interest in Singapore. ICCDU-XI, June 2011, Dijon, France.
24. Katz, T, Clausen I. CO2 capture from flue gases: existing options and perspectives. 4th EucheMs Chemistry Congr., August 2012, Prague, Czech Republic.
25. Slotte M. Romao, L, Zevenhoven, R Challenges in process scale-up of serpentinite carbonation to pilot scale" Proceedings of CPQTE12012. Sept 2012, Gliwice. Poland, paper 59.
26. Björklöf, T, Fagerlund, J, Zevenhoven, R. Novel Low Energy Routes to Activate Minerals for Large-scale Carbonation for Useful Products (NEACAP), project report Oct. 2010 Sept. 2011, Åbo Akademi University, Turku Finland (unpublished) (21 pp.).