Precipitation behaviour of As(V) during neutralization of acidic Fe(II)-As(V) solutions in batch and continuous modes

Hydrometallurgy

Volumn 146, Issue , 2014, Pages 40-47

  Daenzer, Renaud ^a   Xu, Liying ^a,b   Doerfelt, Christoph ^a   Jia, Yongfeng ^b   Demopoulos, George P ^a  

^a MCGILL UNIVERSITY   (Canada)

^b INSTITUTE OF GEOLOGY AND GEOPHYSICS   (China)

Author keywords

Arsenic removal; Ferrous arsenate; Precipitation; Symplesite

Indexed keywords

CALCIUM OXIDE; HYDROMETALLURGY; MOLAR RATIO; POLLUTION CONTROL; PRECIPITATION (CHEMICAL); SODIUM HYDROXIDE; SULFUR COMPOUNDS;

ARSENIC (V) REMOVAL; ARSENIC REMOVAL; FERROUS ARSENATE; FERROUS HYDROXIDE; PRECIPITATION BEHAVIOUR; SIMULTANEOUS REMOVAL; STEADY-STATE REGIME; SYMPLESITE;

IRON COMPOUNDS;

EID: 84898664670     PISSN: 0304386X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.hydromet.2014.03.005     Document Type: Article

References (31)

1. J. Bessière, M. Perdicakis, and B. Humbert Formation de la rouilleverte II sulfatée Fe2(OH)12SO4 par oxydation du sulfate ferreux par l'eau C. R. Acad. Sci. 2 2 1999 101 105
2. P.M.L. Bonin, M.S. Odziemkowski, E.J. Reardon, and R.W. Gillham In situ identification of carbonate-containing green rust on iron electrodes in solutions simulating groundwater J. Solut. Chem. 29 10 2000 1061 1074
3. N. Chen, D.T. Jiang, J. Cutler, T. Kotzer, Y.F. Jia, G.P. Demopoulos, and J.W. Rowson Structural characterization of poorly-crystalline scorodite, iron(III)-arsenate co-precipitates and uranium mill neutralized raffinate solids using X-ray absorption fine structure spectroscopy Geochim. Cosmochim. Acta 73 11 2009 3260 3276
4. R.J. De Klerk Investigating the continuous circuit coprecipitation of arsenic(V) with ferric iron in sulphate media (M.Eng. Thesis) 2008 McGill University Montreal
5. R.J. De Klerk, Y. Jia, R. Daenzer, M.A. Gomez, and G.P. Demopoulos Continuous circuit coprecipitation of arsenic(V) with ferric iron by lime neutralization: process parameter effects on arsenic removal and precipitate quality Hydrometallurgy 111-112 2012 65 72
6. Y. Jia, and G.P. Demopoulos Adsorption of arsenate onto ferrihydrite from aqueous solution: influence of media (sulfate (Pubitemid 41832127)
7. Y. Jia, and G.P. Demopoulos Coprecipitation of arsenate with iron(III) in aqueous sulfate media: effect of time, lime as base and co-ions on arsenic retention Water Res. 42 3 2008 661 668 (Pubitemid 351625264)
8. R.B. Johnston, and P.C. Singer Solubility of symplesite (ferrous arsenate): implications for reduced groundwaters and other geochemical environments Soil Sci. Soc. Am. J. 71 1 2007 101 107 (Pubitemid 46203489)
9. J. Jönsson, and D.M. Sherman Sorption of As(III) and As(V) to siderite, green rust (fougerite) and magnetite: implications for arsenic release in anoxic groundwaters Chem. Geol. 255 1-2 2008 173 181
10. G.H. Khoe, J.C. Huang, and R.G. Robins Precipitation chemistry of the aqueous ferrous-arsenate system D.R. Gaskell, EPD Congress' 91, TMS, Warrendale, PA 1991 101 115
11. E. Krause, and V.A. Ettel Solubilities and stabilities of ferric arsenate compounds Hydrometallurgy 22 3 1989 311 337
12. D. Langmuir, J. Mahoney, A. MacDonald, and J. Rowson Predicting arsenic concentrations in the porewaters of buried uranium mill tailings Geochim. Cosmochim. Acta 63 19-20 1999 3379 3394 (Pubitemid 30106866)
13. 2O) and their application to arsenic behavior in buried mine tailings Geochim. Cosmochim. Acta 70 12 2006 2942 2956 (Pubitemid 43827378)
14. Z. Lin, and R.W. Puls Potential indicators for the assessment of arsenic natural attenuation in the subsurface Adv. Environ. Res. 7 4 2003 825 834 (Pubitemid 36675976)
15. R. Lin, R.L. Spicer, F.L. Tungate, and B.H. Davis A study of the oxidation of ferrous hydroxide in slightly basic solution to produce [gamma]-FeOOH Colloids Surf. A Physicochem. Eng. Asp. 113 1-2 1996 79 96 (Pubitemid 26292287)
16. J. Mahoney, M. Slaughter, D. Langmuir, and J. Rowson Control of As and Ni releases from a uranium mill tailings neutralization circuit: solution chemistry, mineralogy and geochemical modeling of laboratory study results Appl. Geochem. 22 12 2007 2758 2776 (Pubitemid 350117384)
17. Metal mining effluent regulations F. Act, Canada Gazette Part II the Queen's Pinter for Canada 2002 1246 1543 Ottawa
18. T. Misawa, K. Hashimoto, and S. Shimodaira Formation of Fe(II)-Fe(III) intermediate green complex on oxidation of ferrous ion in neutral and slightly alkaline sulfate solutions J. Inorg. Nucl. Chem. 35 12 1973 4167 4174
19. B.J. Moldovan, and M.J. Hendry Characterizing and quantifying controls on arsenic solubility over a pH range of 1-11 in a uranium mill-scale experiment Environ. Sci. Technol. 39 13 2005 4913 4920 (Pubitemid 40966717)
20. 2 in aqueous solution - basic principles and a simple heuristic description Chemosphere 68 11 2007 2080 2084 (Pubitemid 47094892)
21. M. Mukiibi, W.P. Ela, and A.E. Sáez Effect of ferrous iron on arsenate sorption to amorphous ferric hydroxide Ann. N. Y. Acad. Sci. 1140 2008 335 345 (Environmental Challenges in the Pacific Basin)
22. O.P. Perez, and Y. Umetsu ORP-monitored magnetite formation from aqueous solutions at low temperatures Hydrometallurgy 55 1 2000 35 56 (Pubitemid 30558912)
23. P.T. Pinard pyconsort http://sourceforge.net/projects/consort/ 2010
24. P. Refait et al. Chemical composition and Gibbs standard free energy of formation of Fe(II)-Fe(III) hydroxy sulphate green rust and Fe(II) hydroxide Clay Miner. 34 3 1999 499 510 (Pubitemid 30065751)
25. L.C. Roberts et al. Arsenic removal with iron(II) and iron(III) in waters with high silicate and phosphate concentrations Environ. Sci. Technol. 38 1 2004 307 315 (Pubitemid 38044769)
26. R.G. Robins, J.C.Y. Huang, T. Nishimura, and G.H. Khoe The adsorption of arsenate ion by ferric hydroxide R.G. Reddy, J.L. Hendrix, P.B. Queneau, Arsenic Metallurgy: Fundamentals and Applications 1988 TMS Warrendale, PA 99 112
27. C. Ruby, A. Géhin, M. Abdelmoula, J.-M.R. Génin, and J.-P. Jolivet Coprecipitation of Fe(II) and Fe(III) cations in sulphated aqueous medium and formation of hydroxysulphate green rust Solid State Sci. 5 7 2003 1055 1062
28. H. Tamura, K. Goto, and M. Nagayama The effect of ferric hydroxide on the oxygenation of ferrous ions in neutral solutions Corros. Sci. 16 4 1976 197 207
29. L.G. Twidwell, and J.W. McCloskey Removing arsenic from aqueous solution and long-term product storage JOM 63 8 2011 94 100
30. L.G. Twidwell, R.G. Robins, and J.W. Hohn The removal of arsenic from aqueous solution by coprecipitation with iron(III) R.G. Reddy, V. Ramachandran, Arsenic Metallurgy 2005 TMS Warrendale, PA 3 24 (Pubitemid 41092031)
31. J.A. Wilkie, and J.G. Hering Adsorption of arsenic onto hydrous ferric oxide: effects of adsorbate/adsorbent ratios and co-occurring solutes Colloids Surf. A Physicochem. Eng. Asp. 107 1996 97 110 (Pubitemid 26145430)