Chemical kinetics of methane pyrolysis in microwave plasma at atmospheric pressure

Plasma Chemistry and Plasma Processing

Volumn 34, Issue 2, 2014, Pages 313-326

  Dors, Miroslaw ^a   Nowakowska, Helena ^a   Jasiński, Mariusz ^a   Mizeraczyk, Jerzy ^a,b  

^a INSTITUTE OF FLUID FLOW MACHINERY   (Poland)

^b GDYNIA MARITIME UNIVERSITY   (Poland)

Author keywords

Methane; Microwave plasma; Modeling; Pyrolysis

Indexed keywords

ATMOSPHERIC PRESSURE; BOMBS (ORDNANCE); C (PROGRAMMING LANGUAGE); CALORIMETRY; EXPERIMENTS; MICROWAVES; MODELS; PLASMAS; PYROLYSIS; REACTION KINETICS;

CALORIMETRIC BOMB; CHEMICAL KINETICS MODEL; METHANE CONVERSIONS; MICROWAVE PLASMA; NUMERICAL CALCULATION; PLASMA TEMPERATURE; REACTION MECHANISM; THERMODYNAMIC EQUILIBRIA;

METHANE;

EID: 84898547700     PISSN: 02724324     EISSN: None     Source Type: Journal    
DOI: 10.1007/s11090-013-9510-4     Document Type: Article

References (28)

1. Uhm HS, Hong YC, Shin DH (2006) A microwave plasma torch and its application. Plasma Sources Sci Technol 15:S26-S34
2. Kabouzi Y, Moisan M, Rostaing JC, Trassy C, Keroack D, Zakrzewski Z (2003) Abatement of perfluorinated compounds using microwave plasmas at atmospheric pressure. J Appl Phys 93:9483-9496
3. Jasin?ski M, Dors M, Nowakowska H, Mizeraczyk J (2008) Hydrogen production using various microwave plasma sources. Chem Listy 102:1332-1337
4. Jasin?ski M, Dors M, Mizeraczyk J (2008) Production of hydrogen via methane reforming using atmospheric pressure microwave plasma. J Power Sources 181:41-45
5. Jasinski M, Dors M, Mizeraczyk J (2009) Destruction of Freon HFC-134a using a nozzleless microwave plasma source. Plasma Chem Plasma Process 29:363-372
6. Jasin?ski M, Czylkowski D, Hrycak B, Dors M, Mizeraczyk J (2013) Atmospheric pressure microwave plasma source for hydrogen production. Int J Hydrogen Energy. doi:10.1016/j.ijhydene.2013.05.105
7. Moisan M, Sauve G, Zakrzewski Z, Hubert J (1994) An atmospheric pressure waveguide-fed microwave plasma torch: The TIA design. Plasma Sources Sci Technol 3:584-592
8. Moisan M, Zakrzewski Z (1995) Plasma sources using long linear microwave field applicators: Main features, classification and modeling. Plasma Sources Sci Technol 4:379-397
9. Kabouzi Y, Moisan M (2005) Pulsed microwave discharges sustained at atmospheric pressure: Study of the contraction and filamentation phenomena. IEEE Trans Plasma Sci 33:292-293
10. Nowakowska H, Jasin?ski M, Debicki P, Mizeraczyk J (2011) Numerical analysis and optimization of power coupling efficiency in waveguide-based microwave plasma source. IEEE Trans Plasma Sci 39:1935-1941
11. The Leeds methane oxidation mechanism, Version 1.5, http://garfield.chem. elte.hu/Combustion/methane.htm
12. Hughes KJ, Turanyi T, Clague AR, Pilling MJ (2001) Development and testing of a comprehensive chemical mechanism for the oxidation of methane. Int J Chem Kinet 33:513-538
13. Sirignano M, Kent J, D?Anna A (2013) Modeling formation and oxidation of soot in nonpremixed flames. Energy Fuels 27:2303-2315
14. Valin S, Cances J, Castelli P, Thiery S, Dufour A, Boissonnet G, Spindler B (2009) Upgrading biomass pyrolysis gas by conversion of methane at high temperature: Experiments and modeling. Fuel 88:834-842
15. Slavinskaya NA, Frank P (2009) A modelling study of aromatic soot precursors formation in laminar methane and ethene flames. Combust Flame 156:1705-1722
16. Skj?th-Rasmussen MS, Glarborg P, ?stberg M, Johannessen JT, Livbjerg H, Jensen AD, Christensen TS (2004) Formation of polycyclic aromatic hydrocarbons and soot in fuel-rich oxidation of methane in a laminar flow reactor. Combust Flame 136:91-128
17. Nowakowska H, Jasin?ski M, Mizeraczyk J (2010) Two-dimensional simulations of atmospheric pressure microwave discharge in methane, XX European conf. on the atomic and molecular physics of ionized gases, 13-17 July, Novi Sad, Serbia
18. Lee DH, Kim K-T, Song Y-H, Kang WS, Jo S (2013) Mapping plasma chemistry in hydrocarbon fuel processing processes. Plasma Chem Plasma Process 33:249-269
19. Kassel LS (1932) The thermal decomposition of CH4. J Am Chem Soc 54:3949-3961
20. Baulch DL, Cobos CJ, Cox RA, Frank P, Hayman G, Just Th, Kerr JA, Murrells T, Pilling MJ, Troe J, Walker RW, Warnatz J (1994) Evaluated kinetic data for combustion modelling supplement I. J Phys Chem Ref Data 23:847-1033
21. Glarborg P, Miller JA, Kee RJ (1986) Kinetic modeling and sensitivity analysis of nitrogen oxide formation in well-stirred reactors. Combust Flame 64:177-202
22. Bohland T, Dobe S, Temps F, Wagner HG (1985) Kinetics of the reactions between CH2(X3B1)-radicals and saturated hydrocarbons in the temperature range 296 K B TB707 K. Ber Bunsenges Phys Chem 89:1110-1116
23. Langford AO, Petek H, Moore CB (1983) Collisional removal of CH2(1A1)-absolute rate constants for atomic and molecular collisional partners at 295 K. J Chem Phys 78:6650-6659
24. Tsang W, Hampson RF (1986) Chemical kinetic database for combustion chemistry.1. Methane and related-compounds. J Phys Chem Ref Data 15:1087-1279
25. Frank P, Bhaskaran KA, Just T (1986) High-temperature reactions of triplet methylene and ketene with radicals. J Phys Chem 90:2226-2231
26. Miller JA, Bowman CT (1989) Mechanism and modeling of nitrogen chemistry in combustion. Prog Energy Combust Sci 15:287-338
27. Becker KH, Engelhardt B, Wiesen P, Bayes KD (1989) Rate constants for CH(X2P) reactions at low total pressures. Chem Phys Lett 154:342-348
28. Warnatz J (1984) In: Gardiner WC Jr (ed) Combustion chemistry. Springer, New York