Generation of cathode passivation films via oxidation of lithium bis(oxalato) borate on high voltage spinel (LiNi0.5Mn 1.5O4)

Journal of Physical Chemistry C

Volumn 118, Issue 14, 2014, Pages 7363-7368

  Xu, Mengqing ^a   Tsiouvaras, Nikolaos ^b,d   Garsuch, Arnd ^c   Gasteiger, Hubert A ^b   Lucht, Brett L ^a  

^a University of Rhode Island   (United States)

^b TECHNICAL UNIVERSITY OF MUNICH   (Germany)

^c BASF SE   (Germany)

^d BMW AG   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

CARBON DIOXIDE; ELECTROLYTES; ETHYLENE; LITHIUM; MANGANESE; OXIDATION; PASSIVATION; SURFACE ANALYSIS;

BULK ELECTROLYTES; ELECTROCHEMICAL MEASUREMENTS; ETHYLENE CARBONATE; HIGH POTENTIAL; HIGH-VOLTAGE SPINELS; LITHIUM BIS(OXALATO)BORATE; LITHIUM-ION BATTERY; PASSIVATION FILM;

CATHODES;

EID: 84898434290     PISSN: 19327447     EISSN: 19327455     Source Type: Journal    
DOI: 10.1021/jp501970j     Document Type: Article

References (24)

1. 4 Spinel Cathodes in Lithium-ion Cells Chem. Mater. 2009, 21, 1695-1707
2. 4 and Carbon Electrodes for Lithium-ion 5-V Cells J. Power Sources 2006, 162, 780-789
3. 4: Effects of Doping and Particle Size J. Phys. Chem. C 2011, 115, 6102-6110
4. 4 Porous Nanorods as High-Rate and Long-Life Cathodes for Li-Ion Batteries Nano Lett. 2013, 13, 2822-2825
5. 4 Cathodes for Lithium-ion Batteries Electrochem. Solid-State Lett. 2010, 13, A95-A97
6. 4 Cells at High Voltage and Elevated Temperature J. Electrochem. Soc. 2013, 160, A3138-A3143
7. 4 Electrode at Elevated Temperature J Power Sources 2012, 215, 312-316
8. Zhang, Z.; Hu, L.; Wu, H.; Weng, W.; Koh, M.; Redfern, P. C.; Curtiss, L. A.; Amine, K. Fluorinated Electrolytes for 5 V Lithium-ion Battery Chemistry Energy Environ. Sci. 2013, 6, 1806-1810
9. Xu, K.; Angell, C. A. Sulfone-Based Electrolytes for Lithium-Ion Batteries J. Electrochem. Soc. 2002, 149, A920-A926
10. Abouimrane, A.; Belharouak, I.; Amine, K. Sulfone-based Electrolytes for High-voltage Li-ion Batteries Electrochem. Commun. 2009, 11, 1073-1076
11. Felix; Cheng, J. -H.; Hy, S.; Rick, J.; Wang, F. -M; Hwang, B. -J. Mechanistic Basis of Enhanced Capacity Retention Found with Novel Sulfate-Based Additive in High-Voltage Li-Ion Batteries J. Phys. Chem. C 2013, 117, 22619-22626
12. Abu-Lebdeh, Y.; Davidson, I. High-Voltage Electrolytes Based on Adiponitrile for Li-Ion Batteries J. Electrochem. Soc. 2009, 156, A60-A65
13. Cresce, A. V.; Xu, K. Electrolyte Additive in Support of 5 V Li Ion Chemistry J. Electrochem. Soc. 2011, 158, A337-A342
14. 4 Cathodes with Electrolytes Containing Dimethylmethylphosphonate (DMMP) J. Electrochem. Soc. 2012, 159, A2130-A2134
15. 4) Spinel Cathodes Electrochem. Solid-State Lett. 2012, 15, A28-A31
16. 4 Cells at High Voltage and Elevated Temperature with Added Lithium Bis(oxalato) Borate (LiBOB) J. Electrochem. Soc. 2013, 160, A2005-A2013
17. 4 Cathodes at 60 °C Electrochim. Acta 2013, 104, 170-177
18. Pieczonka, N. P. W.; Yang, L.; Balogh, M. P.; Powell, B. R.; Chemlewski, K.; Manthiram, A.; Krachkovskiy, S. A.; Goward, G. R.; Liu, M.; Kim, J.-H. Impact of Lithium Bis(oxalate)borate Electrolyte Additive on the Performance of High-Voltage Spinel/Graphite Li-Ion Batteries J. Phys. Chem. C 2013, 117, 22603-22612
19. 2 Battery J. Electrochem. Soc. 2013, 160, A471-A477
20. Shkrob, I. A.; Zhu, Y.; Marin, T. W.; Abraham, D. P. Mechanistic Insight into the Protective Action of Bis(oxalato)borate and Difluoro(oxalate)borate Anions in Li-Ion Batteries J. Phys. Chem. C 2013, 117, 23750-23756
21. Imhof, R.; Novak, P. Oxidative Electrolyte Solvent Degradation in Lithium-Ion Batteries: An In Situ Differential Electrochemical Mass Spectrometry Investigation J. Electrochem. Soc. 1999, 146, 1702-1706
22. 2 at High Potentials J. Appl. Electrochem. 2008, 38, 893-896
23. 2 Chem. Mater. 2009, 21, 2733-2745
24. Li, W.; Lucht, B. L. Lithium-Ion Batteries: Thermal Reactions of Electrolyte with the Surface of Metal Oxide Cathode Particles J. Electrochem. Soc. 2006, 153, A1617-A1625