Molecular catalysis that transpires only when the complex is heterogenized: Studies of a hydrogenase complex surface-tethered on polycrystalline and (1 1 1)-faceted gold by EC, PM-FT-IRRAS, HREELS, XPS and STM

Journal of Electroanalytical Chemistry

Volumn 716, Issue , 2014, Pages 63-70

  Chmielowiec, Brian ^a   Saadi, Fadl H ^a   Baricuatro, Jack H ^a   Javier, Alnald ^a   Kim, Youn Geun ^a   Sun, Guofeng ^a   Darensbourg, Marcetta Y ^b   Soriaga, Manuel P ^a,b  

^a California Institute of Technology   (United States)

^b TEXAS A AND M UNIVERSITY   (United States)

Author keywords

Biologically inspired electrocatalysis; HER electrocatalysis by surface attached di iron hydrogenase complexes; Heterogeneous catalysis with homogeneous complexes; Hydrogen evolution reaction; Surface immobilization enabled molecular catalysis

Indexed keywords

ABSORPTION SPECTROSCOPY; BIOMIMETICS; CATALYSIS; CATALYST ACTIVITY; ELECTROCATALYSIS; ELECTROCATALYSTS; ELECTRODES; ELECTROLYTES; ELECTRON ENERGY LEVELS; ELECTRON ENERGY LOSS SPECTROSCOPY; ELECTRON SCATTERING; ENERGY DISSIPATION; GOLD; HYDROGEN EVOLUTION REACTION; REDUCTION; SCANNING TUNNELING MICROSCOPY; SHEET METAL; SURFACE REACTIONS; X RAY PHOTOELECTRON SPECTROSCOPY;

BIOLOGICALLY INSPIRED; FOURIER TRANSFORM INFRA REDS; HETEROGENIZED CATALYSTS; HIGH-RESOLUTION ELECTRON ENERGY LOSS SPECTROSCOPY; HYDROGENASES; NON-AQUEOUS ELECTROLYTES; POLARIZATION MODULATION; SURFACE IMMOBILIZATION;

IRON COMPOUNDS;

EID: 84898071850     PISSN: 15726657     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jelechem.2013.12.025     Document Type: Article

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