Controlled radical polymerization at high conversion: Bulk ICAR ATRP of methyl methacrylate

Industrial and Engineering Chemistry Research

Volumn 53, Issue 9, 2014, Pages 3472-3477

  Mohammad Rabea, Ali ^a   Zhu, Shiping ^a  

^a MCMASTER UNIVERSITY   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

CONTROLLED RADICAL POLYMERIZATION; DIFFUSION CONTROLLED REACTIONS; DIFFUSION-CONTROLLED; HIGH CONVERSIONS; METHYL METHACRYLATES; POLYMER MOLECULAR WEIGHT; POLYMERIZATION TEMPERATURE; TERT-BUTYL PEROXYBENZOATE;

ACRYLIC MONOMERS; DIFFUSION; ESTERS; MOLECULAR WEIGHT DISTRIBUTION; POLYMERIZATION; POLYMERS;

ATOM TRANSFER RADICAL POLYMERIZATION;

EID: 84897712537     PISSN: 08885885     EISSN: 15205045     Source Type: Journal    
DOI: 10.1021/ie403731m     Document Type: Article

References (30)

1. Georges, M. K.; Veregin, R. P. N.; Kazmaier, P. M.; Hamer, G. K. Narrow Molecular Weight Resins by a Free-Radical Polymerization Process Macromolecules 1993, 26, 2987
2. Wang, J.; Matyjaszewski, K. Controlled "Living" Radical Polymerization. Atom Transfer Radical Polymerization in the Presence of Transition-Metal Complexes J. Am. Chem. Soc. 1995, 117, 5614
3. Wang, J. S.; Matyjaszewski, K. Controlled/"Living" Radical Polymerization. Halogen Atom Transfer Radical Polymerization Promoted by a Cu(I)/Cu(II) Redox Process Macromolecules 1995, 28, 7901
4. Kato, M.; Kamigaito, M.; Sawamoto, M.; Higashimuras, T. Polymerization of Methyl Methacrylate with the Carbon Tetrachloride/Dichlorotris- (triphenylphosphine)ruthenium(II)/Methylaluminum Bis(2,6-di-tert-butylphenoxide) Initiating System: Possibility of Living Radical Polymerization Macromolecules 1995, 28, 1721
5. Chiefari, J.; Chong, Y. K. B.; Ercole, F.; Krstina, J.; Jeffery, J.; Le, T. P. T.; Mayadunne, R. T. A.; Meijs, G. F.; Moad, C. L.; Moad, G.; Rizzardo, E.; Thang, S. H.; South, C. Living Free-Radical Polymerization by Reversible Addition-Fragmentation Chain Transfer: The RAFT Process Macromolecules 1998, 31, 5559
6. Faucher, S.; Zhu, S. Heterogeneous Atom Transfer Radical Polymerization of Methyl Methacrylate at Low Metal Salt Concentrations Ind. Eng. Chem. Res. 2005, 44, 677
7. He, W.; Zhang, L.; Bai, L.; Zhang, Z.; Zhu, J.; Cheng, Z.; Zhu, X. Iron-Mediated AGET ATRP of Methyl Methacrylate in the Presence of Catalytic Amounts of Base Macromol. Chem. Phys. 2011, 212, 1474
8. Shipp, D. A.; Matyjaszewski, K. Kinetic Analysis of Controlled/ "Living" Radical Polymerizations by Simulations. 1. The Importance of Diffusion-Controlled Reactions Macromolecules 1999, 32, 2948
9. Butte, A.; Storti, G.; Morbidelli, M. Kinetics of "Living" Free Radical Polymerization Chem. Eng. Sci. 1999, 54, 3225
10. Yu, Q.; Zeng, F.; Zhu, S. Atom Transfer Radical Polymerization of Poly(Ethylene Glycol) Dimethacrylate Macromolecules 2001, 34, 1612
11. Delgadillo-Velazquez, O.; Vivaldo-Lima, E. Effects of Diffusion-Controlled Reactions on Atom-Transfer Radical Polymerization AIChE J. 2002, 48, 2597
12. Matyjaszewski, K. Controlled Radical Polymerization: State-of-the-Art in 2011. In Controlled Radical Polymerization: Mechanisms and Techniques; American Chemical Society: Washingtom, DC, 2012; p 1.
13. Matyjaszewski, K.; Patten, T. E.; Xia, J. Controlled/"Living" Radical Polymerization. Kinetics of the Homogeneous Atom Transfer Radical Polymerization of Styrene J. Am. Chem. Soc. 1997, 119, 674
14. Matyjaszewski, K.; Xia, J. Atom Transfer Radical Polymerization Chem. Rev. 2001, 101, 2921
15. Tsarevsky, N. V.; Matyjaszewski, K. Green" Atom Transfer Radical Polymerization: From Process Design to Preparation of Well-Defined Environmentally Friendly Polymeric Materials Chem. Rev. 2007, 107, 2270
16. Haddleton, D. M.; Kukulj, D.; Radigue, A. P. Atom Transfer Polymerisation of Methyl Methacrylate Mediated by Solid Supported Copper Catalysts Chem. Commun. 1999, 99
17. Kickelbick, G.; Paik, H.; Matyjaszewski, K. Immobilization of the Copper Catalyst in Atom Transfer Radical Polymerization Macromolecules 1999, 32, 2941
18. Shen, Y.; Zhu, S.; Zeng, F.; Pelton, R. H. Atom Transfer Radical Polymerization of Methyl Methacrylate by Silica Gel Supported Copper Bromide/Multidentate Amine Macromolecules 2000, 33, 5427
19. Shen, Y.; Zhu, S.; Pelton, R. Packed Column Reactor for Continuous Atom Transfer Radical Polymerization: Methyl Methacrylate Polymerization Using Silica Gel Supported Catalyst Macromol. Rapid Commun. 2000, 21, 956
20. Faucher, S.; Zhu, S. Fundamentals and Development of High-Efficiency J. Polym. Sci., Part A: Polym. Chem. 2007, 45, 553
21. De Campo, F.; Lastécouères, D.; Verlhac, J. B. New and Improved Catalysts for Transition Metal Catalysed Radical Reactions Chem. Commun. 1998, 2117
22. Xia, J.; Gaynor, S. G.; Matyjaszewski, K. Controlled/"Living" Radical Polymerization. Atom Transfer Radical Polymerization of Acrylates at Ambient Temperature Macromolecules 1998, 31, 5958
23. Queffelec, J.; Gaynor, S. G.; Matyjaszewski, K. Optimization of Atom Transfer Radical Polymerization Using Cu (I)/Tris(2-(dimethylamino)ethyl)amine as a Catalyst Macromolecules 2000, 33, 8629
24. Jakubowski, W.; Matyjaszewski, K. Activators Regenerated by Electron Transfer for Atom-Transfer Radical Polymerization of (Meth)acrylates and Related Block Copolymers Angew. Chem. 2006, 118, 4594
25. Jakubowski, W.; Min, K.; Matyjaszewski, K. Activators Regenerated by Electron Transfer for Atom Transfer Radical Polymerization of Styrene Macromolecules 2006, 39, 39
26. Min, K.; Gao, H.; Matyjaszewski, K. Use of Ascorbic Acid as Reducing Agent for Synthesis of Well-Defined Polymers by ARGET ATRP Macromolecules 2007, 40, 1789
27. Matyjaszewski, K.; Jakubowski, W.; Min, K.; Tang, W.; Huang, J.; Braunecker, W. A; Tsarevsky, N. V. Diminishing Catalyst Concentration in Atom Transfer Radical Polymerization with Reducing Agents Proc. Natl. Acad. Sci. U.S.A. 2006, 103, 15309
28. Mastan, E.; Zhou, D.; Zhu, S. Modeling Molecular Weight Distribution and Effect of Termination in Controlled Radical Polymerization: A Novel and Transformative Approach J. Polym. Sci., Part A: Polym. Chem. 2014, 52, 639
29. Wang, A. R.; Zhu, S. ESR Study on Diffusion-Controlled Atom Transfer Radical Polymerization of Methyl Methacrylate and Ethylene Glycol Dimethacrylate Macromolecules 2002, 35, 9926
30. Wang, A. R.; Zhu, S. Effects of Diffusion-Controlled Radical Reactions on RAFT Polymerization Macromol. Theory Simul. 2003, 12, 196