Temperature-dependent raman spectroscopic evidence of and molecular mechanism for irreversible isomerization of β-endosulfan to α-endosulfan

Journal of Agricultural and Food Chemistry

Volumn 62, Issue 9, 2014, Pages 2023-2030

  Schmidt, Walter F ^a   Hapeman, Cathleen J ^a   McConnell, Laura L ^a   Mookherji, Swati ^a   Rice, Clifford P ^a   Nguyen, Julie K ^a   Qin, Jianwei ^a   Lee, Hoyoung ^a   Chao, Kuanglin ^a   Kim, Moon S ^a  

^a AGRICULTURAL RESEARCH SERVICE   (United States)

Author keywords

1,3 dioxepane; 2D TDR spectra; endosulfan (6,7,8,9,10,10 hexachloro 1,5,5a,6,9,9a hexahydro 6,9 methano 2, 4,3 benzodioxathiepine 3 oxide); Raman ring bending frequency; temperature dependent conformational changes; temperature dependent Raman (TDR) spectroscopy

Indexed keywords

1,3-DIOXEPANE; CONFORMATIONAL CHANGE; ENDOSULFANS; RAMAN RING-BENDING FREQUENCY; TEMPERATURE-DEPENDENT RAMAN; BENDING FREQUENCY;

BIOCHEMISTRY; ISOMERIZATION; ISOMERS; ORGANIC POLLUTANTS; AQUATIC ECOSYSTEMS; POLLUTION;

INSECTICIDES;

ENDOSULFAN; INSECTICIDE;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; ISOMERISM; RAMAN SPECTROMETRY;

ENDOSULFAN; INSECTICIDES; ISOMERISM; MOLECULAR STRUCTURE; SPECTRUM ANALYSIS, RAMAN;

EID: 84897676619     PISSN: 00218561     EISSN: 15205118     Source Type: Journal    
DOI: 10.1021/jf404404w     Document Type: Article

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